A process for the polymerization of polymers of itaconic acid and vinyl acetate comprising the step of polymerizing
(i) from 10 to 95 mole percent of monomer units of the formula I:
wherein each of R₁ and R₂, which may be the same or different, represents a hydrogen atom, a methyl group or an ethyl group, and M is a hydrogen atom or an alkyl (C₁ to C₁₈) chain or an organic group such as an amino containing functionality;
(ii) from 5 to 90 mole percent of monomer units of the formula II:
wherein R₃ represents a hydrogen atom or the group -COCH₃; and
(iii) from 0 to 45 mole percent of a ethylenically unsaturated copolymerizable comonomer, said polymerization being carried out using semi-batch polymerization procedures at a temperature of 60 to 200°c in the presence of a substantially anhydrous alcoholic solvent.
一种
衣康酸和
醋酸乙烯聚合物的聚合工艺,包括以下聚合步骤
(i) 10 至 95 摩尔%的式 I 单体单元:
其中 R₁和 R₂(可以相同或不同)各自代表氢原子、甲基或乙基,而 M 是氢原子或烷基(C₁至 C₁₈)链或有机基团,如含有官能度的
氨基;
(ii) 5 至 90 摩尔%的式 II:
其中 R₃ 代表氢原子或基团 -COCH₃;以及
(iii) 0 至 45 摩尔%的
乙烯不饱和共聚单体,所述聚合采用半间歇聚合程序,在 60 至 200 摄氏度的温度下,在基本无
水的
醇类溶剂存在下进行。