hexakis-chloromethyl-benzene | 40205-81-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: hexakis-chloromethyl-benzene
• 英文别名: Hexakis-chlormethyl-benzol；Hexakis(chlormethyl)benzol；Hexakis(chloromethyl)benzene；1,2,3,4,5,6-hexakis(chloromethyl)benzene
• CAS: 40205-81-0
• 化学式: C₁₂H₁₂Cl₆
• 分子量: 368.945
• InChiKey: CBXSRZCXQWNWTK-UHFFFAOYSA-N

物化性质

• 沸点：
  446.1±40.0 °C(Predicted)
• 密度：
  1.443±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  hexakis-chloromethyl-benzene 、 乙酸酐 在 potassium acetate 作用下， 生成 Hexakis-acetoxymethyl-benzol
  参考文献：
  名称：

  Backer, Recueil des Travaux Chimiques des Pays-Bas, 1936, vol. 55, p. 591

  摘要：

  DOI：
• 作为产物：
  描述：

  六甲基苯 在 五氯化磷 作用下， 生成 hexakis-chloromethyl-benzene
  参考文献：
  名称：

  Colson, Bulletin de la Societe Chimique de France, 1886, vol. <2> 46, p. 198

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCTION OF POLYMERS WITH IRON COMPLEX CATALYST
  申请人：Kai Hidetomo

  公开号：US20110105703A1

  公开（公告）日：2011-05-05

  The invention relates to a novel iron complex bearing a cyclic amine as ligand; and a process for the production of polymers by polymerizing a radical-polymerizable monomer in the presence of the iron complex and a radical generator. The invention aims at providing a process by which a polymer having a chemically convertible functional group at the end can be produced from a radical-polymerizable monomer and which permits the production of a block copolymer and a process for recovering, after polymerization, an iron complex into a solvent at a high recovery ratio. The aim can be solved by providing a novel iron complex, a process for producing a polymer in the presence of a radical polymerization initiator by using the iron complex as the polymerization catalyst, a process for the production of a block copolymer which is subsequent to the polymerization for producing the above polymer, and a process for recovering the iron complex easily and simply. The invention provides an iron complex useful in producing a polymer by polymerizing a radical-polymerizable monomer; and a process for the production of polymers with the iron catalyst.

  该发明涉及一种具有环胺作为配体的新型铁配合物；以及通过在铁配合物和自由基发生剂的存在下聚合自由基可聚合单体来生产聚合物的方法。该发明旨在提供一种通过在自由基可聚合单体中生产具有化学可转化官能团末端的聚合物的方法，并且允许生产嵌段共聚物以及在聚合后将铁配合物以高回收率回收到溶剂中的方法。该目的可以通过提供一种新型铁配合物、在自由基聚合引发剂的存在下使用铁配合物作为聚合催化剂生产聚合物的方法、在上述聚合物生产后用于生产嵌段共聚物的方法以及轻松简便地回收铁配合物的方法来实现。该发明提供了一种有用的铁配合物，用于通过聚合自由基可聚合单体来生产聚合物；以及使用铁催化剂生产聚合物的方法。
• Phosphorus-sulfur FR additives and polymer systems containing same
  申请人：Shankar Ravi B.

  公开号：US20080153950A1

  公开（公告）日：2008-06-26

  Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

  磷硫化合物在有机聚合物系统中具有阻燃活性。磷硫化合物可以用以下结构表示：其中X是氧或硫，T是共价键，氧、硫或氮，但至少有一个X和T是硫，每个X'独立地是氧或硫，每个m在X'为氧时独立地为零或1，在X'为硫时为零、1或2，n至少为1，最好至少为2，每个R独立地是未取代或惰性取代的烃基，或者R基共同形成未取代或惰性取代的二价有机基团，A是有机连接基团。
• PROCESS FOR THE PREPARATION OF CROSSLINKED NITROXIDE POLYMERS
  申请人：Nesvadba Peter

  公开号：US20100240858A1

  公开（公告）日：2010-09-23

  The invention relates to a process for the preparation of crosslinked polymers bearing nitroxide groups, which are prepared by a method frequently called atom transfer radical addition polymerization (ATRA). A further aspect of the invention is the use of such polymeric crosslinked nitroxides as stabilizers for polymers against the detrimental influences of heat and UV light, as stabilizers against premature polymerization of vinyl aromatic monomers and as active electrode materials in secondary batteries.

  本发明涉及一种制备带有亚硝基基团的交联聚合物的方法，该方法通常称为原子转移自由基加成聚合（ATRA）。本发明的另一个方面是使用这种聚合物交联的亚硝基作为稳定剂，以抵抗热和紫外线的有害影响，以防止乙烯芳香单体的过早聚合，并作为二次电池中的活性电极材料。
• PHOSPHORUS-SULFUR FR ADDITIVES AND POLYMER SYSTEMS CONTAINING SAME
  申请人：Shankar Ravi B.

  公开号：US20110034573A1

  公开（公告）日：2011-02-10

  Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

  磷硫化合物在有机聚合物系统中具有阻燃活性。磷硫化合物的结构可以表示为：其中X为氧或硫，T为共价键，氧、硫或氮，但至少一个X和T为硫，每个X'独立地为氧或硫，每个m独立地为零或1（当X'为氧时）和零、1或2（当X'为硫时），n至少为1且最好至少为2，每个R独立地为未取代或惰性取代的烃基，或R基共同形成未取代或惰性取代的二价有机基团，A为有机连接基团。
• PROCESS FOR PRODUCTION OF POLYMER USING IRON COMPLEX AS CATALYST
  申请人：Kyushu University, National University Corporation

  公开号：EP1944325A1

  公开（公告）日：2008-07-16

  The object of the present invention is to provide a method of producing a polymer wherein radical-polymerizable monomers can be polymerized in a quantitative manner in a relatively short time, and a polymer or a block copolymer having at its termini a functional group that can be chemically converted while the polymer or the block copolymer has a high molecular weight can be produced. Furthermore, the object of the present invention is to provide a method of producing a polymer wherein the polymer is re-precipitated in a general solvent by an easy method, and the used iron complexes are recovered in the solvent, thereby recycling the iron complexes.

  本发明的目的是提供一种生产聚合物的方法，在这种方法中，可自由基聚合的单体可在相对较短的时间内定量聚合，并可生产出聚合物或嵌段共聚物，该聚合物或嵌段共聚物的端部具有可化学转化的官能团，同时该聚合物或嵌段共聚物具有高分子量。此外，本发明的目的还在于提供一种生产聚合物的方法，在这种方法中，聚合物通过简便的方法在一般溶剂中重新沉淀，用过的铁络合物在溶剂中回收，从而回收了铁络合物。