Bis(2,3,5,6-Tetrafluoro-4-aminophenyl) sulphide | 61907-46-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Bis(2,3,5,6-Tetrafluoro-4-aminophenyl) sulphide
• 英文别名: 4,4'-diamino-octafluorodiphenyl sulfide；bis(4-aminotetrafluorophenyl)sulfane；Bis-<4-amino-2,3,5,6-tetrafluorphenyl>-sulfid；Bis-(4-amino-2,3,5,6-tetrafluorphenyl)-sulfid；4,4'-Sulfanediylbis(tetrafluoroaniline)；4-(4-amino-2,3,5,6-tetrafluorophenyl)sulfanyl-2,3,5,6-tetrafluoroaniline
• CAS: 61907-46-8
• 化学式: C₁₂H₄F₈N₂S
• 分子量: 360.23
• InChiKey: JDVKYLFCIUDDIA-UHFFFAOYSA-N

物化性质

• 沸点：
  295.8±40.0 °C(Predicted)
• 密度：
  1.73±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  2
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  Bis(2,3,5,6-Tetrafluoro-4-aminophenyl) sulphide 在 sodium perborate 、 三氟乙酸 作用下， 反应 24.0h， 以60%的产率得到4,4'-diamino-octafluorodiphenyl sulphone
  参考文献：
  名称：

  氨苯砜体内和体外结构类似物的血液学毒性研究。

  摘要：

  使用由单个人肝制备的微粒体，4,4'-二氨基二苯砜（DDS），4-乙酰基-4-氨基二苯砜（MADDS），4-乙酰基-4-氨基二苯硫醚（MADDT）和4,4'-二乙酰基二苯基与对照相比，硫醚（DADDT）引起的血红蛋白高得多。在大鼠体外，毒性模式略有不同：DADDT无血液毒性，而3,4'-二氨基二苯砜（3,4'DDS）和3,3'-二氨基二苯砜（3,3'DDS）以及DDS，MADDS和MADDT均明显大于对照。4,4'乙酰基二苯砜（DADDS），4,4'二氨基二苯硫醚（DDT），4,4'-二氨基二苯醚（DDE）和4,4'二氨基八氟二苯砜（F8DDS）在人或人中均未引起明显的血红蛋白血症大鼠肝微粒体。DDS，MADDS，在存在人类微粒体的情况下，体外血液生成的毒性与MADDT和MADDT没有显着差异。在体外大鼠中，DDS，MADDS和3,4'DDS在红细胞毒性方面无显着差异，并且是最有效的血红蛋白前体。与DDS相比，3

  DOI：

  10.1111/j.2042-7158.1991.tb03481.x
• 作为产物：
  描述：

  氯五氟苯 在 copper powder 、 NH₃ 作用下， 生成 Bis(2,3,5,6-Tetrafluoro-4-aminophenyl) sulphide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.8, page 209 - 242

  摘要：

  DOI：

文献信息

• Fluorinated bis(phthalic anhydride) and method for producing the same
  申请人：Masuda Go

  公开号：US20050020839A1

  公开（公告）日：2005-01-27

  It is an object of the present invention to provide fluorinated bis(phthalic anhydride) which has less coloration and higher solubility in comparison with conventional compounds, and a method for producing the same. Further, it is also an object of the present invention to provide a method for producing a fluorinated bis(phthalonitrile) compound, which is an intermediate raw material compound of the method for producing the fluorinated bis(phthalic anhydride), and a polyamic acid and a polyimide, which are produced from the fluorinated bis(phthalic anhydride). A fluorinated bis(phthalic anhydride) of the present invention is the fluorinated bis(phthalic anhydride) represented by the following formula (I 1 ), wherein its specific surface area is 3.0 m 2 /g or larger. It is also characterized in that its molar absorption coefficient is 0.6 L/mol·cm or less at a wavelength of 360 nm. [wherein, m and n independently represent integers of 1 to 3, and Z 1 represents a single bond group or a bivalent organic group.]

  本发明的目的是提供具有比传统化合物更少着色和更高溶解性的氟化双(邻苯二甲酸酐)以及其生产方法。此外，本发明还旨在提供一种用于生产氟化双(邻苯二腈)化合物的方法，该化合物是生产氟化双(邻苯二甲酸酐)的中间原料化合物，并且提供由氟化双(邻苯二甲酸酐)生产的聚酰胺酸和聚酰亚胺的方法。本发明的氟化双(邻苯二甲酸酐)是由以下式(I1)表示的氟化双(邻苯二甲酸酐)，其中其比表面积为3.0 m2/g或更大。其特征在于，在360 nm波长处，其摩尔吸光系数不超过0.6 L/mol·cm。【其中，m和n独立表示1到3的整数，Z1表示单键基团或二价有机基团。】
• Perfluorinated polyimide, perfluorinated poly(amic acid), starting compounds therefor, and methods for preparing them
  申请人：NIPPON TELEGRAPH AND TELEPHONE CORPORATION

  公开号：EP0480266A2

  公开（公告）日：1992-04-15

  A perfluorinated polyimide having a repeating unit represented by general formula (1): and a perfluorinated poly(amic acid) having a repeating unit represented by general formula (6): wherein R1 is a tetravalent organic group; and R2 is a divalent organic group, provided that chemical bonds between carbon atoms and monovalent elements contained in R1 and R2 are exclusively carbon-to-fluorine bonds; methods for preparing them; and an optical material including the perfluorinated polyimide. 1,4-Bis(3,4-dicarboxytrifluorophenoxy)tetrafluorobenzene dianhydride, 1,4-difluoropyromellitic anhydride, 1,4-bis(3,4-dicar- boxytrifluorophenoxy)tetrafluorobenzene, 1,4-difluoro-pyromellitic acid, and 1,4-bis(3,4-dicyanotrifluorophenoxy)-tetrafluorobenzene as well as methods preparing them. The perfluorinated polyimide has a thermal stability and has a low optical loss in an optical communication wavelength region (1.0 to 1.7 mm).

  一种全氟聚酰亚胺，其重复单元由通式(1)表示： 和具有通式（6）代表的重复单元的全氟聚（胺）： 其中 R1 是四价有机基团；R2 是二价有机基团，条件是 R1 和 R2 所含碳原子和一价元素之间的化学键完全是碳氟键；制备它们的方法；以及包括全氟聚酰亚胺的光学材料。1,4-双(3,4-二羧基三氟苯氧基)四氟苯二酸酐、1,4-二氟苯甲酸酐、1,4-双(3,4-二羧基三氟苯氧基)四氟苯、1,4-双(3,4-二氰基三氟苯氧基)四氟苯以及制备它们的方法。全氟聚酰亚胺具有热稳定性，在光通信波长区域（1.0 至 1.7 毫米）的光学损耗较低。
• Optical waveplate, method of manufacturing the same, and waveguide device using the same
  申请人：NIPPON TELEGRAPH AND TELEPHONE CORPORATION

  公开号：EP0623830A1

  公开（公告）日：1994-11-09

  An optical waveplate includes a polyimide with a film thickness of 20 µm or less.

  光波板包括薄膜厚度为 20 微米或更薄的聚酰亚胺。
• Waveguide device and method for production thereof
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0720030A1

  公开（公告）日：1996-07-03

  A waveguide device comprising at least a waveguiding layer, a cladding layer and, optionally, an adhesion-enhancing layer is disclosed. By using specific fluorinated polyimides as materials for each of the layers of the waveguide device, the process for producing the waveguide device is simplified, the production cost is reduced, and the flexibility is imparted to the waveguide device, which are not achieved in a quartz-type waveguide. Also, a single mode, a low loss at 1.3 micron band and a high moisture-resistance which are not achieved by conventional plastic-type waveguide are possible.

  本发明公开了一种波导装置，该装置至少包括一个波导层、一个包层和一个附着力增强层。通过使用特定的氟化聚酰亚胺作为波导器件各层的材料，简化了波导器件的生产工艺，降低了生产成本，并赋予了波导器件石英型波导无法实现的灵活性。此外，还可以实现传统塑料型波导无法实现的单模、1.3 微米波段的低损耗和高防潮性。
• BIS (FLUORINE-CONTAINING PHTHALIC ANHYDRIDE) AND METHOD FOR PRODUCTION THEREOF
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1640370A1

  公开（公告）日：2006-03-29

  It is an object of the present invention to provide fluorinated bis(phthalic anhydride) which has less coloration and higher solubility in comparison with conventional compounds, and a method for producing the same. Further, it is also an object of the present invention to provide a method for producing a fluorinated bis(phthalonitrile) compound, which is an intermediate raw material compound of the method for producing the fluorinated bis(phthalic anhydride), and a polyamic acid and a polyimide, which are produced from the fluorinated bis(phthalic anhydride). A fluorinated bis(phthalic anhydride) of the present invention is the fluorinated bis(phthalic anhydride) represented by the following formula (I1), wherein its specific surface area is 3.0 m2/g or larger. It is also characterized in that its molar absorption coefficient is 0.6 L/mol-cm or less at a wavelength of 360 nm. [wherein, m and n independently represent integers of 1 to 3, and Z1 represents a single bond group or a bivalent organic group.]

  本发明的目的是提供与传统化合物相比着色更少、溶解度更高的氟化双（邻苯二甲酸酐），以及生产这种化合物的方法。此外，本发明的另一个目的是提供一种氟化双（邻苯二甲酸酐）化合物的生产方法，该化合物是氟化双（邻苯二甲酸酐）生产方法的中间原料化合物，以及由氟化双（邻苯二甲酸酐）生产的聚酰胺和聚酰亚胺。本发明的氟化双（邻苯二甲酸酐）是由下式（I1）表示的氟化双（邻苯二甲酸酐），其中其比表面积为 3.0 m2/g 或更大。其特征还在于，在波长为 360 纳米时，其摩尔吸收系数为 0.6 L/mol-cm 或以下。 [其中，m 和 n 分别代表 1 至 3 的整数，Z1 代表单键基团或二价有机基团。］