N,N'-(Benzene-1,3-diyldimethanediyl)bis(12-hydroxyoctadecanamide) | 128554-52-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N,N'-(Benzene-1,3-diyldimethanediyl)bis(12-hydroxyoctadecanamide)
• 英文别名: 12-hydroxy-N-[[3-[(12-hydroxyoctadecanoylamino)methyl]phenyl]methyl]octadecanamide
• CAS: 128554-52-9
• 化学式: C₄₄H₈₀N₂O₄
• 分子量: 701.1
• InChiKey: NOWNHFCLWUPOCO-UHFFFAOYSA-N

物化性质

• 沸点：
  885℃[at 101 325 Pa]
• 密度：
  1.04[at 20℃]
• LogP：
  6.5 at 30℃

计算性质

• 辛醇/水分配系数(LogP)：
  13.2
• 重原子数：
  50
• 可旋转键数：
  36
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  4

文献信息

• Pulverulent ink and printing methods
  申请人：KAO CORPORATION

  公开号：EP0472106A2

  公开（公告）日：1992-02-26

  A pulverulent ink comprising in the structure a heat-fusible core comprising a thermo-melting substance and a coloring matter and a shell covering the core on the surface and comprising a resin product obtainable by reacting: (1) 0 to 30 mole % of a monovalent isocyanate compound and/or a monovalent isothiocyanate compound and (2) 100 to 70 mole % of a divalent isocyanate and/or a divalent isothiocyanate compound with (3) 0 to 30 mole % of a compound having an active hydrogen atom to react with the isocyanate and isothiocyanate groups of (1) and (2) and (4) 100 to 70 mole % of a compound having two active hydrogen atoms to react with the isocyanate and isothiocyanate groups of (1) and (2); at a molar ratio of (1) and (2) to (3) and (4) in the range between 1:1 and 1:20, at least 30 percent of all the linkages involved in the isocyanates and the isothiocyanates in the resin product being thermally dissociating. The powder ink is advantageously used in a method for printing an image on a substrate, which comprises forming an image by a thermally transferring printing method and reproducing an ink sheet with electrostatic energy.

  一种粉状油墨，其结构包括一个由热熔物质和着色物质组成的热熔芯体，以及一个表面覆盖芯体并由可通过反应获得的树脂产品组成的外壳： (1) 0 至 30 摩尔%的一价异氰酸酯化合物和/或一价异硫氰酸盐化合物和 (2) 100 至 70 摩尔%的二价异氰酸酯和/或二价异硫氰酸酯化合物与 (3) 0 至 30 摩尔%的具有活性氢原子的化合物，可与(1)和(2)中的异氰酸酯和异硫氰 酸酯基团反应，以及 (4) 100 至 70 摩尔%的具有两个活性氢原子的化合物，与(1)和(2)的异氰酸酯和异硫氰酸 酯基团发生反应；(1)和(2)与(3)和(4)的摩尔比在 1:1 至 1:20 之间，树脂产品中异氰酸酯和异硫氰酸 酯所涉及的所有连接中至少有 30%是热解离的。粉末墨水可用于在基材上印刷图像的方法，该方法包括通过热转印印刷方法形成图像，并利用静电能量复制墨片。
• BIODEGRADABLE RESIN COMPOSITION
  申请人：KAO CORPORATION

  公开号：EP1746136A1

  公开（公告）日：2007-01-24

  The present invention relates to a method of producing a biodegradable resin composition, which includes step (1) of mixing a biodegradable resin, a plasticizer, and a crystal nucleating agent with one another at the melting point (Tm) of the biodegradable resin or more, wherein the crystal nucleating agent is an aliphatic compound having, in its molecule, two or more of at least one group selected from an ester group, a hydroxyl group and an amide group, and step (2) of thermally treating the resulting biodegradable resin composition at a temperature of from the glass transition temperature (Tg) to less than Tm of the composition, as well as a biodegradable resin composition, which contains a biodegradable resin, a plasticizer, and the above crystal nucleating agent, and which satisfies the following conditions: the haze thereof with a thickness of 0.5 mm after thermal treatment at 60°C for 36 or 60 hours is 20% or less; the storage elastic modulus (E') at a temperature of 25°C and a frequency of 50 Hz is 1 × 108 to 2 × 109 Pa; and the storage elastic modulus (E') at a temperature of 60°C and a frequency of 50 Hz is 1 × 107 to 1 × 109 Pa.

  本发明涉及一种生产可生物降解树脂组合物的方法，该方法包括步骤(1)在可生物降解树脂的熔点(Tm)或更高的温度下将可生物降解树脂、增塑剂和晶核剂相互混合，其中晶核剂是一种脂肪族化合物，在其分子中至少有两个或更多的基团，这些基团选自酯基，羟基和酰胺基；以及步骤(2)在组合物的玻璃化温度(Tg)至低于Tm的温度下对所得到的可生物降解树脂组合物进行热处理、步骤(2)在该组合物的玻璃化温度（Tg）至低于 Tm 的温度下热处理得到的可生物降解树脂组合物，以及可生物降解树脂组合物，该组合物包含可生物降解树脂、增塑剂和上述晶核剂，并满足以下条件：在 60°C 热处理后，其雾度厚度为 0.5 mm 的雾度为 20% 或更小；在温度为 25°C 和频率为 50 Hz 时，储存弹性模量（E'）为 1 × 108 至 2 × 109 Pa；在温度为 60°C 和频率为 50 Hz 时，储存弹性模量（E'）为 1 × 107 至 1 × 109 Pa。
• POLYLACTIC ACID RESIN MULTILAYER SHEET AND MOLDED BODY MADE OF SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1942001A1

  公开（公告）日：2008-07-09

  The polylactic acid-based resin laminate sheet of the present invention is a laminate sheet comprising Layer A and Layer B of a polylactic acid-based resin composition, and said Layer A and said Layer B contain poly(meth)acrylate in a specified amount. The present invention is excellent in transparency and heat resistance, and, in addition, provides a polylactic acid-based resin laminate sheet capable of obtaining a molded product of high biobased content therefrom.

  本发明的聚乳酸基树脂层压板是由聚乳酸基树脂组合物的层 A 和层 B 组成的层压板，所述层 A 和所述层 B 含有规定量的聚(甲基)丙烯酸酯。本发明具有出色的透明度和耐热性，此外，还提供了一种能够从中获得生物基含量高的成型产品的聚乳酸基树脂层压板。
• POLYLACTIC ACID RESIN COMPOSITION, MOLDED BODY THEREOF AND POLYLACTIC ACID COMPOUND
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2050789A1

  公开（公告）日：2009-04-22

  An object of the present invention is to provide a resin composition having increased heat resistance (high crystallinity) and transparency without impairing rigidity which a polylactic acid resin inherently has, a molded article composed of the resin composition and a novel polylactic acid compound used in the resin composition. A polylactic acid resin composition of the present invention contains a linear polylactic acid compound (A) having a moiety represented by the formula (1): -X1-R1-X2- and having a weight average molecular weight (Mw) of 5,000 to 500,000. In addition, in the formula (1), X1 and X2 each independently represent an oxygen atom, a sulfur atom or an NH group, R1 represents a divalent group containing at least one aromatic group or aliphatic group, and the hydrocarbon group may contain an oxygen atom, a nitrogen atom or a sulfur atom.

  本发明的目的是提供一种树脂组合物，该树脂组合物具有更高的耐热性（高结晶度）和透明性，同时不损害聚乳酸树脂固有的刚性，还提供一种由该树脂组合物和用于该树脂组合物的新型聚乳酸化合物组成的模塑制品。本发明的一种聚乳酸树脂组合物含有线性聚乳酸化合物（A），其分子式为（1）：-X1-R1-X2-，其重量平均分子量（Mw）为 5,000 至 500,000。此外，在式 (1) 中，X1 和 X2 各自独立地代表氧原子、硫原子或 NH 基团，R1 代表含有至少一个芳香族基团或脂肪族基团的二价基团，烃基可能含有氧原子、氮原子或硫原子。
• POLYLACTIC ACID RESIN COMPOSITION AND MOLDED BODY THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2045293A1

  公开（公告）日：2009-04-08

  An object of the present invention is to provide a resin composition having improved heat resistance (high crystallinity) and transparency without impairing rigidity which a polylactic acid resin inherently has, and a molded article composed of the resin composition. A polylactic acid resin composition of the present invention contains 100 parts by weight of a polylactic acid compound (A) having a specific moiety represented by the formula (1): -X1-R1-X2- and having a weight average molecular weight (Mw) of 5,000 to 500,000, 5 to 2,000 parts by weight of a lactic acid resin (B) and 0.1 to 10 parts by weight of at least one kind of a transparent nucleating agent (C) selected from carboxylic acid amides, aliphatic alcohols and aliphatic carboxylic acid esters. In the formula (1), X1 and X2 each independently represent an oxygen atom, a sulfur atom or an NH group, R1 represents an aliphatic hydrocarbon group having a weight average molecular weight of 25 to 50, 000 without containing a ring structure, and the hydrocarbon group may contain an oxygen atom, a nitrogen atom or a sulfur atom.

  本发明的目的是提供一种树脂组合物，该树脂组合物具有更好的耐热性（高结晶度）和透明性，同时不损害聚乳酸树脂固有的刚性，以及由该树脂组合物组成的模塑制品。本发明的聚乳酸树脂组合物含有 100 重量份的聚乳酸化合物 (A)，该化合物具有由式 (1) 表示的特定分子：-X1-R1-X2-且重量平均分子量（Mw）为 5,000 至 500,000 的聚乳酸化合物（A）、5 至 2,000 重量份的乳酸树脂（B）和 0.1 至 10 重量份的至少一种透明成核剂（C），透明成核剂选自羧酸酰胺、脂肪醇和脂肪族羧酸酯。在式 (1) 中，X1 和 X2 各自独立地代表一个氧原子、一个硫原子或一个 NH 基团，R1 代表一个重量平均分子量为 25 至 50,000 且不含环状结构的脂肪族烃基，该烃基可包含一个氧原子、一个氮原子或一个硫原子。