Dicyclohexyl-[1-(2-methylphenyl)pyrrol-2-yl]phosphane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Dicyclohexyl-[1-(2-methylphenyl)pyrrol-2-yl]phosphane
• 英文别名: dicyclohexyl-[1-(2-methylphenyl)pyrrol-2-yl]phosphane
• 化学式: C₂₃H₃₂NP
• 分子量: 353.5
• InChiKey: XUZHWLIUWWPACE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• METHOD FOR SELECTIVE PALLADIUM-CATALYZED TELOMERIZATION OF SUBSTITUTED DIENES
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：US20170275235A1

  公开（公告）日：2017-09-28

  A method for the selective synthesis of a tail-to-head, or a head-to-head, or a tail-to-tail telomer from an unsymmetrical diene by polymerizing the diene in the presence of [Pd(C 3 H 5 )COD]BF 4 and dicyclohexyl-[1-(2,4,6-trimethylphenyl)imidazol-2-yl]phosphane, Pd(OAc) 2 and triphenylphosphine, or [Pd(C 3 H 5 )COD]BF 4 and tris(2,4-di-tert-butylphenyl)phosphite in combination with a polar protic alcohol, an acidic polar protic alcohol, a polar aprotic ether, or a non-polar aprotic hydrocarbon is provided.

  提供了一种从非对称二烯通过在[Pd(C3H5)COD]BF4和二环己基-[1-(2,4,6-三甲基苯基)咪唑-2-基]膦烷，Pd(OAc)2和三苯基膦，或[Pd( )COD]BF4和三(2,4-二叔丁基苯基)磷酸酯的存在下，通过在极性质子醇，酸性极性质子醇，极性无水醚或非极性无水碳氢化合物中聚合二烯的方法，选择性地合成尾-头，头-头或尾-尾缩聚物。
• Iridium Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
  申请人：Dow Corning Corporation

  公开号：US20140206869A1

  公开（公告）日：2014-07-24

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable, of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
• Cobalt Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
  申请人：Dow Corning Corporation

  公开号：US20140231702A1

  公开（公告）日：2014-08-21

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
• US20140275329A1
  申请人：——

  公开号：US20140275329A1

  公开（公告）日：2014-09-18
• US8957181B2
  申请人：——

  公开号：US8957181B2

  公开（公告）日：2015-02-17