1,10-di(3,4,5-trihydroxybenzoyloxy)decane | 877395-07-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,10-di(3,4,5-trihydroxybenzoyloxy)decane
• 英文别名: 10-(3,4,5-Trihydroxybenzoyl)oxydecyl 3,4,5-trihydroxybenzoate；10-(3,4,5-trihydroxybenzoyl)oxydecyl 3,4,5-trihydroxybenzoate
• CAS: 877395-07-8
• 化学式: C₂₄H₃₀O₁₀
• 分子量: 478.496
• InChiKey: SQELJNAKNQDUEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  34
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  174
• 氢给体数：
  6
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,10-di(3,4,5-trihydroxybenzoyloxy)decane 、 3,4,5-tris(benzyloxy)benzoyl chloride 在 吡啶 、 4-二甲氨基吡啶 作用下， 以 氯仿 为溶剂， 以37.9%的产率得到1,10-di(3,4,5-tri(3,4,5-tribenzyloxybenzoyloxy)benzoyloxy)decane
  参考文献：
  名称：

  Chemiluminescence Change of Polyphenol Dendrimers with Different Core Molecules

  摘要：

  Second generation polyphenol dendrimers (PDs) with different core molecules were synthesized, and their chemiluminescence (CL) was measured by reacting the PDs with H2O2 under alkaline conditions. All of the PDs showed a strong CL, more than 120-fold greater than that of gallic acid. Various CL intensities of the PDs were obtained using different core molecules in the PDs. The distance between each dendron in the PD structure is crucial in the PD CL intensity.

  DOI：

  10.1021/ol802129a
• 作为产物：
  描述：

  1,10-di(3,4,5-tribenzyloxybenzoyloxy)decane 在 氢气 、 钯 作用下， 以 甲醇 、 氯仿 为溶剂， 以95.8%的产率得到1,10-di(3,4,5-trihydroxybenzoyloxy)decane
  参考文献：
  名称：

  Chemiluminescence Change of Polyphenol Dendrimers with Different Core Molecules

  摘要：

  Second generation polyphenol dendrimers (PDs) with different core molecules were synthesized, and their chemiluminescence (CL) was measured by reacting the PDs with H2O2 under alkaline conditions. All of the PDs showed a strong CL, more than 120-fold greater than that of gallic acid. Various CL intensities of the PDs were obtained using different core molecules in the PDs. The distance between each dendron in the PD structure is crucial in the PD CL intensity.

  DOI：

  10.1021/ol802129a

文献信息

• Chemiluminescence Change of Polyphenol Dendrimers with Different Core Molecules
  作者：Hiroki Agawa、Manabu Nakazono、Shinkoh Nanbu、Kiyoshi Zaitsu

  DOI：10.1021/ol802129a

  日期：2008.11.20

  Second generation polyphenol dendrimers (PDs) with different core molecules were synthesized, and their chemiluminescence (CL) was measured by reacting the PDs with H2O2 under alkaline conditions. All of the PDs showed a strong CL, more than 120-fold greater than that of gallic acid. Various CL intensities of the PDs were obtained using different core molecules in the PDs. The distance between each dendron in the PD structure is crucial in the PD CL intensity.