2-(3-((tert-butyldimethylsilyl)oxy)phenyl)pyridine | 481667-88-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(3-((tert-butyldimethylsilyl)oxy)phenyl)pyridine
• 英文别名: 2-(3-Tert-butyldimethylsilyloxyphenyl)pyridine；tert-butyl-dimethyl-(3-pyridin-2-ylphenoxy)silane
• CAS: 481667-88-3
• 化学式: C₁₇H₂₃NOSi
• 分子量: 285.461
• InChiKey: PPODXHFNETVHEG-UHFFFAOYSA-N

物化性质

• 沸点：
  351.9±25.0 °C(Predicted)
• 密度：
  0.983±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.13
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  22.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-辛炔 、 2-(3-((tert-butyldimethylsilyl)oxy)phenyl)pyridine 在 甲基氯化镁 、 二苯基甲氧基膦 、 cobalt(II) bromide 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以55%的产率得到(E)-2-(5-((tert-Butyldimethylsilyl)oxy)-2-(oct-4-en-4-yl)phenyl)pyridine
  参考文献：
  名称：

  Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation

  摘要：

  Ternary catalytic systems consisting of cobalt salts, phosphine ligands, and Grignard reagents promote addition of arylpyridines and imines to unactivated internal alkynes with high regio- and stereoselectivities. Deuterium-labeling experiments suggest that the reaction involves chelation-assisted oxidative addition of the aryl C-H bond to the cobalt center and insertion of the C-C triple bond into the Co-H bond, followed by reductive elimination of the resulting diorganocobalt species.

  DOI：

  10.1021/ja106814p
• 作为产物：
  描述：

  叔丁基二甲基氯硅烷 、 3-(吡啶-2-基)苯酚 以give 2-(3-tert-butyldimethylsilyloxyphenyl)pyridine according to scheme (3)的产率得到2-(3-((tert-butyldimethylsilyl)oxy)phenyl)pyridine
  参考文献：
  名称：

  POLYMER LIGHT-EMITTING MATERIAL, METOHO FOR PRODUCING THE SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE

  摘要：

  本发明公开了一种聚合物发光材料，用于有机电致发光器件，具有优异的发光性能，并适用于湿法处理。该有机电致发光器件的聚合物发光材料是通过将具有2,000-1,000,000的Mw和包含构成主链的功能基团的热塑性树脂和含有反应性基团的金属含磷荧光掺杂化合物进行聚合反应，以将来自金属含磷荧光掺杂剂化合物的荧光掺杂基团连接到热塑性树脂的主链单元上而获得的。所述聚合物发光材料中来自金属含磷荧光掺杂剂化合物的金属含量为0.001-20重量％。

  公开号：

  US20110309342A1

文献信息

• POLYMER LIGHT-EMITTING MATERIAL, METOHO FOR PRODUCING THE SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Tanaka Hiroshige

  公开号：US20110309342A1

  公开（公告）日：2011-12-22

  Disclosed is a polymer light-emitting material for an organic electroluminescent device that displays excellent light-emitting performance and is applicable to a wet process. The polymer light-emitting material for an organic electroluminescent device is obtained by subjecting a thermoplastic resin having an Mw of 2,000-1,000,000 and containing a functional group in a unit constituting the backbone and a metal-containing phosphorescent dopant compound containing a reactive group capable of reacting with the said functional group to a polymer reaction so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound to the unit constituting the backbone of the thermoplastic resin. The content of the metal derived from the metal containing phosphorescent dopant compound in the said polymer light-emitting material is 0.001-20 wt %.

  本发明公开了一种聚合物发光材料，用于有机电致发光器件，具有优异的发光性能，并适用于湿法处理。该有机电致发光器件的聚合物发光材料是通过将具有2,000-1,000,000的Mw和包含构成主链的功能基团的热塑性树脂和含有反应性基团的金属含磷荧光掺杂化合物进行聚合反应，以将来自金属含磷荧光掺杂剂化合物的荧光掺杂基团连接到热塑性树脂的主链单元上而获得的。所述聚合物发光材料中来自金属含磷荧光掺杂剂化合物的金属含量为0.001-20重量％。
• Polymer light-emitting material, method for producing the same, and organic electroluminescent device
  申请人：Tanaka Hiroshige

  公开号：US09290692B2

  公开（公告）日：2016-03-22

  Disclosed is a polymer light-emitting material for an organic electroluminescent device that displays excellent light-emitting performance and is applicable to a wet process. The polymer light-emitting material for an organic electroluminescent device is obtained by subjecting a thermoplastic resin having an Mw of 2,000-1,000,000 and containing a functional group in a unit constituting the backbone and a metal-containing phosphorescent dopant compound containing a reactive group capable of reacting with the said functional group to a polymer reaction so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound to the unit constituting the backbone of the thermoplastic resin. The content of the metal derived from the metal containing phosphorescent dopant compound in the said polymer light-emitting material is 0.001-20 wt %.

  本发明公开了一种聚合物发光材料，适用于湿法工艺，具有优异的发光性能，可用于有机电致发光器件。该聚合物发光材料是通过将具有2,000-1,000,000 Mw和在构成骨架的单元中含有功能基团的热塑性树脂和含有反应性基团的金属含磷光致发光剂化合物进行聚合反应，以将来自金属含磷光致发光剂化合物的磷光致发光基团连接到热塑性树脂的构成单元上而获得的。所述聚合物发光材料中来自金属含磷光致发光剂化合物的金属含量为0.001-20重量％。
• Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation
  作者：Ke Gao、Pin-Sheng Lee、Takeshi Fujita、Naohiko Yoshikai

  DOI：10.1021/ja106814p

  日期：2010.9.8

  Ternary catalytic systems consisting of cobalt salts, phosphine ligands, and Grignard reagents promote addition of arylpyridines and imines to unactivated internal alkynes with high regio- and stereoselectivities. Deuterium-labeling experiments suggest that the reaction involves chelation-assisted oxidative addition of the aryl C-H bond to the cobalt center and insertion of the C-C triple bond into the Co-H bond, followed by reductive elimination of the resulting diorganocobalt species.