N-[[3-(hydroxyiminomethyl)-5-methylphenyl]methylidene]hydroxylamine | 708974-78-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[[3-(hydroxyiminomethyl)-5-methylphenyl]methylidene]hydroxylamine
• CAS: 708974-78-1
• 化学式: C₉H₁₀N₂O₂
• 分子量: 178.191
• InChiKey: FBJAILXBAXGYMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-[[3-(hydroxyiminomethyl)-5-methylphenyl]methylidene]hydroxylamine 在 盐酸 、 氯 作用下， 以 甲醇 、 水 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Synthesis of 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes and isomeric 1,3- and 1,4-bis[3(4)-nitrofuroxan-4(3)-yl]benzenes

  摘要：

  The 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes have been synthesized by dehydration of 1,3- and 1,4-bis(2-aminoglyoximo-1-yl)benzenes followed by oxidation of amino groups. The 1,3- and 1,4-bis(3-nitrofuroxan-4-yl)benzenes have been prepared by nitrozylation of tetrapotassium salts of 1,3- and 1,4-bis(2,2-dinitro-1-oximinoethyl)benzenes and thermally isomerized to 1,3- and 1,4-bis(4-nitrofuroxan-3-yl)benzenes.

  DOI：

  10.1016/j.mencom.2009.07.015
• 作为产物：
  描述：

  5-甲基异苯二醛 在 盐酸羟胺 、 sodium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 0.5h， 生成 N-[[3-(hydroxyiminomethyl)-5-methylphenyl]methylidene]hydroxylamine
  参考文献：
  名称：

  Synthesis of 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes and isomeric 1,3- and 1,4-bis[3(4)-nitrofuroxan-4(3)-yl]benzenes

  摘要：

  The 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes have been synthesized by dehydration of 1,3- and 1,4-bis(2-aminoglyoximo-1-yl)benzenes followed by oxidation of amino groups. The 1,3- and 1,4-bis(3-nitrofuroxan-4-yl)benzenes have been prepared by nitrozylation of tetrapotassium salts of 1,3- and 1,4-bis(2,2-dinitro-1-oximinoethyl)benzenes and thermally isomerized to 1,3- and 1,4-bis(4-nitrofuroxan-3-yl)benzenes.

  DOI：

  10.1016/j.mencom.2009.07.015

文献信息

• Synthesis of 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes and isomeric 1,3- and 1,4-bis[3(4)-nitrofuroxan-4(3)-yl]benzenes
  作者：Igor V. Ovchinnikov、Alexey O. Finogenov、Margarita A. Epishina、Yuri A. Strelenko、Nina N. Makhova

  DOI：10.1016/j.mencom.2009.07.015

  日期：2009.7

  The 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes have been synthesized by dehydration of 1,3- and 1,4-bis(2-aminoglyoximo-1-yl)benzenes followed by oxidation of amino groups. The 1,3- and 1,4-bis(3-nitrofuroxan-4-yl)benzenes have been prepared by nitrozylation of tetrapotassium salts of 1,3- and 1,4-bis(2,2-dinitro-1-oximinoethyl)benzenes and thermally isomerized to 1,3- and 1,4-bis(4-nitrofuroxan-3-yl)benzenes.