fumaric acid allyl ester-methyl ester | 74856-71-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: fumaric acid allyl ester-methyl ester
• 英文别名: Fumarsaeure-allylester-methylester；1-O-methyl 4-O-prop-2-enyl (E)-but-2-enedioate
• CAS: 74856-71-6
• 化学式: C₈H₁₀O₄
• 分子量: 170.165
• InChiKey: UKIODLUVOCRHMM-SNAWJCMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  methyl (E)-4-chloro-4-oxo-2-butenoate 、 烯丙醇 在 吡啶 、 乙醚 作用下， 生成 fumaric acid allyl ester-methyl ester
  参考文献：
  名称：

  The Formation of Linear Polymers from Diene Monomers by a Cyclic Polymerization Mechanism. III. A Study of the Structure of Cyclic Polymers of Certain Unsymmetrical 1,6- and 1,7-Dienes^1,2

  摘要：

  DOI：

  10.1021/ja01531a026

文献信息

• CURATIVES FOR EPOXY ADHESIVE COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100113643A1

  公开（公告）日：2010-05-06

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  该发明提供了包括新型酰氧基和N-酰基固化剂的环氧树脂和氧环烷组合物。使用该发明的固化剂可使胶粘剂组合物固化后的粘附性大大增加，并且与用其他类型的固化剂固化的树脂相比，其亲水性减少。此外，该发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• CURATIVES FOR EPOXY COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100249276A1

  公开（公告）日：2010-09-30

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  本发明提供了环氧和氧杂环烷组分，包括本文所述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化的粘合剂组分具有显著增强的粘附性和降低的亲水性，与使用其他类型固化剂固化的树脂相比。此外，本发明的固化剂不干扰自由基固化，因此适用于混合固化热固性组分的使用。
• CURATIVES FOR EPOXY COMPOSITIONSERS
  申请人：Designer Molecules, Inc.

  公开号：US20130299747A1

  公开（公告）日：2013-11-14

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  本发明提供了环氧和氧杂环戊烷组合物，其中包括所述的新型酰氧基和N-酰基固化剂。使用本发明的固化剂可使固化粘合剂组合物的粘附性显著增加，并且与使用其他类型的固化剂固化的树脂相比，水亲和性降低。此外，本发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。
• Process for producing transparent material made of polylactic acid and transparent material made of polylactic acid
  申请人：Kanazawa Shinichi

  公开号：US20050242466A1

  公开（公告）日：2005-11-03

  The invention provides a process for producing a transparent polyactic acid material, comprising the steps of: kneading a polyactic acid with a monomer having two or more double bonds in its molecule; molding the kneaded product at a temperature of from the melting point of the polyactic acid to 200° C. to obtain a molded article; quenching the molded article after molding; and subjecting the quenched molded article to crosslinking treatment so as to prevent molecules of the polylactic acid from undergoing recrystallization. Also disclosed is a transparent polyactic acid material produced by the process.

  本发明提供了一种生产透明聚乳酸材料的工艺，包括以下步骤：用分子中含有两个或两个以上双键的单体捏合聚乳酸；在聚乳酸熔点至200℃的温度下模塑捏合产品，以获得模塑制品；模塑后对模塑制品进行淬火；以及对淬火后的模塑制品进行交联处理，以防止聚乳酸分子发生再结晶。还公开了一种通过该工艺生产的透明聚乳酸材料。