Bis-<2,2-dimethyl-propyl>-hydrogenphosphit | 54722-84-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Bis-<2,2-dimethyl-propyl>-hydrogenphosphit
• 英文别名: phosphonic acid bis-(2,2-dimethyl-propyl) ester；phosphorous acid bis-(2,2-dimethyl-propyl) ester；Bis(2,2-dimethylpropyl) hydrogen phosphite
• CAS: 54722-84-8
• 化学式: C₁₀H₂₃O₃P
• 分子量: 222.265
• InChiKey: FGDYPDTYJUUHRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Bis-<2,2-dimethyl-propyl>-hydrogenphosphit 在 氢碘酸 作用下， 生成 新戊基碘
  参考文献：
  名称：

  形成异构和光学纯的烷基卤化物的因素。第五部分。由2，2-二甲基丙烷-1-醇制备1-卤代-2,2-二甲基丙烷的过程中，确定2-卤代-2-甲基和2-卤代-3-甲基丁烷形成的条件

  摘要：

  气相色谱分析表明，由相应的醇制备1-卤代-2,2-二甲基丙烷可能伴随着2-卤代-2-甲基丁烷和2-卤代-3-甲基丁烷的形成。后者经常在溴化物或碘化物体系中观察到，并被认为是由于首先形成的叔卤化物的异构化导致的。据报道，在2，2-二甲基丙-1-醇与氢，磷和亚硫酰卤反应期间发生重排，并对各种制备方法进行了评估。

  DOI：

  10.1039/j29680000664
• 作为产物：
  描述：

  新戊醇 在 三溴化磷 作用下， 生成 Bis-<2,2-dimethyl-propyl>-hydrogenphosphit
  参考文献：
  名称：

  形成异构和光学纯的烷基卤化物的因素。第五部分。由2，2-二甲基丙烷-1-醇制备1-卤代-2,2-二甲基丙烷的过程中，确定2-卤代-2-甲基和2-卤代-3-甲基丁烷形成的条件

  摘要：

  气相色谱分析表明，由相应的醇制备1-卤代-2,2-二甲基丙烷可能伴随着2-卤代-2-甲基丁烷和2-卤代-3-甲基丁烷的形成。后者经常在溴化物或碘化物体系中观察到，并被认为是由于首先形成的叔卤化物的异构化导致的。据报道，在2，2-二甲基丙-1-醇与氢，磷和亚硫酰卤反应期间发生重排，并对各种制备方法进行了评估。

  DOI：

  10.1039/j29680000664

文献信息

• CHROMIUM-BASED CATALYST COMPOSITION FOR PRODUCING CONJUGATED DIENE POLYMERS
  申请人：Bridgestone Corp.

  公开号：US20020115558A1

  公开（公告）日：2002-08-22

  A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) a chromium-containing compound; (b) an organomagnesium compound; and (c) a silyl phosphonate. also, a process for forming conjugated diene polymers by using the catalyst composition.

  这是一个催化剂组合物的描述，由以下成分组成或反应生成：(a)含铬化合物；(b)有机镁化合物；和(c)硅基膦酸酯。同时，还提供了使用该催化剂组合物制备共轭二烯聚合物的方法。
• Syndiotactic 1,2-polybutadiene latex
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0357535A1

  公开（公告）日：1990-03-07

  This invention reveals a technique for preparing syndiotactic 1,2-polybutadiene latex. It more specifically discloses a process for synthesizing syndiotactic 1,2-polybutadiene latex by polymerizing 1,3-butadiene in an aqueous medium in the presence of (1) at least one emulsifier, (2) a catalyst emulsion composition which is prepared by a microfluidization or microemulsification process, and (3) at least one member selected from the group consisting of carbon disulfide and phenyl isothiocyanate. Such syndiotactic 1,2-polybutadiene latices can be utilized in preparing blends of syndiotactic 1,2-polybutadiene with rubbers which are prepared by emulsion polymerization.

  本发明揭示了一种制备聚对二甲苯-1,2-聚丁二烯胶乳的技术。更具体地说，它公开了一种在水介质中聚合 1，3-丁二烯，合成辛二聚 1，2-聚丁二烯胶乳的工艺，该工艺存在以下物质：(1) 至少一种乳化剂；(2) 通过微流化或微乳化工艺制备的催化剂乳液组合物；(3) 至少一种选自二硫化碳和异硫氰酸苯酯的成员。这种辛二烯-1,2-聚丁二烯乳液可用于制备辛二烯-1,2-聚丁二烯与通过乳液聚合法制备的橡胶的混合物。
• Syndiotactic 1,2-polybutadiene synthesis in an aqueous medium
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0475221A1

  公开（公告）日：1992-03-18

  Pure syndiotactic 1,2-polybutadiene is a thermoplastic resin which has double bonds attached in an alternating fashion to its polymeric backbone. Films, fibers and molded articles can be made utilizing syndiotactic 1,2-polybutadiene. It can also be blended into rubbers and cocured therewith. Syndiotactic 1,2-polybutadiene can be made by solution, emulsion or suspension polymerization. It typically has a melting point which is within the range of about 195°C to about 215°C. However, it is often desirable for the syndiotactic 1,2-polybutadiene to have a melting point of less than about 195°C. This invention discloses a process for preparing syndiotactic 1,2-polybutadiene having a melting point of less than about 195°C which comprises: polymerizing 1,3-butadiene monomer in an aqueous medium in the presence of (1) a catalyst composition which is made by reacting (a) at least one cobalt compound (b) at least one organoaluminum compound, and (c) at least one conjugated diene; (2) carbon disulfide; and (3) at least one modifier selected from the group consisting of (a) 4-(alkylamino)-benzaldehydes, (b) 4-(dialkylamino)benzaldehydes, (c) 2,4-di-(alkoxy)benzaldehydes, (d) 2,6-di-(alkoxy)-benzaldehydes, (e) 2,4,6-tri-(alkoxy)benzaldehydes, and (f) 4-(1-azacycloalkyl)benzaldehydes.

  纯对位 1,2-聚丁二烯是一种热塑性树脂，其聚合物骨架以交替方式连接双键。利用辛二聚丁二烯可以制成薄膜、纤维和模塑制品。它还可以与橡胶混合并与之共混。1,2-聚丁二烯可以通过溶液聚合、乳液聚合或悬浮聚合制成。其熔点通常在约 195°C 至约 215°C 之间。然而，通常希望辛二聚丁二烯的熔点低于约 195°C。本发明公开了一种制备熔点低于约 195°C 的辛二聚 1,2-聚丁二烯的工艺，该工艺包括： 1：在水介质中聚合 1,3-丁二烯单体，聚合时存在 (1) 催化剂组合物，该催化剂组合物由 (a) 至少一种钴化合物 (b) 至少一种有机铝化合物和 (c) 至少一种共轭二烯反应而成；(2) 二硫化碳；(3) 至少一种改性剂，该改性剂选自以下组别：(a) 4-(烷基氨基)-苯甲醛；(b) 4-(二烷基氨基)苯甲醛；(c) 2,4-二(烷氧基)苯甲醛；(d) 2,6-二(烷氧基)-苯甲醛；(e) 2,4,6-三(烷氧基)苯甲醛；(f) 4-(1-氮杂环烷基)苯甲醛。
• Syndiotactic 1,2-polybutadiene synthesis
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0877035A1

  公开（公告）日：1998-11-11

  Syndiotactic 1,2-polybutadiene is a thermoplastic resin which has double bonds attached in an alternating fashion to its polymeric backbone. Films, fibers and molded articles can be made utilizing syndiotactic 1,2-polybutadiene. It can also be blended into rubbers and cocured therewith. In such applications, sometimes it is beneficial for the syndiotactic 1,2-polybutadiene to have more than one melting point. This invention discloses a process for preparing syndiotactic 1,2-polybutadiene having at least two different melting points which comprises: polymerizing 1,3-butadiene monomer in an aqueous medium in the presence of (1) a catalyst composition which is made by reacting (a) at least one cobalt compound selected from the group consisting of (i) β-diketone complexes of cobalt, (ii) β-keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms and (c) at least one conjugated diene; (2) at least one member selected from the group consisting of carbon disulfide, phenyl isothiocyanate and xanthic acid; and (3) at least one melting-point regulator and (4) a sodium halide salt or a potassium halide salt.

  对位 1,2-聚丁二烯是一种热塑性树脂，其聚合物骨架以交替方式连接双键。利用对位 1,2-聚丁二烯可制成薄膜、纤维和模塑制品。它还可以混入橡胶中并与之共混。在此类应用中，有时辛二聚丁二烯具有一个以上的熔点是有益的。本发明公开了一种制备具有至少两个不同熔点的辛二聚丁二烯的工艺，该工艺包括在水介质中聚合 1,3-丁二烯单体，聚合过程中存在 (1) 催化剂组合物，该催化剂组合物是通过反应 (a) 至少一种钴化合物制成的，该钴化合物选自由以下组成的组 合：(i) 钴的β-二酮络合物；(ii) 钴的β-酮酸酯络合物；(iii) 具有 6 至 15 个碳原子的有机羧酸的钴盐；(iv) 式 CoXn 的卤代钴化合物络合物、其中 X 代表卤素原子，n 代表 2 或 3，与选自由叔胺醇、叔膦、酮和 N,N-二烷基酰胺组成的组的有机化合物的络合物；(b) 至少一种式 AlR3 的有机铝化合物，其中 R 代表 1 至 6 个碳原子的烃基；(c) 至少一种共轭二烯；(2) 至少一种选自二硫化碳、异硫氰酸苯酯和黄原酸的成员；以及 (3) 至少一种熔点调节剂和 (4) 卤化钠盐或卤化钾盐。
• Means to control practicle size and eliminate fouling in the synthesis of syndiotactic 1,2-polybutadiene
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0879834A1

  公开（公告）日：1998-11-25

  Syndiotactic 1,2-polybutadiene is a thermoplastic resin which has double bonds attached in an alternating fashion to its polymeric backbone. Films, fibers and molded articles can be made utilizing syndiotactic 1,2-polybutadiene. It can also be blended into rubbers and cocured therewith. It is generally preferred to synthesize syndiotactic 1,2-polybutadiene in an aqueous medium by suspension or emulsion polymerization. In such aqueous polymerization techniques reactor fouling and particle size control problems are frequently encountered. This invention is based upon the unexpected finding that reactor fouling can be greatly reduced or eliminated and that particle size can be regulated by conducting such aqueous polymerizations in the presence of a controlled amount of dissolved oxygen which is within the range of about 0.01 ppm to about 4 ppm. This invention more specifically discloses a process for preparing syndiotactic 1,2-polybutadiene in an aqueous medium with minimal reactor fouling which comprises polymerizing 1,3-butadiene monomer in the aqueous medium in the presence of (1) a catalyst system which is comprised of (a) transition metal compound, (b) an organoaluminum compound and (c) at least one member selected from the group consisting of carbon disulfide, phenyl isothiocyanate and xanthic acid and (2) from about 0.01 ppm to about 4 ppm of oxygen.

  对位 1,2-聚丁二烯是一种热塑性树脂，其聚合物骨架以交替方式连接双键。利用对位 1,2-聚丁二烯可制成薄膜、纤维和模塑制品。还可以将其混合到橡胶中并与之固化。一般来说，最好在水性介质中通过悬浮聚合或乳液聚合合成辛二素 1,2-聚丁二烯。在这种水性聚合技术中，经常会遇到反应器堵塞和粒度控制问题。本发明基于这样一个意外发现，即在可控的溶氧量（约 0.01 ppm 至约 4 ppm）范围内进行此类水性聚合，可大大减少或消除反应器堵塞，并可调节粒度。本发明更具体地公开了一种在水介质中制备辛二碳1,2-聚丁二烯且反应器堵塞最小的工艺，该工艺包括在水介质中聚合1,3-丁二烯单体，聚合过程中(1)催化剂体系由(a)过渡金属化合物、(b)有机铝化合物和(c)至少一种选自二硫化碳、苯基异硫氰酸酯和黄原酸组成的成员和(2)约0.01 ppm 至约 4 ppm 的氧气。