trans-1-chloro-4-methylammonio-2-butene chloride | 60347-24-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trans-1-chloro-4-methylammonio-2-butene chloride
• 英文别名: (4-chloro-but-2-enyl)-trimethyl-ammonium; (4-chloro-but-2ξ-enyl)-trimethyl-ammonium chloride；(4-Chlor-but-2-enyl)-trimethyl-ammonium; (4-Chlor-but-2ξ-enyl)-trimethyl-ammonium-chlorid；4-chloro-2-butenyltrimethylammonium chloride；(4-Chloro-2-butenyl)trimethylammonium chloride；[(E)-4-chlorobut-2-enyl]-trimethylazanium;chloride
• CAS: 60347-24-2
• 化学式: C₇H₁₅ClN*Cl
• 分子量: 184.109
• InChiKey: ZMSLJULQLLRFMB-FXRZFVDSSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.51
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  反式-1,4-二氯-2-丁烯 、 三甲胺 以 四氢呋喃 为溶剂， 反应 6.0h， 以95%的产率得到trans-1-chloro-4-methylammonio-2-butene chloride
  参考文献：
  名称：

  Facile Synthesis of (ω-Bromoalkyl)trimethylammonium Bromides

  摘要：

  Reaction of a I,omega-dibromoalkane with trimethylamine in THF at room temperature precipitates the corresponding (omega-bromoalkyl)trimethylammonium bromide to cleanly form the mono-substituted product in the absence of the bis-quat salt.

  DOI：

  10.1080/00397919908086244

文献信息

• Preparation of a cationic starch paste
  申请人：GRAIN PROCESSING CORPORATION

  公开号：EP0004774A2

  公开（公告）日：1979-10-17

  A process for preparing a cationic starch dispersion wherein an alkaline, gelatinized starch is reacted with a cationic reagent (e.g. a tertiary amine salt) either concurrently with, or subsequently to, the cooking (gelling) process resulting in a product in which the cationic reagent is chemically bound to the starch molecule. The process is conducive to the on-site preparation of the cationic starch and can be utilized without additional treatment as a papermaking adjunct, textile size, waste-water treatment or tailings flocculent.

  一种制备阳离子淀粉分散液的工艺，其中碱性糊化淀粉与阳离子试剂（如叔胺盐）在蒸煮（胶凝）过程中同时或随后发生反应，得到阳离子试剂与淀粉分子化学结合的产品。该工艺有利于现场制备阳离子淀粉，无需额外处理即可用作造纸辅料、纺织品粒度、废水处理或尾矿絮凝剂。
• Method of improving the soil anti-redeposition properties of washing detergents
  申请人：PROTEIN TECHNOLOGIES INTERNATIONAL, INC.

  公开号：EP0455468A2

  公开（公告）日：1991-11-06

  A detergent composition has its soil anti-redeposition properties significantly improved by incorporating into it an effective amount of an anti-redeposition agent. The anti-redeposition agent is a modified vegetable protein material such as a soy protein isolate which has been modified by reaction with an ionic monomer, such as cationic epoxide monomers, cationic acrylate monomers, cationic chlorohydrin monomers, as well as anionic or carboxylated soy protein derivatives.

  在一种洗涤剂组合物中加入有效量的抗再沉积剂，可明显改善其抗土壤再沉积性能。抗再沉积剂是一种改性植物蛋白材料，如大豆分离蛋白，它是通过与离子单体（如阳离子环氧单体、阳离子丙烯酸酯单体、阳离子氯醇单体以及阴离子或羧化大豆蛋白衍生物）反应而改性的。
• Method of papermaking using crosslinked cationic/amphoteric starches
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0603727A1

  公开（公告）日：1994-06-29

  A method of making paper in an alkaline or acid system wherein a selected crosslinked, cationized or amphoteric starch is added to the system, said starch being crosslinked by adding enough crosslinking agent to provide a starch having a breakdown viscosity of from about 2 to 85% and wherein the crosslinked, cationized or amphoteric starch is jet cooked under super atmospheric pressure at a temperature of from about 195 to 325°F.

  一种在碱性或酸性体系中造纸的方法，其中在该体系中加入选定的交联、阳离子化或两性淀粉，所述淀粉通过加入足够的交联剂进行交联，以提供一种分解粘度约为 2% 至 85% 的淀粉，交联、阳离子化或两性淀粉在超大气压下在约 195 至 325°F 的温度下喷射蒸煮。
• Nonionically derivatized starches and their use in low voc, polyacrylic acid-containing hair fixative compositions
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0948959A2

  公开（公告）日：1999-10-13

  The present invention is directed to a low VOC, non-aerosol, polyacrylic acid containing hair cosmetic compositions which contain nonionically derivatized starches, particularly those derivatized by alkylene oxides. The derivatized starch may be hydrolyzed, particularly enzymatically hydrolyzed by at least one endo-enzyme. In addition, the starch may be cationically modified with a low degree of substitution. Use of such starches is novel and advantageous in that they are compatible with polyacrylic acid, providing a clear, solution with a stable viscosity. Further, the resultant composition provides a clear film which is not tacky, good stiffness, and improved humidity resistance.

  本发明涉及一种低挥发性有机化合物（VOC）、无气溶胶、含聚丙烯酸的护发化妆品组合物，该组合物含有非离子衍生化淀粉，特别是那些由亚烷基氧化物衍生化的淀粉。衍生化淀粉可以水解，特别是通过至少一种内切酶进行酶水解。此外，淀粉还可以进行低取代度的阳离子改性。使用这种淀粉的新颖性和优点在于它们与聚丙烯酸相容，可提供粘度稳定的透明溶液。此外，由此产生的组合物还能提供不粘手的透明薄膜、良好的挺度和更好的防潮性能。
• Non-ionically derivatized starches and their use in aerosol hair fixative compositions
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0948958A2

  公开（公告）日：1999-10-13

  The present invention is directed to low volatile organic compound aerosol hair cosmetic compositions which contain nonionically derivatized starches optionally hydrolyzed and/or ionically modified. Such compositions provide a clear solution with a low viscosity, good spray characteristics, a clear, non-tacky film, good stiffness, and improved humidity resistance.

  本发明涉及低挥发性有机化合物气溶胶护发化妆品组合物，该组合物含有可选水解和/或离子改性的非离子衍生化淀粉。这种组合物可提供粘度低、喷雾特性好、薄膜透明、不粘腻、挺度好和防潮性能更好的透明溶液。