2,5-Dibromo-3-tert-butylpyrrole-1-carboxylic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2,5-Dibromo-3-tert-butylpyrrole-1-carboxylic acid
• 英文别名: 2,5-dibromo-3-tert-butylpyrrole-1-carboxylic acid
• 化学式: C₉H₁₁Br₂NO₂
• 分子量: 325.0
• InChiKey: MWYANXDNAGUHLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  42.2
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• ONO PINCER LIGANDS AND ONO PINCER LIGAND COMPRISING METAL COMPLEXES
  申请人：UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

  公开号：US20140073800A1

  公开（公告）日：2014-03-13

  Embodiments of the invention are directed to ONO pincer ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a transition metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the transition metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are three sp 2 hybridized carbons or the three atoms are a pair of sp 2 hybridized carbons and an sp 3 hybridized carbon or silicon.

  本发明的实施例涉及可以处于三阴离子、质子化或质子化等效形式的ONO夹持配体。ONO夹持配体可以与含有过渡金属的化合物结合，形成含有过渡金属的ONO夹持配体配合物。通过选择ONO夹持配体结构，可以控制过渡金属配合物的立体和电子性质。ONO夹持配体包括一个中心氮原子，该中心氮原子被一对三原子桥连接，其中三个原子是三个sp2杂化碳或一对sp2杂化碳和一个sp3杂化碳或硅原子。
• ONO Pincer Ligands and ONO Pincer Ligand Comprising Metal Complexes
  申请人：University of Florida Research Foundation, Inc.

  公开号：US20170022230A1

  公开（公告）日：2017-01-26

  Embodiments of the invention are directed to ONO pincer ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are a pair of sp 2 hybridized carbons and an sp 3 hybridized carbon.
• US9464104B2
  申请人：——

  公开号：US9464104B2

  公开（公告）日：2016-10-11
• US9765102B2
  申请人：——

  公开号：US9765102B2

  公开（公告）日：2017-09-19