4-[2-(4-Tert-butylphenoxy)ethoxy]benzaldehyde

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[2-(4-Tert-butylphenoxy)ethoxy]benzaldehyde
• 化学式: C₁₉H₂₂O₃
• 分子量: 298.382
• InChiKey: BEXVFDAEAFDKSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,2'-二吡咯基甲烷 、 4-[2-(4-Tert-butylphenoxy)ethoxy]benzaldehyde 在 氢气 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 生成
  参考文献：
  名称：

  Efficient combination of calix[4]arenes and meso-diphenylporphyrins

  摘要：

  The selective mono-alkylation of a calix[4]arene with a functionalized benzaldehyde followed by the condensation with dipyrrylmethane afforded in good yield a porphyrin substituted by two calix[4]arenes. The same multisite ligand was alternatively obtained by double monoalkylation of two calix[4]arenes with a functionalized porphyrin. The two calixarene units are in cone shape and thus can accomodate neutral organic guests. The efficiency of the fluorescence quenching of two porphyrins by benzoquinone has been evaluated and compared. In a first approximation, Stern-Volmer plots provide evidence for an enhanced quenching when calixarene hosts are bound to the porphyrin.

  DOI：

  10.1016/0040-4039(95)00437-h