3,4-dimethacryloyloxytetrahydrofuran | 108578-91-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,4-dimethacryloyloxytetrahydrofuran
• 英文别名: [4-(2-Methylprop-2-enoyloxy)oxolan-3-yl] 2-methylprop-2-enoate
• CAS: 108578-91-2
• 化学式: C₁₂H₁₆O₅
• 分子量: 240.256
• InChiKey: GTMSWMQDLMUTSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基丙烯酰氯 、 cis-3,4-dihydroxytetrahydrofuran 在 三乙胺 作用下， 以 水 、 4-甲基-2-戊酮 为溶剂， 反应 10.25h， 以27.4%的产率得到3-methacryloyloxy-4-hydroxytetrahydrofuran
  参考文献：
  名称：

  WO2006/123473

  摘要：

  公开号：

文献信息

• (METH) ACRYLOYLOXYTETRAHYDROFURANS AND PROCESS FOR PRODUCTION THEREOF
  申请人：Kusaka Haruhiko

  公开号：US20090076201A1

  公开（公告）日：2009-03-19

  The present invention provides a (meth)acrylate containing a heterocyclic ring, which is a structure necessary for achieving physical properties required in many fields, and a hydrophilic group in the same monomer molecule and further provides a process for producing the same from industrially easily-available starting materials by industrially feasible reactions. A (meth)acryloyloxytetrahydrofuran having a structure represented by the following general formula (1): wherein R 1 and R 2 each is a hydrogen atom or a (meth)acryloyl group represented by the following general formula (2) and at least one of R 1 and R 2 is a (meth)acryloyl group represented by the general formula (2).
• MOLECULARLY IMPRINTED POLYMER FOR SELECTIVELY TRAPPING ODOROUS MOLECULES
  申请人：L'OREAL

  公开号：US20150320667A1

  公开（公告）日：2015-11-12

  The invention relates to the use of molecularly imprinted polymer(s) or MIPs, of odorous molecule(s), as deodorant agent in particular for selectively trapping molecules that are the cause of human body odour. More particularly by using MIPs which may be obtained via polymerization, preferably via radical polymerization, of a mixture of: i) optionally one or more polymerization initiator(s); ii) one or more functional monomer(s); iii) one or more crosslinking agent(s); and iv) one or more porogenic solvent(s); it being understood that the polymerization a) or b) is performed in the presence v) of one or more “templates” of target molecule(s) responsible for human body odour. Another subject of the invention concerns a process for preparing MIPs as defined previously, MIPs obtained via this process, and a cosmetic composition comprising at least one MIP as defined previously. Unexpectedly, it appears that the MIPs make it possible to specifically trap precursors of odorous molecules and odorous molecules that may be used in cosmetic formulations, especially those that are the cause of the unpleasant odour of sweat.
• MOLECULARLY IMPRINTED POLYMERS AND THEIR USE AS ANTIDANDRUFF AGENTS
  申请人：L'OREAL

  公开号：US20150342859A1

  公开（公告）日：2015-12-03

  The invention relates to a molecularly imprinted polymer obtained by polymerization of a mixture comprising a basic ethylene monomer having an amine group, a crosslinking agent comprising at least 2 polymerizable ethylene unsaturations, a porogenic solvent and a C 14 -C 20 fatty acid. A cosmetic composition comprising such a polymer. A cosmetic process to prevent and/or treat dandruff of the scalp using such a polymer.
• WO2006/123473
  申请人：——

  公开号：——

  公开（公告）日：——