(2E,6E)-2,6-bis[4-(dimethylamino)benzylidene]-4-methylcyclohexanone

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: (2E,6E)-2,6-bis[4-(dimethylamino)benzylidene]-4-methylcyclohexanone
• 英文别名: (2E,6E)-2,6-bis[[4-(dimethylamino)phenyl]methylidene]-4-methylcyclohexan-1-one
• 化学式: C₂₅H₃₀N₂O
• 分子量: 374.5
• InChiKey: YXQINXKZKRYRQM-LPFJTETCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-甲基环己酮 、 对二甲氨基苯甲醛 以54%的产率得到
  参考文献：
  名称：

  ORLOV V. D.; TROYAN V. N., BECT. XARKOV. YH-TA, 1980, HO 202, 30-33

  摘要：

  DOI：

文献信息

• Curable composition
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0203393A1

  公开（公告）日：1986-12-03

  A curable composition comprising (a) a curable polyimide soluble in organic solvents and (b) a polymerization initiator as essential components, said polyimide consisting of recurring units represented by the formula wherein, each of X, X1, X2, X3 and X4 is a tetravalent carbocyclic or heterocyclic residue, each of Y1, Y2 and Y3 is a divalent carbocyclic or heterocyclic residue, at least one of Z1 and Z2 is a residue having a reactive carbon-carbon double bond, and each of I, m, and n is an integer of 0 or larger.

  一种可固化组合物，包括(a)可溶于有机溶剂的可固化聚酰亚胺和(b)作为基本成分的聚合引发剂，所述聚酰亚胺由由式表示的递归单元组成 其中，X、X1、X2、X3 和 X4 中的每一个是四价碳环或杂环残基，Y1、Y2 和 Y3 中的每一个是二价碳环或杂环残基，Z1 和 Z2 中的至少一个是具有活性碳碳双键的残基，I、m 和 n 中的每一个是 0 或更大的整数。
• A precursor of a low thermal stress polyimide and a photopolymerizable composition containing a polyimide precursor
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0355927A2

  公开（公告）日：1990-02-28

  Disclosed is a polyimide precursor comprising a specific polyamic acid ester, polyamic amide or polyamic acid salt structure derived from a tetracarboxylic acid compound and a diamine compound, which can be converted by heating to a polyimide having low thermal stress. By blending a specific form of this novel polyimide precursor which has an ethylenic double bond, with a photopolymerization initiator, an excellent photopolymerizable composition can be obtained. Not only this precursor but also the crosslinked precursor obtained by the photopolymerization of the photopolymerizable composition can be converted by heating to a polyimide resin which has low thermal expansion coefficient, high heat resistance, excellent mechanical properties and satisfactory adhesion to a substrate. Hence, the precursor and the photopolymerizable composition can advantageously be utilized in the production of electrical and electronic components.

  本发明公开了一种聚酰亚胺前体，它由特定的聚酰胺酸酯、聚酰胺或聚酰胺酸盐结构组成，由四羧酸化合物和二胺化合物衍生而成，可通过加热转化为具有低热应力的聚酰亚胺。将这种具有乙烯双键的新型聚酰亚胺前体的特定形式与光聚合引发剂混合，可以得到一种极佳的光聚合组合物。不仅是这种前体，通过光聚合反应得到的交联前体也可以通过加热转化为聚酰亚胺树脂，这种树脂具有低热膨胀系数、高耐热性、优异的机械性能以及与基材的良好粘合性。因此，这种前体和可光聚合组合物可以很好地用于电气和电子元件的生产。
• Photosensitive resin composition and semiconductor apparatus using it
  申请人：SUMITOMO BAKELITE COMPANY LIMITED

  公开号：EP0430220A2

  公开（公告）日：1991-06-05

  The present invention provides a photosensitive resin composition which comprises as essential components: (A) a polyamic acid having a recurring unit represented by the following formula [I]: wherein 0.5-50 mol% of R₁ consists of a silicone diamine residue represented by the following formula [II]: wherein n represents an integer of 1-50, and the remainder of 50-99.5 mol% of R₁ consists of an organic group selected from the group consisting of an aromatic group, an aliphatic group, an alicyclic group, and a heterocyclic group, and R₂ consists of an organic group selected from the group consisting of an aromatic group, an aliphatic group, an alicyclic group, a heterocyclic group, and a silicone group, and m represents 1 or 2, (B) an amide compound having carbon-carbon double bond, and (C) a photosensitizer. The present invention further provides a semiconductor apparatus in which the above composition is used.

  本发明提供了一种光敏树脂组合物，其主要成分包括 (A) 具有下式[I]代表的递归单元的聚酰胺酸： 其中0.5-50 摩尔%的R₁由下式[II]代表的有机硅二胺残基组成： 其中n代表1-50的整数，其余50-99.5 mol％的R₁由选自芳香族基团、脂肪族基团、脂环族基团和杂环族基团的有机基团组成，R₂由选自芳香族基团、脂肪族基团、脂环族基团、杂环族基团和硅酮基团的有机基团组成，m代表1或2、 (B) 具有碳碳双键的酰胺化合物，和 (C) 一种光敏剂。 本发明进一步提供了一种使用上述组合物的半导体装置。
• CERAMIC GREEN SHEET
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0602252A1

  公开（公告）日：1994-06-22

  A ceramic green sheet used suitably for the formation of a sintered ceramic substrate, which contains a ceramic powder and a photosensitive resin composition. Fine via-holes and through-holes of accurate size can be formed in the green sheet easily, reliably and economically.

  一种适用于形成烧结陶瓷基板的陶瓷绿片，它包含陶瓷粉末和光敏树脂成分。在这种绿色薄片上可以轻松、可靠、经济地形成尺寸精确的细孔和通孔。
• PHOTOSENSITIVE PASTE, PLASMA DISPLAY, AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0775940A1

  公开（公告）日：1997-05-28

  To provide a photosensitive paste that permits pattern formation with a high aspect ratio and a high accuracy and to provide a plasma display comprising said photosensitive paste, by using a photosensitive paste that comprises, as essential components, an inorganic particles and an organic component that contains a photosensitive compound with the difference between the average refractive index of the organic component and the average refractive index of the inorganic particles being 0.1 or less.

  提供一种可形成高纵横比和高精度图案的光敏浆料，并提供一种由所述光敏浆料组成的等离子显示器，该光敏浆料的主要成分包括无机颗粒和含有光敏化合物的有机成分，其中有机成分的平均折射率与无机颗粒的平均折射率之差不超过 0.1。