3,6-bis(5-bromofuran-2-yl)-2,5-didodecylpyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione | 1350611-50-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 3,6-bis(5-bromofuran-2-yl)-2,5-didodecylpyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
• 英文别名: 1,4-Bis(5-bromofuran-2-yl)-2,5-didodecylpyrrolo[3,4-c]pyrrole-3,6-dione
• CAS: 1350611-50-5
• 化学式: C₃₈H₅₄Br₂N₂O₄
• 分子量: 762.666
• InChiKey: VVKAJOCNJFGBRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  46
• 可旋转键数：
  24
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  66.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-氰基呋喃 在 N-溴代丁二酰亚胺(NBS) 、 2-甲基-2-丁醇 、 sodium 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 5.33h， 生成 3,6-bis(5-bromofuran-2-yl)-2,5-didodecylpyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
  参考文献：
  名称：

  Side-Chain Tunability of Furan-Containing Low-Band-Gap Polymers Provides Control of Structural Order in Efficient Solar Cells

  摘要：

  The solution-processability of conjugated polymers in organic solvents has classically been achieved by modulating the size and branching of alkyl substituents appended to the backbone. However, these substituents impact structural order and charge transport properties in thin-film devices. As a result, a trade-off must be found between material solubility and insulating alkyl content. It was recently shown that the substitution of furan for thiophene in the backbone of the polymer PDPP2FT significantly improves polymer solubility, allowing for the use of shorter branched side chains while maintaining high device efficiency. In this report, we use PDPP2FT to demonstrate that linear alkyl side chains can be used to promote thin-film nanostructural order. In particular, linear side chains are shown to shorten pi-pi stacking distances between backbones and increase the correlation lengths of both pi-pi stacking and lamellar spacing, leading to a substantial increase in the efficiency of bulk heterojunction solar cells.

  DOI：

  10.1021/ja2089662

文献信息

• Benzo[1,2-b:4,5-b′]difuran and furan substituted diketopyrrolopyrrole alternating copolymer for organic photovoltaics with high fill factor
  作者：Jia Du、Andria Fortney、Katherine E. Washington、Michael C. Biewer、Tomasz Kowalewski、Mihaela C. Stefan

  DOI：10.1039/c7ta04618a

  日期：——

  comparison to the conjugated polymers synthesized from thiophene or thiophene derivatives, furan and its derivatives are promising alternative building units due to their desirable properties such as smaller heteroatom size, more electronegative heteroatom, and larger dipole moment. Considering the advantages of furan units, conjugated polymers synthesized from furan and its derivatives show a higher degree

  与由噻吩或噻吩衍生物合成的共轭聚合物相比，呋喃及其衍生物因其所需的特性（例如较小的杂原子尺寸，较大的负电性杂原子和较大的偶极矩）而成为有前途的替代建筑单元。考虑到呋喃单元的优点，由呋喃及其衍生物合成的共轭聚合物显示出更高的共轭度，相邻单元之间的扭曲减少，π堆积距离更小，溶解度得到改善。迄今为止，尽管对由呋喃衍生物构成的聚合物的研究受到关注，但仅由呋喃或其衍生物构成的共轭聚合物仍然很少。在这里，我们报道了一种新的共轭聚合物，聚（4,8-双（5-（2-（乙基乙基己基）呋喃-2-基）苯并[1,2- b：4,5- b′] difuran - alt -2,5-didodecyl-3,6-di（furan-2-yl）pyrrolo [3,4- c ] pyrrole-1,4（2 H，5 H）-dione），P（BDF-FDPP），用于有机太阳能电池。P（BDF-FDPP）呋喃中的氧原子较小，导致平面共轭骨架具有较小的扭转强度（二面角<0
• Furan Conjugated Polymers Useful for Photovoltaic Applications
  申请人：Beaujuge Pierre M.

  公开号：US20120085992A1

  公开（公告）日：2012-04-12

  The present invention provides for a polymer comprising a π-conjugated backbone comprising a furan. The polymer has a narrow or low band gap and/or is solution processable. In some embodiments, the polymer is PDPP2FT or PDPP3F. The present invention also provides for a device comprising the polymer, such as a light-emitting diode, thin-film transistor, chemical biosensor, non-emissive electrochromic, memory device, photovoltaic cells, or the like.

  本发明提供了一种聚合物，其包括一个π-共轭骨架，其中包括呋喃。该聚合物具有窄或低带隙和/或可溶解性。在某些实施例中，该聚合物是PDPP2FT或PDPP3F。本发明还提供了一种包括该聚合物的器件，例如发光二极管、薄膜晶体管、化学生物传感器、非发光电致变色、记忆器件、光伏电池等。
• DIKETOPYRROLOPYRROLE POLYMERS FOR USE IN ORGANIC SEMICONDUCTOR DEVICES
  申请人：BASF SE

  公开号：EP2571919B1

  公开（公告）日：2018-07-11
• Dyketopyrrolopyrrole polymers for use in organic semiconductor devices
  申请人：Hayoz Pascal

  公开号：US20110284826A1

  公开（公告）日：2011-11-24

  The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula or a polymer of formula and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
• US9221943B2
  申请人：——

  公开号：US9221943B2

  公开（公告）日：2015-12-29