3-Decylpyrrole | 120394-63-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 3-Decylpyrrole
• 英文别名: 3-Decyl-1H-pyrrole
• CAS: 120394-63-0
• 化学式: C₁₄H₂₅N
• 分子量: 207.359
• InChiKey: FFRZVVFLHHGORC-UHFFFAOYSA-N

物化性质

• 沸点：
  309.9±11.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-[1-(Benzenesulfonyl)pyrrol-3-yl]decan-1-one 在 sodium tetrahydroborate 、 sodium hydroxide 作用下， 以 1,4-二氧六环 、 异丙醇 为溶剂， 反应 30.0h， 生成 3-Decylpyrrole
  参考文献：
  名称：

  天然和合成 Prodiginines 的抗疟活性

  摘要：

  Prodiginines 是一系列线性和环状低聚吡咯红色颜料化合物。在此，我们描述了四种天然 (IC 50 = 1.7–8.0 nM) 和三组合成 prodiginine 对恶性疟原虫的体外抗疟活性。第 1 组化合物取代了天然 prodiginines 的末端非烷基化吡咯环并且活性降低 (IC 50 > 2920 nM)。第 2 组和第 3 组 prodiginine 分别在右手端吡咯的 3 或 5 位被单取代或双取代。使用烷基或芳基取代基观察到有效的体外活性 (IC 50 = 0.9–16.0 nM)。在P. yoelii中评估了 Metacycloprodiginine 和更有效的合成类似物使用口服给药的鼠专利感染。每种类似物在每天 25 (mg/kg) 给药后将寄生虫血症降低了 90% 以上，并且在某些情况下可以治愈。最有利的特征是 5 (mg/kg)/天的寄生虫减少 92%，25 (mg/kg)/天的寄生虫减少

  DOI：

  10.1021/jm200543y

文献信息

• Organometallic Complex, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using the Organometallic Complex
  申请人：Inoue Hideko

  公开号：US20080312437A1

  公开（公告）日：2008-12-18

  According to the present invention, a wider variation of organometallic complexes that can emit phosphorescence can be provided by applying, as a ligand, an organic compound from which a variety of derivatives can be easily synthesized. In particular, an organometallic complex having a sharp emission spectrum is provided. Further, an organometallic complex having high emission efficiency is provided. An organometallic complex represented by the general formula (G1) is provided. In the formula, Ar represents an aryl group, R represents an alkoxy group having 1 to 4 carbon atoms, and R 1 and R 2 individually represent either hydrogen or an alkyl group having 1 to 4 carbon atoms.

  根据本发明，通过应用一种作为配体的有机化合物，可以提供更广泛的能够发射磷光的有机金属配合物变体，从而可以轻松合成各种衍生物。特别地，提供了具有尖锐发射光谱的有机金属配合物。此外，提供了具有高发射效率的有机金属配合物。提供了由通式（G1）表示的有机金属配合物。在该式中，Ar代表芳基，R代表具有1至4个碳原子的烷氧基，R1和R2分别表示氢或具有1至4个碳原子的烷基。
• Exclusive Synthesis of β-Alkylpyrroles under Indium Catalysis: Carbonyl Compounds as Sources of Alkyl Groups
  作者：Teruhisa Tsuchimoto、Motohiro Igarashi、Kazuki Aoki

  DOI：10.1002/chem.201000733

  日期：——

  mixing readily available carbonyl compounds, pyrroles, and nucleophiles with an indium catalyst was found to give β‐alkylpyrroles in a regiospecific manner. Removal of benzyl (Bn) and cumyl groups from the nitrogen atoms of the products enables access to nitrogen‐unsubstituted β‐alkylpyrroles (see scheme).

  不再困难：仅将易于获得的羰基化合物，吡咯和亲核试剂与铟催化剂混合，即可以区域特异性方式产生β-烷基吡咯。从产品的氮原子中除去苄基（Bn）和枯基，可以使用未取代氮的β-烷基吡咯（请参阅方案）。
• RESIN MODIFIER
  申请人：Kitayama Hiroaki

  公开号：US20120263883A1

  公开（公告）日：2012-10-18

  The present invention provides a resin modifier capable of obtaining a coating film having satisfactory basic performances such as antistatic properties, water resistance and transparency, a method for producing a coating film using the resin modifier, and a coating film obtained by the production method. The resin modifier of the present invention is a resin modifier represented by R 31 —O-(AO) n —SO 3 − , R 32 —OSO 3 − , or R 33 —SO 3 − and an ammonium ion that has a polymerizable unsaturated group.

  本发明提供了一种树脂改性剂，能够获得具有良好基本性能，如抗静电性能、耐水性和透明性的涂层膜，以及使用该树脂改性剂生产涂层膜的方法和通过该生产方法获得的涂层膜。本发明的树脂改性剂是由R31—O-(AO)n—SO3−、R32—OSO3−或R33—SO3−和具有聚合可不饱和基团的铵离子表示的树脂改性剂。
• Acenaphthopyridine Derivative, Material of Light-Emitting Element, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance
  申请人：Takasu Takako

  公开号：US20090247753A1

  公开（公告）日：2009-10-01

  It is an object to provide a new compound which is suitable for a material of an electron-transporting layer of a light-emitting element. In particular, it is an object to provide a compound which can be used for forming a light-emitting element capable of emitting light at a low drive voltage. An acenaphthopyridine derivative represented by the following general formula (G1) is provided. In the formula, Het represents a pyridyl group or a quinolyl group.

  提供一种适用于发光元件电子传输层材料的新化合物是一个目标。特别是，提供一种可用于形成能够以低驱动电压发光的发光元件的化合物是一个目标。提供了以下一般式（G1）所代表的一种蒽醌吡啶衍生物。在该式中，Het代表吡啶基团或喹啉基团。
• WATER-SOLUBLE COMPOSITION, PRODUCTION METHOD FOR CURED PRODUCT THEREOF, AND CURED PRODUCT THEREOF, AND ACYL PHOSPHINATE
  申请人：ADEKA CORPORATION

  公开号：US20200032021A1

  公开（公告）日：2020-01-30

  Provided are: a water-soluble composition which has excellent storage stability and is adaptable to a wide range of light sources and capable of forming a highly fine pattern; a method of producing a cured product of the same; a cured product of the same; and an acylphosphinate. The water-soluble composition contains: an acylphosphinate (A) represented by Formula (I) below, wherein X 1 represents an aryl group having 6 to 15 carbon atoms; X 2 represents a linear alkyl group having 1 to 8 carbon atoms or the like; A m+ represents an alkali metal ion or the like; and m represents a number of 1 to 3; and a compound (B) having a group represented by Formula (II) below, wherein R 1 represents a hydrogen atom or the like; Z 1 represents an oxygen atom or the like; R 2 represents a hydrogen atom or the like; Z 2 represents an alkylene group having 1 to 6 carbon atoms; n represents a number of 0 to 30; * means a bond; and, when the compound (B) has plural groups represented by Formula (II), plural R 1′ s, Z 1′ s, Z 2′ s and n's are each optionally the same or different.

  提供了以下内容：一种水溶性组合物，具有优异的储存稳定性，适用于广泛的光源，并能形成高度精细的图案；一种制备该固化产品的方法；一种该固化产品；以及一种酰基膦酸酯。水溶性组合物包含：由下式（I）表示的酰基膦酸酯（A），其中X1表示具有6到15个碳原子的芳基基团；X2表示具有1到8个碳原子的线性烷基基团或类似物；Am+表示碱金属离子或类似物；m表示1到3的数字；以及具有下式（II）表示的基团的化合物（B），其中R1表示氢原子或类似物；Z1表示氧原子或类似物；R2表示氢原子或类似物；Z2表示具有1到6个碳原子的烷基基团；n表示0到30的数字；*表示一个键；当化合物（B）具有由式（II）表示的多个基团时，多个R1'、Z1'、Z2'和n'可以是任意相同或不同。