ethyl 2,2,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecanoate | 202826-14-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: ethyl 2,2,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecanoate
• 英文别名: ethyl 3,3,4,4-tetrahydroperfluorodecanoate
• CAS: 202826-14-0
• 化学式: C₁₂H₉F₁₅O₂
• 分子量: 470.178
• InChiKey: KAAPXVQXUOOTBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  ethyl 2,2,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecanoate 在 盐酸 、 sodium hydroxide 作用下， 以96.7%的产率得到2,2,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecanoic acid
  参考文献：
  名称：

  Hydrogen-containing flourosurfacant and its use in polymerization

  摘要：

  一种部分氟化表面活性剂，具有内部亚甲基基团，其化学式为R.sub.f --(CH.sub.2).sub.m --R'.sub.f --COOM，其中m为1-3，R.sub.f为含有3-8个碳原子的全氟烷基或全氟烷氧基，R'.sub.f为线性或支链全氟烷基烯，含有1-4个碳原子，M为NH.sub.4，Li，Na，K或H，在氟化单体的聚合中非常有用。在四氟乙烯的同聚合中可以实现高分子量。

  公开号：

  US05763552A1

文献信息

• POLY(METH)ACRYLAMIDES AND POLY(METH)ACRYLATES CONTAINING FLUORINATED AMIDE
  申请人：Qiu Weiming

  公开号：US20100233419A1

  公开（公告）日：2010-09-16

  A composition comprising a copolymer having repeating units in any sequence of Formula I wherein R f is a straight or branched perfluoroalkyl group having from about 1 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, X 3 is oxygen or X 1 , each X 1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing an oxygen, nitrogen, or sulfur, or a combination thereof, G is F or CF 3 , A is an amide, j is zero or positive integer, X 2 is an organic linking group, Y is O, N or S, h is zero when Y is N, and h is one when Y is O or S, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, B is H or wherein R f , X 1 , X 3 , G, A, and j are as defined above, provided that when B is H, j is a positive integer, m is a positive integer, q is zero or a positive integer when Y is O, and q is a positive integer when Y is N or S, p is zero or a positive integer when Y is O, and p is a positive integer when Y is N or S, each W is independently various copolymer units.

  一种包含具有任何顺序的重复单元的共聚物的组合物，其化学式为I，其中Rf是直链或支链的全氟烷基基团，具有约1到约20个碳原子，或二者的混合物，可由至少一个氧原子中断，X3是氧或X1，每个X1独立地是具有约1到约20个碳原子的有机二价连接基团，可包含氧、氮或硫，或二者的组合，G是F或CF3，A是酰胺，j是零或正整数，X2是有机连接基团，Y是O、N或S，当Y是N时，h为零，当Y是O或S时，h为一，Z是H，直链或支链的具有约1到约4个碳原子的烷基基团，或卤素，B是H或，其中Rf、X1、X3、G、A和j如上所定义，但当B为H时，j为正整数，m为正整数，当Y为O时，q为零或正整数，当Y为N或S时，q为正整数，当Y为O时，p为零或正整数，当Y为N或S时，p为正整数，每个W独立地是各种共聚物单元。
• Composition containing fluorinated amide
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2287270A2

  公开（公告）日：2011-02-23

  A composition comprising Formula 3, wherein Rf is a linear perfluoroalkyl group having from 1 to 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, X3 is oxygen or X1, each X1 is independently an organic divalent linking group having from 1 to 20 carbon atoms, optionally containing an oxygen, nitrogen, or sulfur, or a combination thereof, G is F or CF3, A is an amide, j is zero or positive integer, provided that when Y is N, j is a positive integer, X2 is an organic linking group, Y is O, N or S, h is zero when Y is N, and h is one when Y is O or S, Z is H, a straight or branched alkyl group having from 1 to 4 carbon atoms, or halide, and B is H or Formula (B), wherein Rf, X1, X3, G, A, and j are as defined above, and E is selected from the group consisting of hydroxyl, amine, halogen and thiol, provided that h is zero when E is amine, and h is one when E is other than amine.

  一种包含式 3 的组合物，其中 Rf 是具有 1 至 20 个碳原子的线性全氟烷基，或其混合物，可选被至少一个氧原子打断，X3 是氧或 X1，每个 X1 独立地是具有 1 至 20 个碳原子的有机二价连接基团，可选含有氧、氮或硫，或其组合，G 是 F 或 CF3，A 是酰胺，j 是零或正整数，条件是当 Y 是 N、j 为正整数，X2 为有机连接基团，Y 为 O、N 或 S，Y 为 N 时 h 为零，Y 为 O 或 S 时 h 为一，Z 为 H、具有 1 至 4 个碳原子的直链或支链烷基或卤化物，B 为 H 或式 (B)、其中 Rf、X1、X3、G、A 和 j 如上定义，E 选自羟基、胺、卤素和硫醇组成的组，但当 E 为胺时，h 为零，当 E 不是胺时，h 为一。
• Hydrogen-containing fluorosurfactant and its use in polymerisation
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0822175B1

  公开（公告）日：2001-05-16
• Poly(meth)acrylamides and poly(meth)acrylates containing fluorinated amide
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2251363B1

  公开（公告）日：2012-12-26
• Compound containing a fluorinated amide group
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP2287270B1

  公开（公告）日：2013-04-03