deuterodichloromethyl | 26443-88-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: deuterodichloromethyl
• 英文别名: dichloro-deuterio-methyl；Deuterio-dichlor-methyl
• CAS: 26443-88-9
• 化学式: CHCl₂
• 分子量: 84.917
• InChiKey: ZJULYDCRWUEPTK-MICDWDOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氢气 、 deuterodichloromethyl 以 neat (no solvent) 为溶剂， 生成 盐酸 、 氘代盐酸 、 dichloromethane-d1 、 chlorocarbene 、 chlorocarbene
  参考文献：
  名称：

  Reaction of hydrogen atoms with halogeno-methanes. Part 3.—Chloroform deuterochloroform and bromodichloromethane

  摘要：

  DOI：

  10.1039/tf9666200405
• 作为产物：
  描述：

  氘代氯仿 以 solid matrix 为溶剂， 生成 deuterodichloromethyl
  参考文献：
  名称：

  Matrix‐Isolation Studies of the Infrared Spectra of the Free Radicals CCl₃ and CBr₃

  摘要：

  CCl3 has been stabilized both by the reaction of lithium atoms with CCl4 in an argon matrix at 20°K and by the vacuum-ultraviolet photolysis of HCCl3 or of DCCl3 in an argon or a nitrogen matrix at 14°K. The analogous techniques have been found to lead to the stabilization of CBr3. The product spectra obtained in the lithium-atom experiments are considerably simpler than those obtained in the previous studies of the reaction of lithium atoms with matrix-isolated CX4. In the vacuum-ultraviolet photolysis experiments, DCCl2, HCBr2, and CBr2 have also been observed. The absorption frequencies and contours obtained for ν3 of CCl3 and of CBr3 are independent of the method used to produce these species, suggesting that lithium atoms and their reaction products do not appreciably perturb the degenerate stretching mode of either CCl3 or CBr3. Despite yields of these species comparable to those previously reported, absorptions at 674 and at 582 cm−1, previously attributed to ν1 of CCl3 and CBr3, respectively, are completely missing from the present experiments. No other absorption attributable to ν1 of either species has been detected. It is concluded that a pyramidal (C3υ) structure for CCl3 and for CBr3 has not been established.

  DOI：

  10.1063/1.1673285

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D2, 3.12.1, page 79 - 80
  作者：

  DOI：——

  日期：——
• Drys, Andrzej; Ratajczak, Emil, Bulletin of the Polish Academy of Sciences: Chemistry, 1987, vol. 35, # 11-12, p. 569 - 575
  作者：Drys, Andrzej、Ratajczak, Emil

  DOI：——

  日期：——
• Matrix‐Isolation Studies of the Infrared Spectra of the Free Radicals CCl₃ and CBr₃
  作者：Ernest E. Rogers、Stanley Abramowitz、Marilyn E. Jacox、Dolphus E. Milligan

  DOI：10.1063/1.1673285

  日期：1970.3

  CCl3 has been stabilized both by the reaction of lithium atoms with CCl4 in an argon matrix at 20°K and by the vacuum-ultraviolet photolysis of HCCl3 or of DCCl3 in an argon or a nitrogen matrix at 14°K. The analogous techniques have been found to lead to the stabilization of CBr3. The product spectra obtained in the lithium-atom experiments are considerably simpler than those obtained in the previous studies of the reaction of lithium atoms with matrix-isolated CX4. In the vacuum-ultraviolet photolysis experiments, DCCl2, HCBr2, and CBr2 have also been observed. The absorption frequencies and contours obtained for ν3 of CCl3 and of CBr3 are independent of the method used to produce these species, suggesting that lithium atoms and their reaction products do not appreciably perturb the degenerate stretching mode of either CCl3 or CBr3. Despite yields of these species comparable to those previously reported, absorptions at 674 and at 582 cm−1, previously attributed to ν1 of CCl3 and CBr3, respectively, are completely missing from the present experiments. No other absorption attributable to ν1 of either species has been detected. It is concluded that a pyramidal (C3υ) structure for CCl3 and for CBr3 has not been established.
• Reaction of hydrogen atoms with halogeno-methanes. Part 3.—Chloroform deuterochloroform and bromodichloromethane
  作者：D. T. Clark、J. M. Tedder

  DOI：10.1039/tf9666200405

  日期：——