-bis-<2-hydroxy-propyl>-amin | 16889-06-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: -bis-<2-hydroxy-propyl>-amin
• 英文别名: N-Allyl-diisopropanolamin；allyl-bis-(2-hydroxy-propyl)-amine；1,1'-(2-Propen-1-ylimino)bis[2-propanol]；1-[2-hydroxypropyl(prop-2-enyl)amino]propan-2-ol
• CAS: 16889-06-8
• 化学式: C₉H₁₉NO₂
• 分子量: 173.255
• InChiKey: JHHCQWBYIIKQGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  43.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  -bis-<2-hydroxy-propyl>-amin 、 甲基丙烯酸甲酯 在 吩噻嗪 、 sodium methylate 作用下， 以 甲醇 为溶剂， 生成 N-Allyl-diisopropanolamin-dimethacrylat
  参考文献：
  名称：

  Korshunov,M.A.; Bodnaryuk,F.N., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, # 7, p. 1157 - 1161

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烯胺 、 methyloxirane 在 水 作用下， 生成 -bis-<2-hydroxy-propyl>-amin
  参考文献：
  名称：

  SYNTHESIS OF N-SUBSTITUTED DIISOPROPANOLAMINES, THEIR SEBACATE POLYESTERS AND POLYURETHANE ELASTOMERS

  摘要：

  通过在常压下，将胺的水溶液与过量的丙烯氧基反应，制备了几种N-取代二异丙醇胺。但是，较高的N-取代二异丙醇胺必须在200°C的高压釜中制备。这些碱的解离常数被测量并记录为pK_a值。它们的红外吸收光谱显示出所有二异丙醇胺共有的频带，主要在3.04、7.14、7.55、7.85、9.45、10.6和11.95微米处。它们与癸二酸的缩聚产物是相应的聚酯，溶解在强酸中，分子量约为1500。羟基终止的聚酯在100°C下与轻微过量的2,4-甲苯二异氰酸酯固化2天，形成具有脆性温度在-50°C左右的弹性体。

  DOI：

  10.1139/v58-206

文献信息

• SYNTHESIS OF N-SUBSTITUTED DIISOPROPANOLAMINES, THEIR SEBACATE POLYESTERS AND POLYURETHANE ELASTOMERS
  作者：Jean L. Boivin

  DOI：10.1139/v58-206

  日期：1958.10.1

  Several N-substituted diisopropanolamines were prepared by reacting aqueous solutions of amines with excess propylene oxide at ordinary pressure but higher N-substituted diisopropanolamines had to be prepared in an autoclave at 200 °C. The ionization constants of these bases were measured and recorded as pK_a values. Their infrared absorption spectra gave bands common to all diisopropanolamines mainly at 3.04, 7.14, 7.55, 7.85, 9.45, 10.6, and 11.95 microns. Their condensation with sebacic acid gave the corresponding polyesters, which were soluble in strong acids and had molecular weights of about 1500. The hydroxyl-terminated polyesters were cured with a slight excess of 2,4-tolylene diisocyanate at 100 °C for 2 days to yield elastomers of brittle temperatures in the region of −50 °C.

  通过在常压下，将胺的水溶液与过量的丙烯氧基反应，制备了几种N-取代二异丙醇胺。但是，较高的N-取代二异丙醇胺必须在200°C的高压釜中制备。这些碱的解离常数被测量并记录为pK_a值。它们的红外吸收光谱显示出所有二异丙醇胺共有的频带，主要在3.04、7.14、7.55、7.85、9.45、10.6和11.95微米处。它们与癸二酸的缩聚产物是相应的聚酯，溶解在强酸中，分子量约为1500。羟基终止的聚酯在100°C下与轻微过量的2,4-甲苯二异氰酸酯固化2天，形成具有脆性温度在-50°C左右的弹性体。
• Cosmetic composition comprising at least one cyclic carbonate
  申请人：——

  公开号：US20040156800A1

  公开（公告）日：2004-08-12

  A cosmetic composition comprising, in a cosmetically acceptable medium, at least one cyclic carbonate capable of polymerizing under an external stimulus, in combination with at least one compound chosen from anionic fixative polymers, nonionic fixative polymers, amphoteric fixative polymers, conditioning agents, anionic direct dyes, quaternized cationic direct dyes, oxidation dyes, reducing agents, surfactants, and oxidizing agents, and method for treatment of hair, eyelashes, skin, and/or nails using said composition.

  一种化妆品组合物，包含在化妆品可接受介质中的至少一种能在外部刺激下聚合的环状碳酸盐，与至少一种选自阴离子固色聚合物、非离子固色聚合物、两性固色聚合物、调理剂、阴离子直接染料、季铵化阳离子直接染料、氧化染料、还原剂、表面活性剂和氧化剂的化合物，以及使用所述组合物处理头发、睫毛、皮肤和/或指甲的方法。
• VOC free latex coalescent systems
  申请人：Sugerman Gerald

  公开号：US20050014877A1

  公开（公告）日：2005-01-20

  Combinations of essentially nonvolatile, unsaturated ethers and/or esters, and small proportions of low glass transition temperature (Tg) latex reins, as replacements for volatile organic compounds (VOCs) as coalescents and optionally reactive amines (as replacements for conventionally employed volatile amines/ammonia neutralizers, respectively), provides economical, low/no VOC-containing acrylic, styrenic copolymer, polyester, polyurethane and vinyl copolymer latex based coatings, paints, and inks; which outperform their conventional counterparts.

  将基本不挥发的不饱和醚和/或酯与小比例的低玻璃化转变温度（Tg）乳胶缰绳相结合，作为凝聚剂和可选活性胺（分别作为传统使用的挥发性胺/氨中和剂的替代品）的挥发性有机化合物（VOC）替代品，可提供经济、低/无 VOC 含量的丙烯酸、苯乙烯共聚物、聚酯、聚氨酯和乙烯基共聚物乳胶基涂料、油漆和油墨；其性能优于传统的同类产品。
• FRICTION MODIFIERS AND A METHOD OF MAKING THE SAME
  申请人：Chevron Oronite Company LLC

  公开号：EP2914704A1

  公开（公告）日：2015-09-09
• COMPOSITION FOR CARING FOR KERATIN FIBERS AND USE THEREOF FOR CLEANSING AND CONDITIONING THE KERATIN FIBERS
  申请人：L'Oréal

  公开号：EP2938322A1

  公开（公告）日：2015-11-04