Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer
申请人:TOHO TITANIUM CO., LTD.
公开号:US11192965B2
公开(公告)日:2021-12-07
Provided is a solid catalyst component for olefin polymerization comprising an electron-donating compound other than a phthalate, the solid catalyst component being equal in the olefin-polymerizing activity and in the primary physical properties of the resulting polymer such as stereoregularity and molecular weight distribution to those with use of a phthalate as an electron-donating compound. A solid catalyst component for olefin polymerization comprises a magnesium atom, a titanium atom, a halogen atom, an ester compound (A) represented by a general formula (1) and a diester compound (B) represented by a general formula (2), wherein
a ratio represented by the following expression:
(content (mass %) of ester compound (A)/content (mass %) of diester compound (B))
is 0.05 to 50.
本发明提供了一种用于烯烃聚合的固体催化剂组分,该组分包括邻苯二甲酸酯以外的一种电子供体化合物,该固体催化剂组分在烯烃聚合活性和所得聚合物的主要物理性质(如立体规整度和分子量分布)方面与使用邻苯二甲酸酯作为电子供体化合物的催化剂组分相同。用于烯烃聚合的固体催化剂组分包括镁原子、钛原子、卤素原子、通式(1)表示的酯化合物 (A)和通式(2)表示的二酯化合物(B),其中
由以下表达式表示的比例:
(酯化合物(A)的含量(质量百分比)/二酯化合物(B)的含量(质量百分比))
为 0.05 至 50。