cyclohex-3-enecarboxylic acid allyl ester | 77626-69-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cyclohex-3-enecarboxylic acid allyl ester
• 英文别名: Cyclohex-3-encarbonsaeure-allylester；3-cyclohexene-1-carboxylic acid allyl ester；allyl 3-cyclohexene-1-carboxylate；allyl 3-cyclohexene carboxylate；prop-2-enyl cyclohex-3-ene-1-carboxylate
• CAS: 77626-69-8
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: KXNUPTIZPIQESN-UHFFFAOYSA-N

物化性质

• 沸点：
  91 °C(Press: 10 Torr)
• 密度：
  0.9972 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cyclohex-3-enecarboxylic acid allyl ester 在 sodium tungstate 氨甲基膦酸 、 双氧水 、 三辛基甲基硫酸铵 作用下， 以 水 为溶剂， 反应 3.25h， 以80%的产率得到allyl 3,4-epoxycyclohexane-1-carboxylate
  参考文献：
  名称：

  WO2006/123814

  摘要：

  公开号：
• 作为产物：
  描述：

  3-环己烯-1-甲酸 、 烯丙醇 在 硫酸 作用下， 生成 cyclohex-3-enecarboxylic acid allyl ester
  参考文献：
  名称：

  Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹

  摘要：

  DOI：

  10.1021/ja01522a048

文献信息

• PROCESS FOR PRODUCING EPOXY COMPOUND
  申请人：Nagato Nobuyuki

  公开号：US20120029217A1

  公开（公告）日：2012-02-02

  According to the present, invention, a process for producing an epoxy compound, where an epoxy compound can be selectively produced from olefins with good yield at low cost in a safe manner by a simple operation under mild conditions without using a quaternary ammonium salt or a metal compound, is provided. The present invention relates to a process for producing an epoxy compound, comprising epoxidizing a carbon-carbon double bond of an organic compound having a carbon-carbon double bond by using hydrogen peroxide as an oxidant, wherein the epoxidation is carried by out using an organic nitrile compound and an organic amine compound.

  根据本发明，提供了一种生产环氧化合物的方法，其中可以通过简单操作在温和条件下以低成本安全地从烯烃中选择性地生产环氧化合物，而无需使用季铵盐或金属化合物。本发明涉及一种生产环氧化合物的方法，包括使用过氧化氢作为氧化剂，通过使用有机腈化合物和有机胺化合物对含有碳碳双键的有机化合物的碳碳双键进行环氧化。
• PYRIDAZINONES AS GPR119 AGONISTS
  申请人：Grauert Matthias

  公开号：US20130172323A1

  公开（公告）日：2013-07-04

  The present invention relates to pyridazinone derivatives of general formula I, wherein the groups A, G and R 1 are as defined in the application, the tautomers thereof, stereoisomers thereof, the mixtures thereof and the salts thereof, which have valuable pharmacological properties, and in particular bind to the GPR119 receptor and modulate its activity.

  本发明涉及一般式I的吡啶并咪唑酮衍生物，其中A、G和R1基团如本申请中所定义，其互变异构体、立体异构体、其混合物和其盐，具有有价值的药理特性，特别是能够结合GPR119受体并调节其活性。
• Epoxy compound and process for producing the epoxy compound
  申请人：Arai Yoshikazu

  公开号：US08426614B2

  公开（公告）日：2013-04-23

  An object of the present invention is to provide an epoxy compound which has a quick curing rate and is excellent in an etching durability and a selectivity and which is liquid at room temperature and a process for producing the above epoxy compound. The epoxy compound of the present application is represented by Formula (I): (YSiO3/2)n  (I) (in Formula (I), p (p is a natural number equal to n or less) groups of Y out of n groups thereof represent specific groups, and (n−p) groups of Y represent a hydrogen atom or —OSiR12H; and n represents an integer of 2 to 500).

  本发明的目的是提供一种具有快速固化速度、在蚀刻耐久性和选择性方面表现出色、并在室温下为液态的环氧化合物以及制备上述环氧化合物的方法。本申请的环氧化合物由式（I）表示：(YSiO3/2)n  (I)（在式（I）中，n个中的p个Y（p是小于或等于n的自然数）代表特定的基团，而（n-p）个Y代表氢原子或—OSiR12H；n表示2至500的整数）。
• POLYMERIZABLE COMPOSITIONS AND MOLDED ARTICLES PRODUCED BY USING THE SAME
  申请人：ZEON CORPORATION

  公开号：EP1655321A1

  公开（公告）日：2006-05-10

  The present invention provides a polymerizable composition and a resin formed object capable of providing a crosslinked cycloolefin resin formed object and a crosslinked cycloolefin resin composite excellent in heat resistance, more specifically, a polymerizable composition comprising a cycloolefin mixture containing 0.1 to 50% by mole of a cycloolefin having, as a substituent group, a monovalent group including an aliphatic carbon-carbon unsaturated bond, a metathesis polymerization catalyst, and a radical generating agent; and formed objects produced by using a polymerizable composition described above which preferably further comprises a chain transfer agent and making the cycloolefin mixture undergo at least ring-opening polymerization.

  本发明提供了一种可聚合组合物和一种树脂成型物，能够提供一种交联环烯烃树脂成型物和一种耐热性优异的交联环烯烃树脂复合材料，更具体地说，一种可聚合组合物包括一种环烯烃混合物，该环烯烃混合物含有0.1至50%（以摩尔计）的环烯烃混合物，其取代基为包括脂肪族碳-碳不饱和键的单价基团、偏聚合催化剂和自由基生成剂；以及通过使用上述可聚合组合物生产的成型物体，该组合物最好进一步包含链转移剂，并使环烯烃混合物至少进行开环聚合。
• NOVEL EPOXY COMPOUND AND PROCESS FOR PRODUCTION THEREOF
  申请人：Showa Denko K.K.

  公开号：EP2055708A1

  公开（公告）日：2009-05-06

  A novel epoxy compound represented by the following general formula (I), and a production process thereof, is provided:         Y-(CH2)3-Si(OR1)nR23-n     (I) (wherein, Y is represented by any of the following formulas: or wherein, R1 and R2 represent alkyl groups having 1 to 5 carbon atoms, n represents an integer of 1 to 3, R3 and R4 represent hydrogen atoms, alkyl groups having 1 to 6 carbon atoms or trialkylsilyl groups having 1 to 4 carbon atoms, R5 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a trialkylsilyl group having 1 to 4 carbon atoms, R6 to R12 represent hydrogen atoms, alkyl groups having 1 to 6 carbon atoms or trialkylsilyl groups having 1 to 4 carbon atoms, and R13 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a trialkylsilyl group having 1 to 4 carbon atoms or an aryl group).

  本发明提供了一种由以下通式 (I) 表示的新型环氧化合物及其生产工艺： Y-(CH2)3-Si(OR1)nR23-n (I) 其中，Y 由下列任何式子表示：Y-(CH2)3-Si(OR1)nR23-n (I) 或 其中，R1 和 R2 代表具有 1 至 5 个碳原子的烷基，n 代表 1 至 3 的整数，R3 和 R4 代表氢原子、具有 1 至 6 个碳原子的烷基或具有 1 至 4 个碳原子的三烷基硅烷基，R5 代表氢原子、具有 1 至 6 个碳原子的烷基或具有 1 至 4 个碳原子的三烷基硅烷基、R6 至 R12 代表氢原子、具有 1 至 6 个碳原子的烷基或具有 1 至 4 个碳原子的三烷基硅基，R13 代表氢原子、具有 1 至 6 个碳原子的烷基、具有 1 至 4 个碳原子的三烷基硅基或芳基）。