3-((4-chlorophenyl)disulfanyl)-1H-1,2,4-triazole | 1264674-58-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-((4-chlorophenyl)disulfanyl)-1H-1,2,4-triazole
• 英文别名: 5-[(4-chlorophenyl)disulfanyl]-1H-1,2,4-triazole
• CAS: 1264674-58-9
• 化学式: C₈H₆ClN₃S₂
• 分子量: 243.741
• InChiKey: MXXULNMXUVXMMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-巯基-1,2,4-三氮唑 、 4-chloro-benzenesulfenyl chloride 在 水 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成 3-((4-chlorophenyl)disulfanyl)-1H-1,2,4-triazole
  参考文献：
  名称：

  A traceless, one-pot preparation of unsymmetric disulfides from symmetric disulfides through a repeated process involving sulfenic acid and thiosulfinate intermediates

  摘要：

  A variable group of unsymmetric disulfides was prepared under mild reaction conditions and in high yields through the reaction of symmetric disulfides with sulfuryl chloride followed by treatment with thiols in the presence of water. (C) 2010 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2010.11.042

文献信息

• A traceless, one-pot preparation of unsymmetric disulfides from symmetric disulfides through a repeated process involving sulfenic acid and thiosulfinate intermediates
  作者：Minsoo Han、Jong Tak Lee、Hoh-Gyu Hahn

  DOI：10.1016/j.tetlet.2010.11.042

  日期：2011.1

  A variable group of unsymmetric disulfides was prepared under mild reaction conditions and in high yields through the reaction of symmetric disulfides with sulfuryl chloride followed by treatment with thiols in the presence of water. (C) 2010 Published by Elsevier Ltd.