N,N-bis(2-ethylhexyl)formamide;2-(methylamino)acetic acid

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N,N-bis(2-ethylhexyl)formamide;2-(methylamino)acetic acid
• 化学式: C20H42N2O3
• 分子量: 358.6
• InChiKey: DHLLYKVGQIANGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.17
• 重原子数：
  25
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  69.6
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• ZIRCONIUM EXTRACTANT AND METHOD FOR EXTRACTING ZIRCONIUM
  申请人：Kyushu University, National University Corporation

  公开号：US20180010211A1

  公开（公告）日：2018-01-11

  Provided are: an extractant which is capable of quickly and highly efficiently extracting zirconium from an acidic solution that is obtained by acid leaching a material containing zirconium and scandium such as an SOFC electrode material; and a method for extracting zirconium, which uses this extractant. A zirconium extractant according to the present invention is composed of an amide derivative represented by general formula (I). In the formula, R1 and R2 respectively represent the same or different alkyl groups, each of which may be linear or branched; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or an arbitrary group other than an amino group, said arbitrary group being bonded, as an amino acid, to the α carbon.

  提供了一种萃取剂，能够快速高效地从通过酸浸提取含锆和钪材料（如SOFC电极材料）得到的酸性溶液中提取锆；以及使用该萃取剂的提取锆的方法。根据本发明的锆萃取剂由一般式（I）表示的酰胺衍生物组成。在该式中，R1和R2分别表示相同或不同的烷基基团，每个基团可以是直链或支链；R3表示氢原子或烷基基团；R4表示氢原子或除氨基以外的任意基团，该任意基团作为氨基酸与α碳结合。
• COBALT EXTRACTION METHOD
  申请人：Kyushu University, National University Corporation

  公开号：EP2682486A1

  公开（公告）日：2014-01-08

  The objective of the present invention is to selectively extract cobalt from an acidic solution containing a high concentration of manganese. This cobalt extraction method extracts cobalt from an acidic solution containing manganese and cobalt by subjecting the acidic solution to solvent extraction by means of a valuable metal extraction agent comprising an amide derivative represented by general formula (I). The valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each represent the same or different alkyl group; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or any given group aside from an amino group bonded to the a carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, the pH of the acidic solution is 3.5-5.5 inclusive.

  本发明的目的是从含有高浓度锰的酸性溶液中选择性地提取钴。本发明的钴萃取方法是从含有锰和钴的酸性溶液中萃取钴，其方法是将酸性溶液用溶剂萃取，溶剂萃取剂包括通式(I)表示的酰胺衍生物。有价金属萃取剂由通式表示。式中R1 和 R2 分别代表相同或不同的烷基；R3 代表氢原子或烷基；R4 代表氢原子或除作为氨基酸键合在碳上的氨基外的任何基团。通式中最好有一个甘氨酸单元、一个组氨酸单元、一个赖氨酸单元、一个天冬氨酸单元或一个 N-甲基甘氨酸单元。酸性溶液的 pH 值最好在 3.5-5.5 之间。
• NICKEL EXTRACTION METHOD
  申请人：Kyushu University, National University Corporation

  公开号：EP2902511A1

  公开（公告）日：2015-08-05

  In the present invention, nickel is selectively extracted from an acidic solution that contains a high concentration of manganese. This valuable metal extraction agent is represented by the general formula. In the formula, R1 and R2 are alkyl groups that may be the same or different, R3 is a hydrogen atom or an alkyl group, and R4 is a hydrogen atom or any group, other than an amino group, bonded to an α carbon atom of an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit or a n-methylglycine unit. When extracting nickel by using this extraction agent, it is preferable to adjust the pH of the acidic solution to 2.3 to 5.5 inclusive.

  在本发明中，镍被选择性地从含有高浓度锰的酸性溶液中提取出来。这种有价金属萃取剂由通式表示。式中，R1 和 R2 是可以相同或不同的烷基，R3 是氢原子或烷基，R4 是氢原子或与氨基酸的 α 碳原子键合的任何基团（氨基除外）。通式中最好有一个甘氨酸单元、一个组氨酸单元、一个赖氨酸单元、一个天冬氨酸单元或一个正甲基甘氨酸单元。使用这种萃取剂萃取镍时，最好将酸性溶液的 pH 值调至 2.3 至 5.5（含 5.5）。
• EXTRACTION AGENT FOR PRECIOUS METALS AND RHENIUM, AND EXTRACTION METHOD FOR PRECIOUS METALS AND RHENIUM USING SAME
  申请人：Kyushu University, National University Corporation

  公开号：EP2960349A1

  公开（公告）日：2015-12-30

  The present invention extracts precious metals from an acidic solution containing precious metals in an early and highly efficient manner. Provided is an extraction agent for precious metals that is represented by the general formula below. In the formula, R1 and R2 each represent the same alkyl group or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or a discretionary group that is not an amino group and that bonds to α carbon as an amino acid. It is preferable that the general formula have a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By subjecting an acidic solution containing precious metals to solvent extraction using the extraction agent for precious metals, a plurality of precious metals can be recovered all at once from a solution containing a large amount of various impurities. When recovering precious metals, it is preferable that the pH be set to 3.0 or less and further preferable that the pH be set to 2.5 or less. In addition, it is possible to separate palladium from other precious metals by performing reverse extraction using a second acidic solution having a lower pH than the original acidic solution.

  本发明能从含有贵金属的酸性溶液中快速高效地萃取贵金属。本发明提供了一种由以下通式表示的贵金属萃取剂。式中，R1和R2各自代表相同的烷基或不同的烷基，R3代表氢原子或烷基，R4代表氢原子或非氨基且作为氨基酸与α碳键合的任意基团。通式中最好有一个甘氨酸单元、一个组氨酸单元、一个赖氨酸单元、一个天冬氨酸单元或一个 N-甲基甘氨酸单元。使用贵金属萃取剂对含有贵金属的酸性溶液进行溶剂萃取，可以从含有大量各种杂质的溶液中一次性回收多种贵金属。回收贵金属时，pH 值最好设定在 3.0 或以下，pH 值最好设定在 2.5 或以下。此外，还可以使用第二种酸性溶液进行反向萃取，这种溶液的 pH 值比原来的酸性溶液低，从而将钯从其他贵金属中分离出来。
• Zirconium extractant and method for extracting zirconium
  申请人：Kyushu University, National University Corporation

  公开号：US10036082B2

  公开（公告）日：2018-07-31

  Provided are: an extractant which is capable of quickly and highly efficiently extracting zirconium from an acidic solution that is obtained by acid leaching a material containing zirconium and scandium such as an SOFC electrode material; and a method for extracting zirconium, which uses this extractant. A zirconium extractant according to the present invention is composed of an amide derivative represented by general formula (I). In the formula, R1 and R2 respectively represent the same or different alkyl groups, each of which may be linear or branched; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or an arbitrary group other than an amino group, said arbitrary group being bonded, as an amino acid, to the α carbon.

  本发明提供了一种萃取剂，该萃取剂能够从酸性溶液中快速高效地萃取锆，酸性溶液是通过酸性浸出含锆和钪的材料（如 SOFC 电极材料）而获得的；还提供了一种使用该萃取剂萃取锆的方法。根据本发明，锆萃取剂由通式（I）表示的酰胺衍生物组成。式中，R1 和 R2 分别代表相同或不同的烷基，每个烷基可以是直链或支链；R3 代表氢原子或烷基；R4 代表氢原子或氨基以外的任意基团，所述任意基团作为氨基酸键合在α 碳上。