4-chloro-2-fluoro-5-isopropyloxyphenyl isocyanate | 85113-29-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-chloro-2-fluoro-5-isopropyloxyphenyl isocyanate
• 英文别名: 4-chloro-2-fluoro-5-isopropoxy-phenyl isocyanate；2-fluoro-4-chloro-5-isopropyloxy-phenylisocyanate；4-chloro-2-fluoro-5-isopropyloxyphenylisocyanate；2-fluoro-4-chloro-5-isopropoxyphenyl isocyanate；4-chloro-2-fluoro-5-isopropoxyphenyl isocyanate；2-fluoro-4-chloro-5-isopropoxyphenylisocyanate；1-chloro-5-fluoro-4-isocyanato-2-propan-2-yloxybenzene
• CAS: 85113-29-7
• 化学式: C₁₀H₉ClFNO₂
• 分子量: 229.638
• InChiKey: PZPMUYOAILKKIF-UHFFFAOYSA-N

物化性质

• 沸点：
  299.0±40.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-chloro-2-fluoro-5-isopropyloxyphenyl isocyanate 以 N-甲基乙酰胺 为溶剂， 生成 ethyl 2-ethyl-3-[3-(4-chloro-2-fluoro-5-isopropoxyphenyl)ureido]-crotonate
  参考文献：
  名称：

  3-Aryluracils having an ether (thio) carbomyloxy or sulphomyloxy

  摘要：

  这项发明涉及式子##STR1##中的3-芳基尿嘧啶，其中R.sup.1、R.sup.2、R.sup.3、R.sup.4、R.sup.5和R.sup.6如本文所述，以及它们的盐及其制备方法，含有这些化合物作为活性物质的除草剂组合物以及利用这些活性物质或组合物进行除草的用途。该发明还涉及具有除草活性的起始材料和含有这些起始材料的除草剂组合物。

  公开号：

  US04859229A1
• 作为产物：
  描述：

  光气 、 4-氯-2-氟-5-(1-甲基乙氧基)-苯胺 以 甲苯 为溶剂， 生成 4-chloro-2-fluoro-5-isopropyloxyphenyl isocyanate
  参考文献：
  名称：

  4-(2-Fluoro-4-halo-5-substituted phenyl)urazols, and their production

  摘要：

  一种化学式为：##STR1##的缩聚苯基脲，其中X为氯原子或溴原子，Y和Z分别为氧原子或硫原子，R为C.sub.1 -C.sub.3烷基，烯丙基或丙炔基，n为4或5的整数，可用作除草剂。

  公开号：

  US04452981A1

文献信息

• Diaryl ethers and processes for their preparation and herbicidal and
  申请人：Ishihara Sangyo Kaisha, Ltd.

  公开号：US06121201A1

  公开（公告）日：2000-09-19

  A compound represented by the formula (I) or its salt and herbicidal and desiccant use thereof: ##STR1## wherein X, Y are independently hydrogen, halogen, cyano, nitro, or (C.sub.1-6)haloalkyl; Z is oxygen or sulfur; and Q is ##STR2##

  化合物的化学式（I）或其盐及其除草剂和脱水剂用途：##STR1##其中X，Y分别是氢，卤素，氰基，硝基或（C.sub.1-6）卤代烷基；Z是氧或硫；Q是##STR2##
• Diaryl ethers and processes for their preparation and herbicidal and desiccant compositions containing them
  申请人：ISK Americas Incorporated

  公开号：US06333296B1

  公开（公告）日：2001-12-25

  Diaryl ether compounds useful in the control of weeds are described. An exemplary compound is represented by the general formula (I): In this formula Q is represented by Q9: X and Y represent a hydrogen atom, halogen atom, cyano group, nitro group or (C1-6)haloalkyl group. A1 and A2 are independently oxygen or sulfur atoms. R9 and R10 represent a hydrogen atom, a (C1-6)alkyl group, an acyl group, or a (C1-6)alkylsulfonyl group; or R9 and R10 may form a ring consisting of polymethylene, (CH2)m groups, where m is an integer of 2, 3, 4 or 5, together with the nitrogen atom of NR9R10, which may or may not have a (C1-6)alkyl substituent. Methods of making the compounds are also described.

  描述了在除草中有用的二芳醚化合物。一个示例化合物由通用式(I)表示： 在这个式子中，Q由Q9表示： X和Y代表氢原子、卤原子、氰基、硝基或(C1-6)卤代烷基。A1和A2独立地表示氧或硫原子。R9和R10代表氢原子、(C1-6)烷基、酰基或(C1-6)烷基磺酰基；或者R9和R10可以形成由聚亚甲基(CH2)m基团组成的环，其中m是2、3、4或5的整数，与NR9R10的氮原子一起，该氮原子可能具有或不具有(C1-6)烷基取代基。还描述了制备这些化合物的方法。
• Arylaminocarbonyl compounds
  申请人：Sandoz Ltd.

  公开号：US05362706A1

  公开（公告）日：1994-11-08

  Hydantoin for the control of weeds are disclosed.

  已披露用于控制杂草的咪唑啉。
• Herbicidal heterocyclic compounds
  申请人：Hoffmann-La Roche Inc.

  公开号：US04812164A1

  公开（公告）日：1989-03-14

  The invention is concerned with novel C.sub.1-4 -alkyl, C.sub.2-4 -alkenyl and C.sub.3 or 4 -alkynyl enol ethers of 3-aryluracils of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and X are as defined in the specification, their manufacture, weed control compositions which contain such enol ethers as the active substance and the use of the active substances or compositions for the control of weeds. The invention is also concerned with certain novel intermediates, some of which possess herbicidal activity, and with weed control compositions containing such active substances.

  这项发明涉及新颖的3-芳基尿嘧啶的C.sub.1-4-烷基，C.sub.2-4-烯基和C.sub.3或4-炔基烯醇醚，其化学式如下所示：其中R.sup.1，R.sup.2，R.sup.3，R.sup.4，R.sup.5和X如规范中定义，它们的制造，含有这种烯醇醚作为活性物质的除草剂组合物，以及利用这些活性物质或组合物来控制杂草。该发明还涉及某些新颖的中间体，其中一些具有除草活性，并且含有这种活性物质的除草剂组合物。
• 4-imino-oxazolidine-2-one derivatives, a process for producing such
  申请人：Sagami Chemical Research Center

  公开号：US05612289A1

  公开（公告）日：1997-03-18

  The invention relates to 4-imino-oxazolidine-2-one derivatives represented by the general formula (1): ##STR1## and a process for producing said compounds by reacting aryl isocyanates of the general formula (2): ##STR2## with methacrolein cyanohydrin in the presence of a base, as well as a herbicide containing said compounds as an active ingredient; it also relates to a process for producing oxazolidinedione derivatives useful as herbicides by hydrolyzing said compounds.

  本发明涉及通式(1)表示的4-亚氨基-噁唑烷-2-酮衍生物：##STR1##以及通过在碱的存在下，使通式(2)表示的芳基异氰酸酯：##STR2##与甲基丙烯醛氰醇反应来制备所述化合物的方法，以及含有所述化合物作为活性成分的除草剂；还涉及通过水解所述化合物来制备作为除草剂有用的噁唑烷二酮衍生物的方法。