1,3-Cyclohexadiene, 2-iodo

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,3-Cyclohexadiene, 2-iodo
• 英文别名: 2-iodocyclohexa-1,3-diene
• 化学式: C₆H₇I
• 分子量: 206.02
• InChiKey: YLTLVRQQBHLAKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Transition metal complexes with (pyridyl)imidazole ligands and their use
  申请人：Abbott Diabetes Care Inc.

  公开号：EP2301942A1

  公开（公告）日：2011-03-30

  Novel transition metal complexes of iron, cobalt, ruthenium, osmium, and vanadium are described. The transition metal complexes can be used as redox mediators in enzyme-based electrochemical sensors. The transition metal complexes include substituted or unsubstituted(pyridyl)imidazole ligands. Transition metal complexes attached to polymeric backbones are also described.

  介绍了铁、钴、钌、锇和钒的新型过渡金属配合物。这些过渡金属配合物可用作基于酶的电化学传感器中的氧化还原介质。过渡金属配合物包括取代或未取代的（吡啶基）咪唑配体。此外，还介绍了附着在聚合物骨架上的过渡金属配合物。
• MATERIAL FOR USE IN PHOSPHORESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2415772A1

  公开（公告）日：2012-02-08

  Provided is an organic electroluminescent device (organic EL device), in which the luminous efficiency of the device is improved, driving stability is sufficiently ensured, and the construction of the device is simple. This organic EL device is an organic electroluminescent device, including a light-emitting layer between an anode and a cathode laminated on a substrate, in which the light-emitting layer contains a phosphorescent light-emitting dopant and an indolocarbazole compound as a host material. Examples of the indolocarbazole compound include a compound represented by the following formula (1). It should be noted that in the formulae: a ring A and a ring B are represented by the formulae (1a) and (1b), respectively; Ar's each represent an aromatic hydrocarbon group or an aromatic heterocyclic group; R's each represent a hydrogen atom, an alkyl group, or a cycloalkyl group; X represents a methine group or a nitrogen atom; A represents an aromatic hydrocarbon group, an alkyl group, a cycloalkyl group, or a group represented by the formula (1c); and n represents 0 or 1.

  本发明提供了一种有机电致发光器件（organic EL device），该器件的发光效率得到提高，驱动稳定性得到充分保证，而且结构简单。这种有机 EL 器件是一种有机电致发光器件，包括层叠在基底上的阳极和阴极之间的发光层，其中发光层包含磷光发光掺杂剂和作为主材料的吲哚咔唑化合物。吲哚咔唑化合物的例子包括下式（1）所代表的化合物。应注意，在式中：环 A 和环 B 分别由式（1a）和（1b）表示；Ar 各代表芳香烃基团或芳香杂环基团；R 各代表氢原子、烷基或环烷基；X 代表甲基或氮原子；A 代表芳香烃基团、烷基、环烷基或由式（1c）表示的基团；n 代表 0 或 1。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2492987A1

  公开（公告）日：2012-08-29

  Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secure of driving stability, and of a simple configuration. The organic EL device comprises organic layers comprising a hole-transporting layer and a light-emitting layer sandwiched between an anode and a cathode. The light-emitting layer contains a fluorescent light-emitting material and an electron- and/or exciton-blocking layer containing an indolocarbazole derivative represented by general formula (2) is disposed between the hole-transporting layer and the light-emitting layer so as to be adjacent to the light-emitting layer. In general formula (2), ring B is a heterocyclic ring fused to the adjacent rings and represented by formula (1c), Z is an n-valent aromatic hydrocarbon group or aromatic heterocyclic group, and n is 1 or 2.

  本发明公开了一种有机电致发光器件（有机 EL 器件），它的发光效率更高，完全保证了驱动稳定性，而且结构简单。有机电致发光器件由有机层组成，有机层包括夹在阳极和阴极之间的空穴传输层和发光层。发光层包含一种荧光发光材料，电子和/或激子阻挡层包含一种由通式（2）表示的吲哚咔唑衍生物，该层位于空穴传输层和发光层之间，与发光层相邻。在通式（2）中，环 B 是与相邻环融合的杂环，由式（1c）表示；Z 是正价芳香烃基团或芳香杂环基团；n 是 1 或 2。
• ORGANIC LIGHT-EMITTING MATERIAL AND ORGANIC LIGHT-EMITTING ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2511360A1

  公开（公告）日：2012-10-17

  Provided are a fluorescence-emitting material which improves luminous efficiency of an organic light-emitting element such as an organic EL element or an organic PL element and an organic light-emitting element using the fluorescence-emitting material. The fluorescence-emitting material includes a compound having an indolocarbazole skeleton represented by the following general formula (1). The organic light-emitting element includes an organic EL element including: a substrate; an anode; a cathode; and a light-emitting layer, the anode and the cathode being laminated on the substrate and the light-emitting layer being sandwiched between the anode and the cathode, in which the light-emitting layer includes: the organic light-emitting material; and as a host material, an organic compound having excited triplet energy higher than that of the organic light-emitting material. In the general formula (1) : a ring A represents an aromatic ring represented by the formula (1a) to be fused with an adjacent ring; a ring B represents a heterocycle represented by the formula (1b) to be fused with an adjacent ring; Ar represents an aromatic hydrocarbon group or an aromatic heterocyclic group; R's each represent hydrogen or a monovalent substituent; and n represents an integer of 1 to 4.

  本发明提供了一种可提高有机发光元件（如有机 EL 元件或有机 PL 元件）发光效率的荧光发光材料，以及使用该荧光发光材料的有机发光元件。荧光发光材料包括具有由以下通式（1）表示的吲哚咔唑骨架的化合物。有机发光元件包括有机 EL 元件，其中有机 EL 元件包括：基板；阳极；阴极；和发光层，阳极和阴极层叠在基板上，发光层夹在阳极和阴极之间，其中发光层包括：有机发光材料；和作为宿主材料的有机化合物，该有机化合物的激发三重能高于有机发光材料的激发三重能。在通式（1）中：环 A 代表由式（1a）表示的与相邻环融合的芳香环；环 B 代表由式（1b）表示的与相邻环融合的杂环；Ar 代表芳香烃基团或芳香杂环基团；R 各代表氢或一价取代基；n 代表 1 至 4 的整数。
• ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC EL DISPLAY DEVICE, AND ORGANIC EL LIGHTING
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2592671A1

  公开（公告）日：2013-05-15

  The present invention is to provide a highly efficient organic electroluminescence element which has a long life and an organic electroluminescence device which includes the element. The invention relates to an organic electroluminescence element which comprises an anode, a luminescent layer, two or more electron transport layers and a cathode, in this order, wherein at least one of the two or more electron transport layers adjoins the luminescent layer, the luminescent layer contains a luminescent material and a charge transport material, the electron transport layer which adjoins the luminescent layer contains a charge transport material, the charge transport material contained in the luminescent layer and the charge transport material contained in the electron transport layer which adjoins the luminescent layer may be the same material or may be different material, when an electron affinity of the charge transport material which serves to transport electrons, among the charge transport materials contained in the luminescent layer, is expressed by EA1, and an electron affinity of the charge transport material which is the highest in an absolute value of electron affinity, among the charge transport materials contained in the electron transport layer that adjoins the luminescent layer, is expressed by EA2, then EA1 and EA2 satisfy the relationship represented by the following expression (1), and when an electron affinity of the charge transport material which is the highest in an absolute value of electron affinity, among the charge transport materials contained in the electron transport layer located on the most cathode side among the two or more electron transport layers, is expressed by EA3, and a work function of the cathode is expressed by WF, then EA3 and WF satisfy the relationship represented by the following expression (2):

  本发明旨在提供一种使用寿命长的高效有机电致发光元件和一种包括该元件的有机电致发光器件。本发明涉及一种有机电致发光元件，它依次包括阳极、发光层、两个或多个电子传输层和阴极，其中两个或多个电子传输层中至少有一个与发光层相邻，发光层包含发光材料和电荷传输材料，与发光层相邻的电子传输层包含电荷传输材料、发光层中包含的电荷传输材料和与发光层相邻的电子传输层中包含的电荷传输材料可以是相同的材料，也可以是不同的材料、用 EA1 表示，而在与发光层相邻的电子传输层中所包含的电荷传输材料中，电子亲和力绝对值最高的电荷传输材料的电子亲和力用 EA2 表示，则 EA1 和 EA2 满足以下表达式 (1) 所表示的关系、当位于两个或多个电子传输层中最阴极一侧的电子传输层所含电荷传输材料中电子亲和力绝对值最高的电荷传输材料的电子亲和力用 EA3 表示，阴极的功函数用 WF 表示时，则 EA3 和 WF 满足以下表达式 (2) 所表示的关系：