N-(4-bromophenyl)-N-(naphtho-2-yl)-1-naphthylamine | 690658-67-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-bromophenyl)-N-(naphtho-2-yl)-1-naphthylamine
• 英文别名: N-(4-bromophenyl)-N-naphthalen-1-ylnaphthalen-2-amine
• CAS: 690658-67-4
• 化学式: C₂₆H₁₈BrN
• 分子量: 424.34
• InChiKey: WPEVURPEDNGPEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(4-bromophenyl)-N-(naphtho-2-yl)-1-naphthylamine 、 N,N'-bis(phenantho-9-yl)-4,4'-benzidine 在 bis-triphenylphosphine-palladium(II) chloride sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 24.0h， 生成 4-N-naphthalen-1-yl-4-N-naphthalen-2-yl-1-N-[4-[4-[4-[naphthalen-1-yl(naphthalen-2-yl)amino]-N-phenanthren-9-ylanilino]phenyl]phenyl]-1-N-phenanthren-9-ylbenzene-1,4-diamine
  参考文献：
  名称：

  AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

  摘要：

  提供了以下式（1）所表示的芳香胺化合物和具有至少一个含有上述芳香胺衍生物的有机薄膜层的有机电致发光元件，该层以单一组分形式存在。上述有机电致发光元件在低电压下具有高发光效率和长寿命。即使在高温下也能发出蓝光。在式（1）中，Ar1和Ar2分别表示萘基等；Ar3至Ar6分别表示苯基、萘基、菲基等；Ar7至Ar10分别表示1,4-苯基等；L表示单键等；满足以下条件：（1）至少Ar3至Ar6中的一个是具有10至50个核碳原子的缩合芳基基团；（2）至少Ar1和Ar2中的一个是具有12至50个核碳原子的缩合芳基基团。

  公开号：

  EP1559706A1
• 作为产物：
  描述：

  1,4-二溴苯 、 1,2'-二萘胺(升华精制品) 在 copper(l) iodide 、 caesium carbonate 作用下， 以 甲苯 为溶剂， 反应 7.0h， 以60%的产率得到N-(4-bromophenyl)-N-(naphtho-2-yl)-1-naphthylamine
  参考文献：
  名称：

  一种新的有机电致发光材料及其制备方法和 应用

  摘要：

  一种新的有机电致发光材料及其制备方法和应用。本发明提供了一种新的蒽衍生物，是在蒽化合物中引进醚结构链接Y1和Ar1、Ar2和R1基团改善化合物的立体技能以及调剂配体R1分子量，按配体种类性能改善及技能改善等优点，使用本发明的新的蒽衍生物制备的器件具备高的亮度、优秀的耐热性、长寿命及高效率等特点。

  公开号：

  CN105384613B

文献信息

• Aromatic amine derivative and organic electroluminescent element employing the same
  申请人：Kawamura Hisayuki

  公开号：US20060061265A1

  公开（公告）日：2006-03-23

  Provided are an aromatic amine compound represented by the following Formula (1) and an organic electroluminescent element which has at least one organic thin film layer containing the above aromatic amine derivative in the form of a single component. The organic electroluminescent element described above has a high luminescent efficiency even at a low voltage and a long life. It can emit blue light even at high temperatures. In Formula (1), Ar 1 and Ar 2 each represent naphthyl and the like; Ar 3 to Ar 6 each represent phenyl, naphthyl, phenanthryl and the like; Ar 7 to Ar 10 each represent 1,4-phenylene and the like; L represents a single bond and the like; provided that the conditions of (1) and/or (2) are satisfied: (1) at least one of Ar 3 to Ar 6 is a condensed aryl group having 10 to 50 nuclear carbon atoms and (2) at least one of Ar 1 and Ar 2 is a condensed aryl group having 12 to 50 nuclear carbon atoms.

  提供了一种由以下式子（1）表示的芳香胺化合物和一种含有至少一种有机薄膜层的有机电致发光元件，该有机薄膜层以单一组分的形式含有上述芳香胺衍生物。上述有机电致发光元件在低电压下具有高发光效率和长寿命。它甚至在高温下也可以发出蓝光。在式（1）中，Ar1和Ar2分别表示萘基等；Ar3到Ar6分别表示苯基、萘基、菲基等；Ar7到Ar10分别表示1,4-苯基等；L表示单键等；前提是满足（1）和/或（2）的条件：（1）Ar3到Ar6中至少有一个是具有10至50个核碳原子的紧缩芳基基团；（2）Ar1和Ar2中至少有一个是具有12至50个核碳原子的紧缩芳基基团。
• Organic electronic element comprising compound for organic electronic element, and electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US10658597B2

  公开（公告）日：2020-05-19

  An organic electric element includes a first electrode, a second electrode, and an organic material layer between the first electrode and the second electrode. The organic material layer includes the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, stability, and life span can be improved.

  一种有机电元件包括第一电极、第二电极以及位于第一电极和第二电极之间的有机材料层。有机材料层包括由式 1 表示的化合物。当有机电子元件在有机材料层中包含该化合物时，发光效率、稳定性和使用寿命都能得到改善。
• ORGANIC ELECTRONIC ELEMENT COMPRISING COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, AND ELECTRONIC DEVICE THEREOF
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US20160163994A1

  公开（公告）日：2016-06-09

  An organic electric element includes a first electrode, a second electrode, and an organic material layer between the first electrode and the second electrode. The organic material layer includes the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, stability, and life span can be improved.
• COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME
  申请人：Duk San Neolux Co., Ltd.

  公开号：US20170141311A1

  公开（公告）日：2017-05-18

  The purpose of the present invention is to provide a compound that can improve the lifespan, low drive voltage and high luminous efficiency of an element, an organic electronic element using same, and an electronic device comprising same.
• [EN] COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC DEVICE USING SAME, AND ELECTRONIC DEVICE THEREOF<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRONIQUE ORGANIQUE, DISPOSITIF ÉLECTRONIQUE ORGANIQUE L'UTILISANT ET DISPOSITIF ÉLECTRONIQUE ASSOCIÉ<br/>[KO] 유기전기소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2018012781A1

  公开（公告）日：2018-01-18

  본 발명에 따른 화합물을 인광 호스트 물질로 이용함으로써, 유기전기소자의 높은 발광효율, 낮은 구동전압을 달성할 수 있으며, 또한 소자의 수명을 크게 향상시킬 수 있는 유기전기소자, 그 전자장치를 제공한다.