1-phenyl-3,3-dipropyl-triazene | 36719-39-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-3,3-dipropyl-triazene
• 英文别名: 1-Phenyl-3,3-dipropyl-triazen；N-phenyldiazenyl-N-propylpropan-1-amine
• CAS: 36719-39-8
• 化学式: C₁₂H₁₉N₃
• 分子量: 205.303
• InChiKey: MHNQVULYVOWIIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  28
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2928000090

反应信息

• 作为反应物：
  描述：

  萘酚 、 1-phenyl-3,3-dipropyl-triazene 在 C₆H₉N₂O₂⁽¹⁺⁾*C₇H₇O₃S^(1-) 作用下， 以 水 为溶剂， 反应 4.0h， 以85%的产率得到(4E)-4-(phenylhydrazinylidene)naphthalen-1-one
  参考文献：
  名称：

  通过离子液体促进的CN键形成与芳基三氮烯绿色合成偶氮染料的环保方法

  摘要：

  通过布朗斯台德酸性离子液体（IL）促进的萘酚与芳基三氮烯的重氮偶合反应，已开发出一种高效且绿色的偶氮染料合成方法。反应在室温下在空气和无金属条件下，以芳基三氮烯为重氮化剂，以布朗斯台德酸性离子液体为促进剂，以水为绿色溶剂进行。值得注意的是，该方法的吸引人的优点包括温和的条件，优异的收率，简单的产物分离过程，大规模实验，药物的后期修饰和促进剂的可回收性。另外，在DMSO中研究了偶氮染料的紫外可见光谱特性。

  DOI：

  10.1016/j.dyepig.2018.05.073
• 作为产物：
  描述：

  偶氮苯六氟磷酸盐 、 二正丙胺 生成 1-phenyl-3,3-dipropyl-triazene
  参考文献：
  名称：

  1-Aryl-3,3-dialkyltriazenes as Tumor Inhibitors

  摘要：

  DOI：

  10.1021/jo01353a030

文献信息

• UNSATURATED CYCLIC ANHYDRIDE END CAPPED POLYIMIDES AND POLYAMIC ACIDS AND PHOTOSENSITIVE COMPOSITIONS THEREOF
  申请人：PROMERUS, LLC

  公开号：US20200283580A1

  公开（公告）日：2020-09-10

  Embodiments in accordance with the present invention encompass polyamic acid or polyimide polymers containing a reactive unsaturated cyclic anhydride end group as well as photosensitive compositions made therefrom which are useful for forming films that can be patterned to create structures for microelectronic devices, microelectronic packaging, microelectromechanical systems, optoelectronic devices and displays. In some embodiments the compositions of this invention are shown to feature excellent hitherto unachievable mechanical properties. The negative images formed therefrom exhibit improved thermo-mechanical properties, among other property enhancements.
• POLYCYCLIC-OLEFINIC COMPOSITIONS FOR LOW-LOSS FILMS HAVING IMPROVED THERMAL PROPERTIES
  申请人：PROMERUS, LLC

  公开号：US20220135831A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers and at least one multifunctional olefinic monomer which when subjected to a suitable temperature undergoes mass polymerization to provide a three-dimensional insulating article which exhibits hitherto unattainable low dielectric constant and low-loss properties, and very high thermal properties. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. The compositions are stable at room temperature and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100° C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• SHELF LIFE STABLE AND IMPROVED MASS POLYMERIZABLE POLYCYCLIC-OLEFINIC COMPOSITIONS
  申请人：PROMERUS, LLC

  公开号：US20220135832A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers, optionally at least one multifunctional olefinic monomer and a suitable solvent, which exhibits long shelf life stability and undergoes mass polymerization only when subjected to a suitable temperature to provide a three-dimensional insulating articles. Embodiments of this invention exhibit hitherto unattainable properties, such as for example, low dielectric constant and low loss properties, and very high thermal properties, among others. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. In general the compositions are stable at room temperature for an extended period of time lasting up to a few weeks and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100° C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• [EN] SHELF LIFE STABLE AND IMPROVED MASS POLYMERIZABLE POLYCYCLIC-OLEFINIC COMPOSITIONS<br/>[FR] COMPOSITIONS OLÉFINIQUES POLYCYCLIQUES POLYMÉRISABLES EN MASSE À DURÉE DE CONSERVATION STABLE ET AMÉLIORÉES
  申请人：[en]PROMERUS, LLC

  公开号：WO2022094236A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers, optionally at least one multifunctional olefinic monomer and a suitable solvent, which exhibits long shelf life stability and undergoes mass polymerization only when subjected to a suitable temperature to provide a three- dimensional insulating articles. Embodiments of this invention exhibit hitherto unattainable properties, such as for example, low dielectric constant and low loss properties, and very high thermal properties, among others. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. In general the compositions are stable at room temperature for an extended period of time lasting up to a few weeks and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100 °C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• [EN] POLYCYCLIC-OLEFINIC COMPOSITIONS FOR LOW-LOSS FILMS HAVING IMPROVED THERMAL PROPERTIES<br/>[FR] COMPOSITIONS POLYCYCLIQUES-OLÉFINIQUES POUR DES FILMS À FAIBLE PERTE PRÉSENTANT DES PROPRIÉTÉS THERMIQUES AMÉLIORÉES
  申请人：[en]PROMERUS, LLC

  公开号：WO2022094232A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers and at least one multifunctional olefinic monomer which when subjected to a suitable temperature undergoes mass polymerization to provide a three-dimensional insulating article which exhibits hitherto unattainable low dielectric constant and low-loss properties, and very high thermal properties. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. The compositions are stable at room temperature and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100 °C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.