N-(2-[2]pyridyl-ethyl)-p-anisidine | 55496-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N-(2-[2]pyridyl-ethyl)-p-anisidine
• 英文别名: N-(2-[2]Pyridyl-aethyl)-p-anisidin；N-[2-(pyridin-2-yl)ethyl]-4-methoxy-aniline；N-[2-(2-pyridyl)ethyl]-4-methoxy-aniline；(4-Methoxy-phenyl)-(2-pyridin-2-yl-ethyl)-amine；4-methoxy-N-(2-pyridin-2-ylethyl)aniline
• CAS: 55496-58-7
• 化学式: C₁₄H₁₆N₂O
• mdl: MFCD02336284
• 分子量: 228.294
• InChiKey: NXRQNMNZSKSLEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.214
• 拓扑面积：
  34.2
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT

反应信息

• 作为反应物：
  描述：

  N-(2-[2]pyridyl-ethyl)-p-anisidine 、 4-二乙氨基酮酸 生成 6'-(Diethylamino)-2'-(2-pyridin-2-ylethylamino)spiro[2-benzofuran-3,9'-xanthene]-1-one
  参考文献：
  名称：

  HUNG, WILLIAM M.;EHLINGER, EDWARD E.

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙烯基吡啶 、 甲氧苯胺 以40%的产率得到
  参考文献：
  名称：

  YUAN, GUO-QING;CHEN, RONG-YAO, ACTA CHIM. SIN., 1984, 42, N 6, 583-586

  摘要：

  DOI：

文献信息

• Pyridine containing benzoic acid derivatives
  申请人：Sterling Drug Inc.

  公开号：US04447616A1

  公开（公告）日：1984-05-08

  2-And/or 6-pyridylethylamino-substituted fluorans useful as color formers, particularly in pressure-sensitive carbonless duplicating systems and thermal-responsive marking systems are prepared by the interaction of (pyridylethylaminophenyl)carbonylbenzoic acids with 4-hydroxy- or alkoxyanilines or by the interaction of (disubstituted aminophenyl)carbonylbenzoic acids with N-pyridylethyl-4-hydroxy- or alkoxy acetanilides. The (pyridylethylaminophenyl)carbonylbenzoic acid intermediates required for the fluorans are prepared by interacting a N-pyridylethyl-3-hydroxyaniline with a substituted or unsubstituted phthalic anhydride. The N-pyridylethyl-4-hydroxy- or alkoxyanilines and the N-pyridylethyl-3-hydroxyanilines are prepared by interacting the respective aniline with a vinylpyridine.

  2-和/或6-吡啶乙基氨基取代的氟兰在颜色形成剂中有用，特别适用于压敏无碳复写系统和热响应标记系统，通过(吡啶乙基氨基苯基)羰基苯甲酸与4-羟基或烷氧基苯胺的相互作用制备，或通过(二取代氨基苯基)羰基苯甲酸与N-吡啶乙基-4-羟基或烷氧基乙酰苯胺的相互作用制备。用于制备氟兰的(吡啶乙基氨基苯基)羰基苯甲酸中间体通过将N-吡啶乙基-3-羟基苯胺与取代或未取代的邻苯二酐相互作用制备。N-吡啶乙基-4-羟基或烷氧基苯胺和N-吡啶乙基-3-羟基苯胺通过将相应苯胺与乙烯吡啶相互作用制备。
• Fluoran compounds and marking systems
  申请人：The Hilton-Davis Chemical Company

  公开号：US04639750A1

  公开（公告）日：1987-01-27

  2- And/or 6-pyridylethylamino-substituted fluorans useful as color formers, particularly in pressure-sensitive carbonless duplicating systems and thermal-responsive marking systems are prepared by the interaction of (pyridylethylaminophenyl)carbonylbenzoic acids with 4-hydroxy- or alkoxyanilines or by the interaction of (disubstituted aminophenyl)carbonylbenzoic acids with N-pyridylethyl-4-hydroxy- or alkoxyacetanilides. The (pyridylethylaminophenyl)carbonylbenzoic acid intermediates required for the fluorans are prepared by interacting a N-pyridylethyl-3-hydroxyaniline with a substituted or unsubstituted phthalic anhydride. The N-pyridylethyl-4-hydroxy- or alkoxyanilines and the N-pyridylethyl-3-hydroxyanilines are prepared by interacting the respective aniline with a vinylpyridine.

  2-并/或6-吡啶乙基氨基取代的氟兰色素在压敏无碳复写系统和热响应标记系统中作为色素形成剂，通过（吡啶乙基氨基苯基）羰基苯甲酸与4-羟基或烷氧基苯胺的相互作用，或通过（二取代氨基苯基）羰基苯甲酸与N-吡啶乙基-4-羟基或烷氧基乙酰苯胺的相互作用制备。制备氟兰色素所需的（吡啶乙基氨基苯基）羰基苯甲酸中间体是通过将N-吡啶乙基-3-羟基苯胺与取代或未取代的邻苯二酸酐相互作用而制备的。N-吡啶乙基-4-羟基或烷氧基苯胺和N-吡啶乙基-3-羟基苯胺是通过将相应的苯胺与乙烯基吡啶相互作用而制备的。
• Pyridylethylaminofluorans
  申请人：STERLING DRUG INC.

  公开号：EP0110366A2

  公开（公告）日：1984-06-13

  2- and/or 6-pyridylethylamino-substituted fluorans useful as color formers, particularly in pressure-sensitive carbonless duplicating systems and thermal-responsive marking systems are prepared by the interaction of (pyridylethylaminophe- nyl)carbonylbenzoic acids with 4-hydroxy- or alkoxyanilines or by the interaction of (disubstituted aminophenyl)carbonylben- zoic acids with N-pyridylethyl-4-hydroxy- or alkoxy acetanilides. The (pyridylethylaminophenyl)carbonylbenzoic acid intermediates required for the fluorans are prepared by interacting a N-pyridylethyl-3-hydroxyaniline with a substituted or unsubstituted phthalic anhydride. The N-pyridylethyl-4-hydroxy-or alkoxyanilines and the N-pyridylethyl-3-hydroxyanilines are prepared by interacting the respective aniline with a vinylpyridine.

  2- 和/或 6-吡啶乙氨基取代的荧烷可用作显色剂，特别是在压敏无碳复写系统和热敏打标系统中，其制备方法是(吡啶乙氨基苯基)羰基苯甲酸与 4-羟基或烷氧基苯胺作用，或(二取代氨基苯基)羰基苯甲酸与 N-吡啶乙基-4-羟基或烷氧基乙酰苯胺作用。通过 N-吡啶乙基-3-羟基苯胺与取代或未取代的邻苯二甲酸酐相互作用，制备出氟化合物所需的(吡啶乙基氨基苯基)羰基苯甲酸中间体。N-吡啶乙基-4-羟基或烷氧基苯胺和 N-吡啶乙基-3-羟基苯胺是通过各自的苯胺与乙烯基吡啶作用制备的。
• Profft, CHEMTECH, 1955, vol. 7, p. 511,517
  作者：Profft

  DOI：——

  日期：——
• HUNG, WILLIAM M.;EHLINGER, EDWARD E.
  作者：HUNG, WILLIAM M.、EHLINGER, EDWARD E.

  DOI：——

  日期：——