5-对甲苯-1-乙烯基-1H-吡咯-2-羧酸 | 131172-66-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 中文名称: 5-对甲苯-1-乙烯基-1H-吡咯-2-羧酸
• 英文名称: 5-p-Tolyl-1-vinyl-1H-pyrrole-2-carboxylic acid
• 英文别名: 1-ethenyl-5-(4-methylphenyl)pyrrole-2-carboxylic acid
• CAS: 131172-66-2
• 化学式: C₁₄H₁₃NO₂
• 分子量: 227.263
• InChiKey: RNHLYONFHRHIPV-UHFFFAOYSA-N

物化性质

• 沸点：
  322.0±42.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  42.2
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 危险类别：
  IRRITANT

反应信息

• 作为产物：
  描述：

  2,2,2-Trifluoro-1-(5-p-tolyl-1-vinyl-1H-pyrrol-2-yl)-ethanone 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以82%的产率得到5-对甲苯-1-乙烯基-1H-吡咯-2-羧酸
  参考文献：
  名称：

  Synthesis of pyrrole-2-carboxylic acids and their N-vinyl derivatives

  摘要：

  DOI：

  10.1007/bf00487424

文献信息

• SOBENINA, L. N.;SERGEEVA, M. P.;MIXALEVA, A. I.;SIGALOV, M. V.;KOROSTOVA,+, XIMIYA GETEROTSIKL. SOED.,(1990) N, S. 612-616
  作者：SOBENINA, L. N.、SERGEEVA, M. P.、MIXALEVA, A. I.、SIGALOV, M. V.、KOROSTOVA,+

  DOI：——

  日期：——
• WATER BASED ANIONIC POLYMERS FOR INKJET INKS
  申请人：PENN COLOR, INC.

  公开号：US20140113990A1

  公开（公告）日：2014-04-24

  The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
• US9434849B2
  申请人：——

  公开号：US9434849B2

  公开（公告）日：2016-09-06
• Synthesis of pyrrole-2-carboxylic acids and their N-vinyl derivatives
  作者：L. N. Sobenina、M. P. Sergeeva、A. I. Mikhaleva、M. V. Sigalov、S. E. Korostova、N. I. Golovanova、V. N. Salaurov、E. V. Bakhareva、N. N. Vasil'eva

  DOI：10.1007/bf00487424

  日期：1990.5