1,5,6-tri-O-acetyl-2,3,4-tri-O-methyl-D-galactitol

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,5,6-tri-O-acetyl-2,3,4-tri-O-methyl-D-galactitol
• 英文别名: 1,5,6-tri-O-acetyl-2,3,4-tri-O-methylgalactitol；2,3,4-tri-O-methyl-1,5,6-tri-O-acetylgalactitol；1-O,5-O,6-O-Triacetyl-2-O,3-O,4-O-trimethyl-D-galactitol；[(2S,3R,4S,5R)-5,6-diacetyloxy-2,3,4-trimethoxyhexyl] acetate
• 化学式: C₁₅H₂₆O₉
• 分子量: 350.366
• InChiKey: RUAAXNGDIMCTCD-YJNKXOJESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  24
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  (2R,3R,5R,6R)-2-(hydroxymethyl)-6-(4-nitrophenoxy)oxane-3,4,5-triol 生成 1,5,6-tri-O-acetyl-2,3,4-tri-O-methyl-D-galactitol
  参考文献：
  名称：

  SHEA, ELAINE M.;CARPITA, NICHOLAS C., J. CHROMATOGR., 445,(1988) N 2, 424-428

  摘要：

  DOI：

文献信息

• The structural elucidation of the capsular polysaccharide of Klebsiella K68
  作者：Guy G.S. Dutton、Haralambos Parolis、Lesley S. Parolis

  DOI：10.1016/s0008-6215(00)90305-7

  日期：1986.9

  The structure of the capsular polysaccharide isolated from Klebsiella K68 bacteria has been elucidated by both chemical and spectroscopic methods. The structure is of the "3 + 1" type, similar in pattern to the structures of the polysaccharides of Klebsiella K11 and K57, having a single branch point on the uronic acid. The polysaccharide is shown to consist of the following repeating unit: (Formula: see text).
• Structural elucidation of three novel oligosaccharides from Kunlun Chrysanthemum flower tea and their bioactivities
  作者：Qian Yu、Wei Chen、Jing Zhong、Degang Qing、Chunyan Yan

  DOI：10.1016/j.fct.2021.112032

  日期：2021.3
• Synthesis of polysaccharides. Communication 15. Synthesis of ?-(1 ? 6)-D-galactan
  作者：N. K. Kochetkov、A. Ya. Ott

  DOI：10.1007/bf00954103

  日期：1984.10
• SHEA, ELAINE M.;CARPITA, NICHOLAS C., J. CHROMATOGR., 445,(1988) N 2, 424-428
  作者：SHEA, ELAINE M.、CARPITA, NICHOLAS C.

  DOI：——

  日期：——