3-ethyl-2-methyl-3-pentenoic acid | 126486-07-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-ethyl-2-methyl-3-pentenoic acid
• 英文别名: E-3-ethyl-2-methylpent-3-enoic acid；3-ethyl-2-methyl-pent-3-enoic acid；3-Aethyl-2-methyl-pent-3-ensaeure；(E)-3-ethyl-2-methylpent-3-enoic acid
• CAS: 126486-07-5
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: MSQYRBGOIPUKMF-QPJJXVBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-ethyl-2-methyl-3-pentenoic acid 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Kon et al., Journal of the Chemical Society, 1931, p. 1414

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 生成 3-ethyl-2-methyl-3-pentenoic acid
  参考文献：
  名称：

  Kon et al., Journal of the Chemical Society, 1931, p. 1414

  摘要：

  DOI：

文献信息

• EtAlCl₂/2,6-Disubstituted Pyridine-Mediated Carboxylation of Alkenes with Carbon Dioxide
  作者：Shinya Tanaka、Kota Watanabe、Yuuki Tanaka、Tetsutaro Hattori

  DOI：10.1021/acs.orglett.6b00918

  日期：2016.6.3

  and trialkyl-substituted alkenes undergo carboxylation with CO2 in the presence of EtAlCl2 and 2,6-dibromopyridine to afford the corresponding α,β- and/or β,γ-unsaturated carboxylic acids. This reaction is suggested to proceed via the electrophilic substitution of EtAlCl2 with the aid of the base, followed by the carbonation of the resulting ate complex. This reaction can be applied to terminal dialkylalkenes

  在EtAlCl 2和2,6-二溴吡啶的存在下，α-芳基烯烃和三烷基取代的烯烃与CO 2进行羧化反应，得到相应的α，β-和/或β，γ-不饱和羧酸。建议该反应通过在碱的辅助下对EtAlCl 2进行亲电取代，然后将所得的盐配合物碳酸化来进行。通过使用2，6-二叔丁基吡啶和2，6-二溴吡啶的混合物，该反应可用于末端二烷基烯烃。
• A mat film or sheet and method for preparing the same
  申请人：Nippon Petrochemicals Company, Limited

  公开号：EP0508415A2

  公开（公告）日：1992-10-14

  A polyolefin-based mat film or sheet can be preared from a polymeric blend of the preset invention comprising a propylene polymer or copolymer as component (A) and a specific ethylene-α-olefin copolymer (VLDPE, so-called "super low-density polyethylene") as component (B). The polymeric blend may further comprise a high-pressure radical polymerization process ethylene polymer or copolymer and /or a modified polyolefin-based resin as component (C). The above blend of the present invention may further comprise an inorganic filler as component (D) and a flame retardant as component (E). The mat films or sheets prepared from these polymeric blends are excellent in tensile modulus, flexibility, impact resistance, thermal resistance, laminating properties, flame resistance, chalking resistance, covering power, scratch resistance, and widely used for fabricating adhesive tapes, covers or cases for stationeries, fashion bags, sheets for interior finish work in construction and automobile industries, and sheets for dressing steel plates.

  聚烯烃基垫层薄膜或片材可以由本发明的聚合物混合物预制而成，该聚合物混合物由丙烯聚合物或共聚物作为组分（A）和特定的乙烯-α-烯烃共聚物（VLDPE，即所谓的 "超低密度聚乙烯"）作为组分（B）组成。聚合物混合物可进一步包括高压自由基聚合工艺乙烯聚合物或共聚物和/或改性聚烯烃基树脂作为组分（C）。本发明的上述混合物还可进一步包括作为组分（D）的无机填料和作为组分（E）的阻燃剂。用这些聚合物混合物制备的毡膜或薄片具有优异的拉伸模量、柔韧性、抗冲击性、耐热性、层压性、阻燃性、抗粉化性、遮盖力和抗划伤性，可广泛用于制造胶带、文具封面或包装盒、时装包、建筑和汽车工业内部装修用薄片以及钢板修整用薄片。
• VINYL CHLORIDE RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2607423A1

  公开（公告）日：2013-06-26

  The present invention provides a vinyl chloride resin composition having an improved resistance to warm-water bleaching. The vinyl chloride resin composition according to the present invention is characterized by comprising, with respect to 100 parts by mass of a vinyl chloride-based resin, 0.01 to 10 parts by mass of (a) a zinc-modified hydrotalcite and 0.01 to 10 parts by mass of (b) an acrylic processing aid having a weight-average molecular weight of 200,000 to 7,000,000. The above-described (a) zinc-modified hydrotalcite is preferably a compound represented by the following Formula (I):         Mgx1Znx2Al2(OH)2(x1+x2)+4·CO3·mH2O     (I) (wherein, x1 and x2 each represent a number satisfying the conditions of the following equations; and m represents a real number: 0.1 ≤ x2/x1 < 10, 2 ≤ x1 + x2 < 20).

  本发明提供了一种氯乙烯树脂组合物，它具有更好的耐温水漂白性。根据本发明的氯乙烯树脂组合物的特点是，相对于 100 份质量的氯乙烯基树脂，包含 0.01 至 10 份质量的(a)锌改性氢铝酸盐和 0.01 至 10 份质量的(b)丙烯酸加工助剂，其重量平均分子量为 200,000 至 7,000,000。上述(a)锌改性氢铝酸盐最好是由下式(I)表示的化合物： Mgx1Znx2Al2(OH)2(x1+x2)+4-CO3-mH2O (I) (其中，x1 和 x2 分别代表满足下式条件的数字；m 代表实数：0.1 ≤ x2/x1 ＜ 10，2 ≤ x1 + x2 ＜ 20)。
• VINYL CHLORIDE RESIN COMPOSITION FOR INJECTION MOLDING
  申请人：Adeka Corporation

  公开号：EP2711393A1

  公开（公告）日：2014-03-26

  The present invention provides a vinyl chloride resin composition for injection molding, including relative to 100 parts by mass of a vinyl chloride resin, (a) 0.01 to 10 parts by mass of an organic acid calcium salt and/or an organic acid zinc salt, (b) 0.01 to 10 parts by mass of a hydrotalcite compound, (c) 0.01 to 10 parts by mass of a β-diketone compound, and (d) 0.01 to 10 parts by mass of a polyol mixture, wherein the polyol mixture of component (d) is a polyol mixture composed of pentaerithrytol and condensates thereof; when the degree of condensation of pentaerithritol is represented by n, the combined content of the pentaerithrytol and condensates thereof of n = 1 to 3 is 5 to 40% by mass relative to the overall amount of the polyol mixture.

  本发明提供了一种用于注塑成型的氯乙烯树脂组合物，其中包括相对于 100 质量份的氯乙烯树脂、 (a) 0.01 至 10 质量份的有机酸钙盐和/或有机酸锌盐、 (b) 0.01 至 10 质量份的氢滑石化合物、 (c) 0.01 至 10 质量份的β-二酮化合物，和 (d) 0.01 至 10 质量份的多元醇混合物、 其中，(d)组分的多元醇混合物是由戊四醇及其缩合物组成的多元醇混合物；当戊四醇的缩合度用 n 表示时，相对于多元醇混合物的总量，n=1 至 3 的戊四醇及其缩合物的总含量为 5%至 40%（质量分数）。
• RESIN COMPOSITION FOR PRINTING FILM AND PRINTING FILM
  申请人：Adeka Corporation

  公开号：EP2907844A1

  公开（公告）日：2015-08-19

  The present invention provides a resin composition for a printing film, which has excellent colorability, heat resistance and printability; and a printing film using the same. The resin composition for a printing film is characterized by comprising, with respect to 100 parts by mass of a vinyl chloride-based resin: (A) 0.001 to 1 part by mass of (a-1) at least one benzotriazole compound represented by the following Formula (I) and/or (a-2) at least one salicylamide compound represented by the following Formula (II); (B) 0.001 to 1 part by mass of a β-diketone compound; and (C) 0.001 to 1 part by mass of a phenolic antioxidant: (wherein, R1, R2, R3 and R4 each independently represent, for example, a hydrogen atom) (wherein, R represents, for example, a hydrogen atom).

  本发明提供了一种印刷薄膜用树脂组合物，该组合物具有优异的着色性、耐热性和印刷性；以及使用该组合物的印刷薄膜。该印刷薄膜用树脂组合物的特征是，相对于 100 份质量的氯乙烯基树脂，它包括：(A) 0.001 至 1 份质量的(a-1)至少一种由下式(I)表示的苯并三唑化合物和/或(a-2)至少一种由下式(II)表示的水杨酰胺化合物；(B) 0.001 至 1 份质量的β-二酮化合物；以及(C) 0.001 至 1 份质量的酚类抗氧化剂： (其中，R1、R2、R3 和 R4 各自独立地代表例如氢原子) (其中，R 代表氢原子）。