(S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene | 1433725-32-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene
• 英文别名: (1S,5S)-2-methylbicyclo[3.3.1]nona-2,6-diene
• CAS: 1433725-32-6
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: FZUSLCULPIFDAF-UWVGGRQHSA-N

物化性质

• 沸点：
  192.9±25.0 °C(predicted)
• 密度：
  0.923±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (S,S)-bicyclo[3.3.1]nonane-2,6-dione 在 正丁基锂 、 四甲基乙二胺 、 三氟化硼乙醚 、 二异丙胺 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 二氯甲烷 为溶剂， 反应 8.0h， 生成 (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene
  参考文献：
  名称：

  Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex

  摘要：

  New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,5)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer In 74% yield In 80% ee.

  DOI：

  10.1021/ol400963d

文献信息

• Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex
  作者：Yuki Hiroi、Nobuyuki Komine、Sanshiro Komiya、Masafumi Hirano

  DOI：10.1021/ol400963d

  日期：2013.5.17

  New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,5)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer In 74% yield In 80% ee.