N-hydroxybenzothioamide | 15177-34-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-hydroxybenzothioamide
• 英文别名: N-hydroxybenzenecarbothioamide
• CAS: 15177-34-1
• 化学式: C₇H₇NOS
• 分子量: 153.205
• InChiKey: FBYRYEFDOMKFEE-UHFFFAOYSA-N

物化性质

• 沸点：
  280.2±23.0 °C(Predicted)
• 密度：
  1.291±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  64.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-hydroxybenzothioamide 在 四丁基碘化铵 、 三乙胺 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 1.5h， 生成 allyl N-acetoxybenzimidothioate
  参考文献：
  名称：

  Synthesis of Thiohydroxamic Acids and Thiohydroximic Acid Derivatives

  摘要：

  An improved and expanded preparation of thiohydroxamic acids is reported along with a one-pot conversion of these compounds to novel thiohydroximic acid derivatives. A variety of aryl, heteroaryl, and alkyl substituents are well tolerated to provide a rapid approach to alkene-functionalized thiohydroximic acids that serve as potentially useful building blocks for organic synthesis.

  DOI：

  10.1021/jo500080x
• 作为产物：
  描述：

  苯二硫代甲酸 在 羟胺 作用下， 生成 N-hydroxybenzothioamide
  参考文献：
  名称：

  Cambi et al., Rendiconti - Istituto Lombardo Accademia di Scienze e Lettere, A: Scienze Matematiche, Fisiche, Chimiche e Geologiche, 1956, vol. 90, p. 577

  摘要：

  DOI：

文献信息

• Collision-induced dissociation mass spectra of glucosinolate anions
  作者：Jason B. Bialecki、Josef Ruzicka、Carl S. Weisbecker、Meena Haribal、Athula B. Attygalle

  DOI：10.1002/jms.1711

  日期：2010.3

  for the thioglucose anion, which further dissociates via an ion/neutral complex to give two peaks at m/z 75 and 119. The other product ions observed at m/z 80, 96 and 97 are characteristic for the sulfate moiety. The peaks at m/z 259 and 275 have been attributed previously to glucose 1-sulfate anion and 1-thioglucose 2-sulfate anion, respectively. However, based on our tandem mass spectrometric experiments

  在负离子模式下研究了不同取代的芥子油苷的碰撞诱导解离（CID）质谱。从数个芥子油苷及其同位素（（34）S和（2）H）获得的数据表明，观察到的许多峰与取代基的性质无关。例如，所有研究过的芥子油苷阴离子片段都会在m / z 195处观察到硫代葡萄糖阴离子的产物离子，该硫离子会通过离子/中性络合物进一步解离，从而在m / z 75和119处出现两个峰。观察到的其他产物离子m / z为80、96和97的硫酸盐部分是特征性的。先前分别将m / z 259和275处的峰归因于葡萄糖1硫酸根阴离子和1-硫葡萄糖2硫酸根阴离子。但是，根据我们的串联质谱实验，我们建议在m / z 275处的峰代表葡萄糖1-硫代硫酸根阴离子。除常见峰外，芥子油酸苯基酯（β-D-葡糖醛糖，1-硫代-，1- [N-（磺氧基）苯甲酰亚胺）的光谱还显示出C（m / z 152）处的取代基特定峰6）H（5）-C（= NOH）S（-），
• Metal complexes, the preparation thereof and use as biocides
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0392648A1

  公开（公告）日：1990-10-17

  A metal complex of the general formula [R1CSNRO]xM(L)y where R and R1 are optionally substituted hydrocarbyl groups, M is a metal of Group IIIA to VA and IB to VIIB, with the exception of copper, L is a ligand, x has a value of 1 to 3 and y is zero or has a value of up to 4. The complex may be prepared by the reaction of a metal salt with an N-hydroxythiobenzamide. Complexes of this type have anti-microbial properties, and can be used as industrial biocides.

  通用公式[R1CSNRO]xM(L)y的金属配合物，其中R和R1是可选择取代的烃基，M是III A到VA族和IB到VIIB族的金属，但不包括铜，L是配体，x的值为1到3，y为零或最多为4。该配合物可以通过金属盐与N-羟基硫代苯甲酰胺反应制备而成。这种类型的配合物具有抗微生物特性，可用作工业杀菌剂。
• Synthese von Heterocyclen mit N-Dichlormethylensulfonamiden
  作者：R. Neidlein、H. Krüll

  DOI：10.1002/ardp.19713041008

  日期：——

  Es werden die Synthesen beschrieben von 1,2‐Dihydro‐2‐sulfonyl‐amino‐3,1,4 H‐benzoxazin‐4‐onen (3), von 2‐N‐Sulfonyl‐amino‐4‐hydroxy‐chinazolonen (10) sowie das Reaktionsverhalten von 1 gegenüber o‐Aminophenolen und o‐Aminothenolen untersucht und die Strukturen der erhaltenen Substanzen aufgeklärt.

  Es werden die Synthesen beschrieben von 1,2-Dihydro-2-sulfonyl-amino-3,1,4 H-benzoxazin-4-onen (3), von 2-N-Sulfonyl-amino-4-hydroxy-chinazolonen (10 ) sowie das Reaktionsverhalten von 1 gegenüber o-Aminophenolen und o-Aminothenolen untersucht und die Strukturen der erhaltenen Substanzen aufgeklärt。
• Composition and method for inhibiting perspiration with S-substituted
  申请人：Colgate-Palmolive Company

  公开号：US03953590A1

  公开（公告）日：1976-04-27

  A method for inhibiting perspiration comprises applying to a site at which perspiration is normally exuded, an antiperspirant of the formula ##SPC1## Or a salt thereof. In preferred compounds, A, B, D, E, and G are hydrogen and R is phenyl, alkyl, hydroxyalkyl, aminoalkyl, alkenyl or oxopyridyl. Also useful are the corresponding hydrohalic acid salts. The compounds are preferably applied to the human axillae as aqueous antiperspirant compositions containing a surface active agent. Some of the S-substituted benzothiohydroximic acids and hydrohalic acid salts are new compounds of especially good antiperspirant activities, e.g., those in which the R group is linear alkyl of 6 to 9 carbon atoms, lower aminoalkyl, lower hydroxyalkyl, 1-oxopyridyl, and the hydrochloric acid salts of the compounds in which R is lower aminoalkyl.

  一种抑制出汗的方法包括在通常会分泌汗液的部位上涂抹式如下公式的除臭剂或其盐： ##SPC1## 其中，在优选的化合物中，A、B、D、E和G为氢，R为苯基、烷基、羟基烷基、氨基烷基、烯基或氧代吡啶基。相应的氢卤酸盐也是有用的。这些化合物最好以含有表面活性剂的水性除臭剂组成物的形式涂抹于人体腋窝。一些S-取代苯并硫脲酸和氢卤酸盐是具有特别好的抑汗活性的新化合物，例如，其中R基为6至9个碳原子的线性烷基、较低的氨基烷基、较低的羟基烷基、1-氧代吡啶基和R为较低的氨基烷基的化合物的氯化氢盐。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。