(2S)-2-[[2-(dioctylamino)-2-oxoethyl]amino]-3-(1H-imidazol-5-yl)propanoic acid

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (2S)-2-[[2-(dioctylamino)-2-oxoethyl]amino]-3-(1H-imidazol-5-yl)propanoic acid
• 化学式: C₂₄H₄₄N₄O₃
• 分子量: 436.6
• InChiKey: UEDVJMMPAVTAMA-QFIPXVFZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  31
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  98.3
• 氢给体数：
  3
• 氢受体数：
  5

文献信息

• EP2682486B1
  申请人：——

  公开号：EP2682486B1

  公开（公告）日：2016-03-16
• VALUABLE METAL EXTRACTION AGENT AND VALUABLE METAL EXTRACTION METHOD USING SAID EXTRACTION AGENT
  申请人：Kyushu University, National University Corporation

  公开号：US20140234187A1

  公开（公告）日：2014-08-21

  The objective of the present invention is to selectively extract light rare earth metals, and by extension, europium, from an acidic solution containing a plurality of types of rare earth metal. This valuable metal extraction agent is represented by the general formula. In the formula: R 1 and R 2 each indicate the same or different alkyl group; R 3 indicates a hydrogen atom or an alkyl group; and R 4 indicates a hydrogen atom or any given group other than an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, when extracting europium using the extraction agent, the pH is adjusted into the range of 2.0-3.0 inclusive, and when selectively extracting light rare earth metals, the pH is adjusted to 1.7-2.7 inclusive.
• COBALT EXTRACTION METHOD
  申请人：Kyushu University, National University Corporation

  公开号：US20140328737A1

  公开（公告）日：2014-11-06

  The objective of the present invention is to selectively extract cobalt from an acidic solution containing a high concentration of manganese. This cobalt extraction method extracts cobalt from an acidic solution containing manganese and cobalt by subjecting the acidic solution to solvent extraction by means of a valuable metal extraction agent comprising an amide derivative represented by general formula (I). The valuable metal extraction agent is represented by the general formula. In the formula: R 1 and R 2 each represent the same or different alkyl group; R 3 represents a hydrogen atom or an alkyl group; and R 4 represents a hydrogen atom or any given group aside from an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, the pH of the acidic solution is 3.5-5.5 inclusive.
• METHOD FOR ISOLATING VALUABLE METAL
  申请人：Kyushu University, National University Corporation

  公开号：US20150240329A1

  公开（公告）日：2015-08-27

  Provided is a method that selectively extracts and, at a low cost, recovers indium from an acidic solution containing indium and gallium. The present invention is a method that is for isolating a valuable metal and that, by means of subjecting an acidic solution containing indium and gallium to a solvent extraction that is by means of an extraction agent comprising an amide derivative represented by a general formula, extracts indium from the acidic solution. In the formula, R 1 and R 2 each indicate the same or a different alkyl group, R 3 indicates a hydrogen atom or an alkyl group, and R 4 indicates a hydrogen atom or any given group, other than an amino group, bonded to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit.
• GALLIUM EXTRACTION AGENT AND GALLIUM EXTRACTION METHOD
  申请人：Kyushu University, National University Corporation

  公开号：US20150211093A1

  公开（公告）日：2015-07-30

  Provided are an extraction agent and extraction method that selectively extract and, at a low cost, recover gallium from an acidic solution containing gallium and zinc. The gallium extraction agent comprises an amide derivative represented by general formula (1). In the formula, R and R 2 each indicate the same or different alkyl group, R 3 indicates a hydrogen atom or an alkyl group, and R 4 indicates a hydrogen atom or any given group, other than an amino group, bonded to the α-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. By extracting gallium from an acidic solution containing gallium and zinc by means of solvent extraction using the extraction agent, it is possible to selectively extract gallium.