N-[[10-[[2-[bis(pyridin-2-ylmethyl)amino]ethylamino]methyl]anthracen-9-yl]methyl]-N',N'-bis(pyridin-2-ylmethyl)ethane-1,2-diamine | 1218934-50-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-[[10-[[2-[bis(pyridin-2-ylmethyl)amino]ethylamino]methyl]anthracen-9-yl]methyl]-N',N'-bis(pyridin-2-ylmethyl)ethane-1,2-diamine
• CAS: 1218934-50-9
• 化学式: C₄₄H₄₆N₈
• 分子量: 686.903
• InChiKey: ODROSGITDAMEBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  52
• 可旋转键数：
  18
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  82.1
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  9,10-二甲酰基蒽 、 N,N-二(2-吡啶甲基)乙二胺 在 sodium tetrahydroborate 作用下， 以 二氯甲烷 、 甲醇 为溶剂， 反应 12.0h， 以85%的产率得到N-[[10-[[2-[bis(pyridin-2-ylmethyl)amino]ethylamino]methyl]anthracen-9-yl]methyl]-N',N'-bis(pyridin-2-ylmethyl)ethane-1,2-diamine
  参考文献：
  名称：

  Fluorescent Zn2+ chemosensors, functional in aqueous solution under environmentally relevant conditions

  摘要：

  The synthesis and evaluation of two new ratiometric chemosensors for the quantification of potentially toxic free Zn2+ ions in aqueous solutions are described. Both sensors show high selectivity for Zn2+ over other cations, and are functional at environmentally relevant pH with detection limits of 0.05 mu M for free Zn2+. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.12.069

文献信息

• Fluorescent Zn2+ chemosensors, functional in aqueous solution under environmentally relevant conditions
  作者：Amanda E. Lee、Michael R. Grace、Adam G. Meyer、Kellie L. Tuck

  DOI：10.1016/j.tetlet.2009.12.069

  日期：2010.2

  The synthesis and evaluation of two new ratiometric chemosensors for the quantification of potentially toxic free Zn2+ ions in aqueous solutions are described. Both sensors show high selectivity for Zn2+ over other cations, and are functional at environmentally relevant pH with detection limits of 0.05 mu M for free Zn2+. (C) 2009 Elsevier Ltd. All rights reserved.