1-(2-Methylphenoxy)propan-1-ol | 89360-37-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(2-Methylphenoxy)propan-1-ol
• CAS: 89360-37-2
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: BVFULMNNRVECNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• METHOD FOR PRODUCING FLUORENE DERIVATIVE
  申请人：Fujii Katsuhiro

  公开号：US20120029244A1

  公开（公告）日：2012-02-02

  A method for producing a fluorene derivative by reacting fluorenone with a phenol or a phenoxyalcohol in the presence of an acid catalyst includes: adding an alkali to an obtained reaction liquid containing a fluorene derivative; and concentrating a resultant mixture liquid without removing the alkali thus added and a reaction product of the alkali, thereby separating an unreacted phenol or unreacted phenoxyalcohol.

  一种制备芴衍生物的方法，通过在酸催化剂存在下将芴酮与苯酚或苯氧乙醇反应，包括以下步骤：向含有芴衍生物的反应液中加入碱；在不去除已添加的碱和碱的反应产物的情况下浓缩混合液，从而分离未反应的苯酚或未反应的苯氧乙醇。
• Verfahren zur Herstellung von Aryloxyessigsäuren
  申请人：BAYER AG

  公开号：EP0011793A1

  公开（公告）日：1980-06-11

  Die Erfindung betrifft ein Verfahren zur Herstellung von Aryloxyessigsäuren durch Oxidation von Aryloxyäthanolen bei dem man mit Sauerstoff oder Sauerstoff enthaltenden Gasen in wäßrig alkalischen Medien bei Temperaturen von 0°C bis zum Siedepunkt des Reaktionsgemisches in Gegenwart von Platinmetall-Katalysatoren die Oxidation in Gegenwart von Aktivatoren aus Blei und/oder Wismut und/oder deren Verbindungen und gegebenenfalls in zusätzlicher Gegenwart von Cadmium und/oder dessen Verbindungen vornimmt.

  本发明涉及一种通过氧化芳氧基乙醇制备芳氧基乙酸的工艺，在该工艺中，氧化是在水性碱性介质中用氧气或含氧气体在0℃至反应混合物沸点的温度下，在铂金属催化剂的存在下，在铅和/或铋和/或其化合物的活化剂存在下，以及可选择地在镉和/或其化合物的额外存在下进行的。
• COMPOUND HAVING FLUORENE SKELETON, AND METHOD FOR MANUFACTURING SAME
  申请人：Teijin Limited

  公开号：EP3747856A1

  公开（公告）日：2020-12-09

  Provided are a novel compound having a fluorene skeleton, and a method for manufacturing the same, the compound having a low palladium content or other content of a specific metal or content of a specific compound in a raw material alcohol, and being excellent in hue or various characteristics (optical characteristics, heat resistance, moldability, and other characteristics) as a raw material or in a resin that uses the raw material. This compound is a mixture of compounds having a fluorene skeleton represented by formula (1) (in formula (1), the rings Z being (same or different) aromatic groups, R1 and R2 each independently representing a hydrogen atom, a halogen atom, or a C1-12 hydrocarbon group which may include an aromatic group, Ar1 and Ar2 representing C6-10 aromatic groups which may have a substituent, L1 and L2 representing alkylene groups, j and k each independently representing an integer of 0 or greater, and m and n each independently representing an integer of 0 to 5), the mixture of compounds having a fluorene skeleton being characterized in that the content of elemental palladium therein satisfies formula (2) ((2): 0 ≤ Pd ≤ 50 ppm), and among the mixture of compounds represented by formula (1), compounds comprising the integers m = 1-5 and n = 0 are included in a range of 0-5%.

  本发明提供了一种具有芴骨架的新型化合物及其制造方法，该化合物在原料酒精中的钯含量或其他特定金属含量或特定化合物含量较低，作为原料或在使用该原料的树脂中的色调或各种特性（光学特性、耐热性、成型性和其他特性）优良。该化合物是具有由式（1）表示的芴骨架的化合物混合物（在式（1）中，环 Z 是（相同或不同的）芳香基团，R1 和 R2 各自独立地代表氢原子、卤素原子或可包括芳香基团的 C1-12 碳氢基团，Ar1 和 Ar2 代表可具有取代基的 C6-10 芳香基团、L1和L2代表亚烷基，j和k各自独立地代表0或更大的整数，m和n各自独立地代表0至5的整数），具有芴骨架的化合物混合物的特征在于其中钯元素的含量满足式(2)（(2)：0≤钯≤50ppm)，在式(1)表示的化合物混合物中，包含整数m＝1-5和n＝0的化合物在0-5％的范围内。
• Compound having fluorene skeleton, and method for manufacturing same
  申请人：TEIJIN LIMITED

  公开号：US11339249B2

  公开（公告）日：2022-05-24

  Provided are a novel compound having a fluorene skeleton, and a method for manufacturing the same, the compound having a low palladium content or other content of a specific metal or content of a specific compound in a raw material alcohol, and being excellent in hue or various characteristics (optical characteristics, heat resistance, moldability, and other characteristics) as a raw material or in a resin that uses the raw material. This compound is a mixture of compounds having a fluorene skeleton represented by formula (1) (in formula (1), the rings Z being (same or different) aromatic groups, R1 and R2 each independently representing a hydrogen atom, a halogen atom, or a C1-12 hydrocarbon group which may include an aromatic group, Ar1 and Ar2 representing C6-10 aromatic groups which may have a substituent, L1 and L2 representing alkylene groups, j and k each independently representing an integer of 0 or greater, and m and n each independently representing an integer of 0 to 5), the mixture of compounds having a fluorene skeleton being characterized in that the content of elemental palladium therein satisfies formula (2) ((2): 0≤Pd≤50 ppm), and among the mixture of compounds represented by formula (1), compounds comprising the integers m=1-5 and n=0 are included in a range of 0-5%.

  本发明提供了一种具有芴骨架的新型化合物及其制造方法，该化合物在原料酒精中的钯含量或其他特定金属含量或特定化合物含量较低，作为原料或在使用该原料的树脂中的色调或各种特性（光学特性、耐热性、成型性和其他特性）优良。该化合物是具有由式（1）表示的芴骨架的化合物混合物（在式（1）中，环 Z 是（相同或不同的）芳香基团，R1 和 R2 各自独立地代表氢原子、卤素原子或可包括芳香基团的 C1-12 碳氢基团，Ar1 和 Ar2 代表可具有取代基的 C6-10 芳香基团、L1和L2代表亚烷基，j和k各自独立地代表0或更大的整数，m和n各自独立地代表0至5的整数），具有芴骨架的化合物混合物的特征在于其中钯元素的含量满足式(2)（(2)：0≤Pd≤50ppm)，在式(1)表示的化合物混合物中，包含整数m＝1-5和n＝0的化合物在0-5%的范围内。
• Dyeing composition and processes for dyeing fabrics made of polyester or a polyester blend with cotton or wool
  申请人：CIBA-GEIGY AG

  公开号：EP0018947B1

  公开（公告）日：1984-02-01