[2-(1,3-benzodithiol-2-ylidene)-1,3-dithiol-4-yl]methyl N-(3-triethoxysilylpropyl)carbamate | 1323394-57-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: [2-(1,3-benzodithiol-2-ylidene)-1,3-dithiol-4-yl]methyl N-(3-triethoxysilylpropyl)carbamate
• CAS: 1323394-57-5
• 化学式: C₂₁H₂₉NO₅S₄Si
• 分子量: 531.814
• InChiKey: YTXPJAPZKUGYJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  32
• 可旋转键数：
  13
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  167
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  dimethyl benzotetrathiafulvalene-1,2-dicarboxylate 在 水 、 二异丁基氢化铝 、 三乙胺 、 lithium bromide 作用下， 以 四氢呋喃 、 六甲基磷酰三胺 、 二氯甲烷 为溶剂， 反应 3.5h， 生成 [2-(1,3-benzodithiol-2-ylidene)-1,3-dithiol-4-yl]methyl N-(3-triethoxysilylpropyl)carbamate
  参考文献：
  名称：

  A Three-State Surface-Confined Molecular Switch with Multiple Channel Outputs

  摘要：

  A self-assembled monolayer of a tetrathiafulvalene derivative on indium tin oxide is shown to operate as a ternary redox switch in which the magnetic and optical outputs are employed to provide a readout of the state. This surface-confined molecular switch exhibits excellent reversibility and stability and is thus promising for the development of molecular electronics.

  DOI：

  10.1021/ja204898u

文献信息

• A Three-State Surface-Confined Molecular Switch with Multiple Channel Outputs
  作者：Cláudia Simão、Marta Mas-Torrent、Javier Casado-Montenegro、Francisco Otón、Jaume Veciana、Concepció Rovira

  DOI：10.1021/ja204898u

  日期：2011.8.31

  A self-assembled monolayer of a tetrathiafulvalene derivative on indium tin oxide is shown to operate as a ternary redox switch in which the magnetic and optical outputs are employed to provide a readout of the state. This surface-confined molecular switch exhibits excellent reversibility and stability and is thus promising for the development of molecular electronics.