1,4,7,10-Tetraoxadecane, 1,10-bis(4'-formyl-2'-methoxyphenyl)- | 180266-69-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4,7,10-Tetraoxadecane, 1,10-bis(4'-formyl-2'-methoxyphenyl)-
• 英文别名: 4-[2-[2-[2-(4-formyl-2-methoxyphenoxy)ethoxy]ethoxy]ethoxy]-3-methoxybenzaldehyde
• CAS: 180266-69-7
• 化学式: C₂₂H₂₆O₈
• 分子量: 418.444
• InChiKey: STDGLUYIJBAWLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  30
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,4,7,10-Tetraoxadecane, 1,10-bis(4'-formyl-2'-methoxyphenyl)- 在 potassium permanganate 作用下， 以 水 为溶剂， 反应 3.0h， 以68.7%的产率得到4-[2-[2-[2-(4-Carboxy-2-methoxyphenoxy)ethoxy]ethoxy]ethoxy]-3-methoxybenzoic acid
  参考文献：
  名称：

  Fluorescence sensing of Cu2+ within a pseudo 18-crown-6 cavity

  摘要：

  We report herein a pseudo-crown based fluorescent receptor (1) for the selective detection of Cu2+ cation. Receptor 1 can detect Cu2+ even in 5 mu M level in acetonitrile-water (9:1 v/v). Compound 1 is very effective for the detection of Cu2+ amongst the series of metal ions studied (Li+, Na+ K+, Ca2+, Mg2+, Ba2+, Pb2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Mn2+). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.08.011
• 作为产物：
  描述：

  香草醛 、 三乙二醇二(对甲苯磺酸酯) 在 四丁基溴化铵 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 24.0h， 以24%的产率得到1,4,7,10-Tetraoxadecane, 1,10-bis(4'-formyl-2'-methoxyphenyl)-
  参考文献：
  名称：

  Fluorescence sensing of Cu2+ within a pseudo 18-crown-6 cavity

  摘要：

  We report herein a pseudo-crown based fluorescent receptor (1) for the selective detection of Cu2+ cation. Receptor 1 can detect Cu2+ even in 5 mu M level in acetonitrile-water (9:1 v/v). Compound 1 is very effective for the detection of Cu2+ amongst the series of metal ions studied (Li+, Na+ K+, Ca2+, Mg2+, Ba2+, Pb2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Mn2+). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.08.011

文献信息

• Fluorescence sensing of Cu2+ within a pseudo 18-crown-6 cavity
  作者：Shyamaprosad Goswami、Rinku Chakrabarty

  DOI：10.1016/j.tetlet.2009.08.011

  日期：2009.10

  We report herein a pseudo-crown based fluorescent receptor (1) for the selective detection of Cu2+ cation. Receptor 1 can detect Cu2+ even in 5 mu M level in acetonitrile-water (9:1 v/v). Compound 1 is very effective for the detection of Cu2+ amongst the series of metal ions studied (Li+, Na+ K+, Ca2+, Mg2+, Ba2+, Pb2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Mn2+). (C) 2009 Elsevier Ltd. All rights reserved.