Acrylic acid 2-acryloyloxymethyl-2-{3-[[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-(2-{bis-[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-amino}-ethyl)-amino]-propionyloxymethyl}-butyl ester | 511550-36-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Acrylic acid 2-acryloyloxymethyl-2-{3-[[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-(2-{bis-[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-amino}-ethyl)-amino]-propionyloxymethyl}-butyl ester
• 英文别名: 2,2-Bis(prop-2-enoyloxymethyl)butyl 3-[2-[bis[3-[2,2-bis(prop-2-enoyloxymethyl)butoxy]-3-oxopropyl]amino]ethyl-[3-[2,2-bis(prop-2-enoyloxymethyl)butoxy]-3-oxopropyl]amino]propanoate；2,2-bis(prop-2-enoyloxymethyl)butyl 3-[2-[bis[3-[2,2-bis(prop-2-enoyloxymethyl)butoxy]-3-oxopropyl]amino]ethyl-[3-[2,2-bis(prop-2-enoyloxymethyl)butoxy]-3-oxopropyl]amino]propanoate
• CAS: 511550-36-0
• 化学式: C₆₂H₈₈N₂O₂₄
• 分子量: 1245.38
• InChiKey: KBOMRWCIBYJUMA-UHFFFAOYSA-N

物化性质

• 沸点：
  1025.9±65.0 °C(Predicted)
• 密度：
  1.164±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  88
• 可旋转键数：
  63
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  322
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  Acrylic acid 2-acryloyloxymethyl-2-{3-[[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-(2-{bis-[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-amino}-ethyl)-amino]-propionyloxymethyl}-butyl ester 、 乙二胺 以 甲醇 为溶剂， 生成 [2-[3-(2-Aminoethylamino)propanoyloxymethyl]-2-[3-[[3-[2,2-bis[3-(2-aminoethylamino)propanoyloxymethyl]butoxy]-3-oxopropyl]-[2-[bis[3-[2,2-bis[3-(2-aminoethylamino)propanoyloxymethyl]butoxy]-3-oxopropyl]amino]ethyl]amino]propanoyloxymethyl]butyl] 3-(2-aminoethylamino)propanoate
  参考文献：
  名称：

  Fast growing dendritic poly(ester–amines) from alternate reaction of EDA and TMPTA

  摘要：

  Starting with ethylene diamine (EDA) as the core, dendritic poly(ester-amines) were prepared from directly alternate reaction of EDA and trimethylolpropane triacrylate (TMPTA) under mild conditions without protection-deprotection steps. Multiple reactive hydrogen atoms in EDA and acrylate groups in TMPTA led to fast growing of dendrimers and the number of their peripheral groups. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.01.180
• 作为产物：
  描述：

  乙二胺 、 三羟甲基丙烷三丙烯酸酯 以 甲醇 为溶剂， 生成 Acrylic acid 2-acryloyloxymethyl-2-{3-[[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-(2-{bis-[2-(2,2-bis-acryloyloxymethyl-butoxycarbonyl)-ethyl]-amino}-ethyl)-amino]-propionyloxymethyl}-butyl ester
  参考文献：
  名称：

  Fast growing dendritic poly(ester–amines) from alternate reaction of EDA and TMPTA

  摘要：

  Starting with ethylene diamine (EDA) as the core, dendritic poly(ester-amines) were prepared from directly alternate reaction of EDA and trimethylolpropane triacrylate (TMPTA) under mild conditions without protection-deprotection steps. Multiple reactive hydrogen atoms in EDA and acrylate groups in TMPTA led to fast growing of dendrimers and the number of their peripheral groups. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.01.180

文献信息

• Unique steric and geometry induced stoichiometries observed in the divergent synthesis of poly(ester-acrylate/amine) (PEA) dendrimers
  作者：Douglas R. Swanson、Baohua Huang、Hosam G. Abdelhady、Donald A. Tomalia

  DOI：10.1039/b700193m

  日期：——

  controlled dendrimers possessing, macrocyclic (looped) structures (i.e., geometrically induced stoichiometry (GIS)) were formed when adequate reactivity space was available on the amine scaffolding. However, when amine core reaction sites became highly congested, one observed the formation of well defined, non-ideal dendrimers exhibiting sterically induced stoichiometries (SIS). It is postulated that

  这项工作描述了未保护的，支链的（A）x型丙烯酸酯单体（即，三羟甲基丙烷三丙烯酸酯（TMPTA）；x = 3或季戊四醇四丙烯酸酯（PTA）；X = 4），以温和的条件下的各种单和多亚烷基胺内核，以产生（芯：胺）; G = 1；[树状-聚（酯-丙烯酸酯）z ]；（PEA）型树状聚合物的一步。十分明显的是，这种策略并不需要像传统的Tomalia型聚（酰氨基胺）（PAMAM）树状大分子合成所需要的那样，需要大量过量的试剂方案，而产生的寡聚/聚合物副产物却相对较少。以高收率获得了理想的，数学上可预测的树枝状大分子结构，仅适度过量（即，4.0摩尔的单体/核心-NH）；而在较低的比率（即0.5 / 2.0摩尔的单体/核心-NH）下，具有几何结构的非理想树枝状大分子具有大环（环状）结构（即当胺骨架上有足够的反应空间时，就形成了几何诱导化学计量（GIS）。但是，当胺核心反​​应位变得高度拥挤时，人们观察到形
• DEVICES AND METHOS FOR DETECTING OR MONITORING THE QUALITY OF FOOD PRODUCTS
  申请人：University of Florida Research Foundation, Inc.

  公开号：US20210279857A1

  公开（公告）日：2021-09-09

  Described herein are devices for determining or monitoring the quality of a food product. In one aspect, the devices comprise a pH-sensitive film incorporated within a quick response code, wherein the pH-sensitive film is positioned to be in contact with the food product. The pH-sensitive film produces different colors subject to changes in pH of the food product. The color produced by the pH-sensitive film can then be correlated to the quality of the food product. The quick response code can provide additional information regarding the food product.
• Fast growing dendritic poly(ester–amines) from alternate reaction of EDA and TMPTA
  作者：Dongmei Xu、Keda Zhang、Xiulin Zhu

  DOI：10.1016/j.tetlet.2005.01.180

  日期：2005.4

  Starting with ethylene diamine (EDA) as the core, dendritic poly(ester-amines) were prepared from directly alternate reaction of EDA and trimethylolpropane triacrylate (TMPTA) under mild conditions without protection-deprotection steps. Multiple reactive hydrogen atoms in EDA and acrylate groups in TMPTA led to fast growing of dendrimers and the number of their peripheral groups. (c) 2005 Elsevier Ltd. All rights reserved.