Tributyl(methyl)phosphanium;fluoride

• 分子结构分类: 有机化合物 - 有机磷化合物 - 四烷基鏻化合物
• 英文名称: Tributyl(methyl)phosphanium;fluoride
• 英文别名: tributyl(methyl)phosphanium;fluoride
• 化学式: C13H30FP
• 分子量: 236.35
• InChiKey: IYRRNWPLLPEWEF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.04
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Method for preparing a fluorinated organic compound
  申请人：RHODIA OPERATIONS

  公开号：US20140148603A1

  公开（公告）日：2014-05-29

  A method for preparing a fluorinated organic compound (II) from an organic compound (I) comprising at least one nucleofugal group Nu, and also a preparation of different specific organic compounds, in particular a fluoro-methylpyrazole compound. The method comprises: a reaction, in the presence of water, of the organic compound (I) and at least one salt providing at least one fluoride anion; and a replacement of at least one nucleofugal group Nu of the compound (I) with a fluorine atom, in order to obtain the fluorinated organic compound (II).

  一种从含有至少一个亲核离开基团Nu的有机化合物(I)制备氟化有机化合物(II)的方法，以及制备不同特定有机化合物，特别是氟甲基吡唑化合物的方法。该方法包括：在水的存在下，有机化合物(I)与至少提供至少一个氟化物阴离子的盐的反应；以及将化合物(I)中至少一个亲核离开基团Nu替换为氟原子，以获得氟化有机化合物(II)。
• METHOD FOR PRODUCING A FLUORINE- AND SULPHUR-BEARING COMPOUND AND SALTS THEREOF IN AN AQUEOUS MEDIUM
  申请人：RHODIA OPERATIONS

  公开号：US20160304347A1

  公开（公告）日：2016-10-20

  The invention relates to a method for producing a fluorine- and sulphur-bearing compound of formula F—SO—R (I) or F—SO 2 —R (II), comprising the reaction, in the presence of water, of at least one salt providing a fluoride anion and at least one halgoenosulfoxide compound of formula X—SO—R′ (I0) from a halogenosulfonyl compound of formula X—SO 2 —R′ (II0), in which X is a halogen atom other than fluorine and R and R′ are each a group linked by a covalent bond to the sulphur atom, said bond linking the sulphur atom with a nitrogen atom. The invention also relates to a method for producing salts of a fluorine- and sulphur-bearing compound of formula F—SO—R (I) or F—SO 2 —R (II) which are advantageously used as electrolyte salts, as precursors of antistatic agents or as surfactant precursors.
• PROCESS FOR FLUORINATION OF SULPHONYL HALIDE COMPOUNDS
  申请人：RHODIA OPERATIONS

  公开号：US20160368866A1

  公开（公告）日：2016-12-22

  The preparation is described of a compound of formula (I) comprising an —SO 2 F function by reacting a compound of formula (II) with a fluorinating agent selected from hydrofluoric acid and an ionic fluoride of a monovalent or divalent cation: R-SO 2 F   (I) R′-SO 2 X   (II) where R is selected from the groups R1, R2 and R3: R1=—C n H a F b with n=1-10, a+b=2n+1, b≧1; R2=—C x H y F z —SO 2 F with x=1-10, y+z=2x and z≧1; R3=φ-C c H h F f with c=1-10; h+f=2c and f≧1; where R′ is selected from the following groups R′1, R′2 and R′3: R′1=—C n H a X b with n=1-10, a+b=2n+1, b≧1; R′2=—C x H y X z -SO 2 X with x=1-10, y+z=2x and z≧1; R′3=φ-C c H h X f with c=1-10; h+f=2c and f≧1; φ denoting a phenyl group; X=Cl, Br.
• US9278935B2
  申请人：——

  公开号：US9278935B2

  公开（公告）日：2016-03-08
• US9765021B2
  申请人：——

  公开号：US9765021B2

  公开（公告）日：2017-09-19