(methylenedi-4,1-phenylene)bis(glycidyl carbamate) | 85896-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (methylenedi-4,1-phenylene)bis(glycidyl carbamate)
• 英文别名: Carbamic acid, (methylenedi-4,1-phenylene)bis-, bis(oxiranylmethyl) ester；oxiran-2-ylmethyl N-[4-[[4-(oxiran-2-ylmethoxycarbonylamino)phenyl]methyl]phenyl]carbamate
• CAS: 85896-20-4
• 化学式: C₂₁H₂₂N₂O₆
• 分子量: 398.415
• InChiKey: WUHXZSHVMTZSOK-UHFFFAOYSA-N

物化性质

• 沸点：
  509.5±40.0 °C(Predicted)
• 密度：
  1.381±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (methylenedi-4,1-phenylene)bis(glycidyl carbamate) 在 1,5,7-三氮杂双环[4.4.0]癸-5-烯 作用下， 以 丙酮 为溶剂， 反应 24.0h， 以56%的产率得到3,3'-(methylenedi-4,1-phenylene)bis[4-(hydroxymethyl)-2-oxazolidinone]
  参考文献：
  名称：

  双环胍催化氨基甲酸缩水甘油酯衍生物合成多功能4-羟甲基2-恶唑烷酮

  摘要：

  通过以双环胍为有效催化剂的氨基缩水甘油酯衍生物的分子内环化，已在温和条件下成功合成了4-羟甲基2-恶唑烷酮。该反应体系也适用于多官能化合物，可以提供具有恶唑烷酮部分的双官能和三官能醇。

  DOI：

  10.1016/j.tetlet.2021.153086
• 作为产物：
  描述：

  缩水甘油 、 4,4'-二苯甲烷二异氰酸酯、2,4'-二苯甲烷二异氰酸酯和2,2'-二苯甲烷二异氰酸酯的混合物 以 二氯甲烷 为溶剂， 反应 24.0h， 以96%的产率得到(methylenedi-4,1-phenylene)bis(glycidyl carbamate)
  参考文献：
  名称：

  双环胍催化氨基甲酸缩水甘油酯衍生物合成多功能4-羟甲基2-恶唑烷酮

  摘要：

  通过以双环胍为有效催化剂的氨基缩水甘油酯衍生物的分子内环化，已在温和条件下成功合成了4-羟甲基2-恶唑烷酮。该反应体系也适用于多官能化合物，可以提供具有恶唑烷酮部分的双官能和三官能醇。

  DOI：

  10.1016/j.tetlet.2021.153086

文献信息

• JP2016513093A5
  申请人：——

  公开号：JP2016513093A5

  公开（公告）日：2016-05-12
• SYNTHESIS OF POLYURETHANE POLYMERS VIA COPPER AZIDE-ALKYNE CLICK CHEMISTRY FOR COATINGS, ADHESIVES, SEALANTS AND ELASTOMER APPLICATIONS
  申请人：Sika Technology AG

  公开号：US20150368530A1

  公开（公告）日：2015-12-24

  The present application is directed at the reaction product of an azide compound having two or more azide groups attached thereto and an alkyne compound having two or more alkyne groups attached thereto, wherein the azide and alkyne groups react in a 1,3-dipolar cyclo addition to form 1,4-disubstituted triazols and wherein the azide or alkyne compound or both include —O—(C═O)—NR— functional groups. The reaction products can be used as coatings, such as for flat roofs, sealants, adhesives and in elastomer applications. Methods for producing the reaction products as well as substrates including a coating of the reaction product are also disclosed.
• US9790398B2
  申请人：——

  公开号：US9790398B2

  公开（公告）日：2017-10-17
• [EN] CURABLE COMPOSITIONS CONTAINING URETHANE LINKAGES FOR REWORKABLE ADHESIVES<br/>[FR] COMPOSITIONS DURCISSABLES CONTENANT DES LIAISONS URÉTHANNES POUR ADHÉSIFS APTES À UNE REPRISE
  申请人：HENKEL CORP

  公开号：WO2009155291A1

  公开（公告）日：2009-12-23

  A reworkable resin having an urethane linkage with a thermally curable terminal functionality is disclosed. The cured product of the reworkable resin is particularly useful to adhere electronic components to substrates where reworkability is desirable
• [EN] SYNTHESIS OF POLYURETHANE POLYMERS VIA COPPER AZIDE-ALKYNE CLICK CHEMISTRY FOR COATINGS, ADHESIVES, SEALANTS AND ELASTOMER APPLICATIONS<br/>[FR] SYNTHÈSE DE POLYMÈRES DE POLYURÉTHANE PAR CHIMIE CLICK DE COUPLAGE AZIDE-ALCYNE CATALYSÉE PAR LE CUIVRE POUR REVÊTEMENTS, ADHÉSIFS, MATÉRIAUX D'ÉTANCHÉITÉ ET APPLICATIONS ÉLASTOMÈRES
  申请人：SIKA TECHNOLOGY AG

  公开号：WO2014122153A1

  公开（公告）日：2014-08-14

  The present application is directed at the reaction product of an azide compound having two or more azide groups attached thereto and an alkyne compound having two or more alkyne groups attached thereto, wherein the azide and alkyne groups react in a 1,3-dipolar cyclo addition to form 1,4-disubstituted triazols and wherein the azide or alkyne compound or both comprise -O-(C=O)-NR- functional groups. The inventive reaction products are suitable as a replacement for conventional polyurethane-based sealing, coating and adhesive materials and provide the benefits, that the final cross-linking reaction proceeds in the absence of isocyanates leading to significantly lower exposition risks than the conventional polyisocyanate-based materials. The present application further relates to the use of these reaction products as coatings, preferably for flat roofs, sealants, adhesives and in elastomer applications. Furthermore, the present application relates to methods for producing the reaction products as well as substrates comprising a coating of said reaction product.