[Fluorosulfanyl(phenoxy)methyl] thiohypofluorite

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Fluorosulfanyl(phenoxy)methyl] thiohypofluorite
• 英文别名: [fluorosulfanyl(phenoxy)methyl] thiohypofluorite
• 化学式: C₇H₆F₂OS₂
• 分子量: 208.3
• InChiKey: OZWLHLVGIVWHRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• [EN] DIFLUOROCARBENE FROM FLUOROFORM FOR PREPARATION OF DIFLUOROMETHYOXYARENES, DIFLUOROTHIOMETHOXYARENES AND HETEROARENES<br/>[FR] DIFLUOROCARBÈNE À PARTIR DE TRIFLUOROMÉTHANE POUR LA PRÉPARATION DE DIFLUOROMÉTHYOXYARÈNES, DIFLUOROTHIOMÉTHOXYARÈNES ET HÉTÉROARÈNES
  申请人：UNIV FLORIDA

  公开号：WO2014113412A1

  公开（公告）日：2014-07-24

  A method for the transformation of hydroxyarenes, hydroxyheteroarenes, thiohydroxyarenes or thiohydroxyheteroarenes involves reaction with fluoroform in the presence of base comprising solution to yield a difluoromethoxyarene, diflurothiomethoxyheteroarene, or diflurothiomethoxyheteroarene. The transformation can be carried out at ambient room pressure or at elevated pressures. The transformation can be carried out at temperatures of 0 to 70 °C.

  一种将羟基芳烃、羟基杂芳烃、硫羟基芳烃或硫羟基杂芳烃转化的方法涉及在碱性溶液存在下与氟仿反应，生成二氟甲氧基芳烃、二氟甲硫氧基杂芳烃或二氟甲硫氧基芳烃。该转化可以在常压或升压下进行，也可以在0至70℃的温度下进行。
• Difluorocarbene From Fluoroform for Preparation of Difluoromethyoxyarenes, Difluorothiomethoxyarenes and Heteroarenes
  申请人：UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

  公开号：US20150353486A1

  公开（公告）日：2015-12-10

  A method for the transformation of hydroxyarenes, hydroxyheteroarenes, thiohydroxyarenes or thiohydroxyheteroarenes involves reaction with fluoroform in the presence of base comprising solution to yield a difluoromethoxyarene, diflurothiomethoxyheteroarene, or diflurothiomethoxyheteroarene. The transformation can be carried out at ambient room pressure or at elevated pressures. The transformation can be carried out at temperatures of 0 to 70° C.