2,3,5,6-Tetrafluoro-4-sulfanylbenzonitrile | 111727-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 2,3,5,6-Tetrafluoro-4-sulfanylbenzonitrile
• CAS: 111727-09-4
• 化学式: C₇HF₄NS
• 分子量: 207.151
• InChiKey: SUZOPJDWIZVANH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.8
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  二氯(1,10-亚铁试剂)铂(II) 、 2,3,5,6-Tetrafluoro-4-sulfanylbenzonitrile 在 hexamethylenetetraamine 、 KO-t-Bu 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到1,10-phenanthrolinebis(4-cyano-tetrafluorophenylthiolato)platinum(II)
  参考文献：
  名称：

  具有全氟化硫醇盐配体的PtII二亚胺发色团：转移至二亚胺的最低激发态的性质和动力学。

  摘要：

  带有全氟化硫醇盐配体Pt（II）（NN）（4-XC（6）F（4）-S）（2）的新Pt（II）二亚胺配合物的合成，其中NN = 2,2'-联吡啶或报道了1，10-菲咯啉和X ＝ F或CN，以及对它们的最低激发态的性质和动力学的研究。结合的紫外可见光谱，（光谱）电化学，共振拉曼光谱和时间分辨红外（TRIR）研究表明，HOMO主要由硫醇盐（pi）/ S（p）/ Pt（d）轨道组成，并且LUMO主要位于pi *（二亚胺）轨道上，因此揭示了最低激发态的[电荷转移至二亚胺]性质。在共振拉曼光谱中观察到硫醇盐环振动，CF振动以及硫醇盐部分上CN取代基振动的增强，而对于非氟化类似物没有观察到这种增强。因此，与具有非氟化硫醇盐的类似络合物相比，在硫醇盐部分上引入氟取代基可能导致硫醇内模式对HOMO的更显着贡献。此外，将p-CN基团引入到硫醇盐部分中，可以监视Pt（bpy）（4-CN-C（6）F（4）-S）（

  DOI：

  10.1021/ic026286l
• 作为产物：
  描述：

  五氟苯腈 生成 2,3,5,6-Tetrafluoro-4-sulfanylbenzonitrile
  参考文献：
  名称：

  ISIKAVA, RYUITI;KAJEHDA, OSAMU

  摘要：

  DOI：

文献信息

• AROMATIC POLYETHERS
  申请人：Moore David Roger

  公开号：US20090163692A1

  公开（公告）日：2009-06-25

  An aromatic polyether comprising structural units derived from a halosulfone sulfonate having structure (I): wherein R 1 is a C 3 -C 25 aromatic radical, a C 3 -C 25 cycloaliphatic radical, or a C 1 -C 10 aliphatic radical; M is hydrogen or a charge balancing cation; Y 1 is independently at each occurrence a halogen; “t” is an integer having a value of 1 or 2; “s” is an integer having a value 0 to 3, “b” is an integer having a value 1 to 4; and “c” is an integer having a value 1 to 20. Also provided are methods of preparing the aromatic polyethers, and compositions including the aromatic polyethers.

  一种芳香族聚醚，包括由具有结构（I）的卤代磺酸酯衍生的结构单元，其中 R1 是 C3-C25 芳香基团、C3-C25 环状脂肪族基团或 C1-C10 脂肪基团；M 是氢或平衡电荷的阳离子；Y1 独立地在每次出现时是卤素；“t” 是一个整数，取值为1或2；“s” 是一个整数，取值为0到3，“b” 是一个整数，取值为1到4；“c” 是一个整数，取值为1到20。还提供了制备芳香族聚醚的方法以及包括芳香族聚醚的组合物。
• Quinizarin compound, method for production thereof, and use therefor
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0661350A1

  公开（公告）日：1995-07-05

  This invention is to provide a novel quinizarin compound which has a quinizarin structure represented by a following formula (1) having one to four of the 5, 6, 7, and 8 positions and at least either the 6 or 7 position formed of at least one member selected from the class consisting of secondary amino groups, alkylthio groups, and optionally substituted phenylthio groups, and having the remaining positions thereof formed of at least one member selected from the class consisting of hydrogen atom, halogen atoms, amino group, hydroxy group, alkoxy groups, and optionally substituted phenoxy groups, a method for the produciton thereof, and a dye, an electrophotographic grade color toner composition, a thermal-transfer recording sheet, an optical recording medium, an ink jet grade ink composition and a color filter severally comprising the quinizarin compound.

  本发明旨在提供一种新型喹嗪啉化合物，该化合物具有下式(1)所代表的喹嗪啉结构，其5、6、7和8位中的一至四个位以及至少6或7位上的至少一个位由选自仲氨基、烷硫基和任选取代的苯硫基组成的类别中的至少一个成员构成、其剩余位置由至少一个选自氢原子、卤素原子、氨基、羟基、烷氧基和任选取代的苯氧基组成的类别的成员构成；其生产方法；以及包含该喹吖啶化合物的染料、电子照相级彩色调色剂组合物、热转印记录片、光学记录介质、喷墨级墨水组合物和彩色滤光片。
• Color filter grade photosensitive resin coloring composition, and color filter using the same
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0833203A1

  公开（公告）日：1998-04-01

  A photosensitive resin coloring composition for use in a color filter containing a resin and a dye which is a material for the formation of a colored layer of the color filter, characterized in that the dye is manufactured with one member selected from the class consisting of a (C) group alone (which includes only phthalocyanine compounds represented by the formula (1) below and having one to eight unsubstituted or substituted alkoxy group(s) and/or unsubstituted or substituted phenoxy group(s) substituted at the 2, 3, 6, 7, 10, 11, 14 and 15 positions thereof), a combination of (A) + (B) groups, a combination of (A) + (C) groups, a combination of (B) + (C) groups, and a combination of (A) + (B) + (C) groups, wherein (A) represents a group of quinizarine compounds having a quinizarine skeleton in which one to three of the 5, 6, 7, and 8 positions and at least either of the 6 and 7 positions are each occupied by a secondary amino group and the remainders of the 5, 6, 7, and 8 positions are occupied each by at least one group selected from the class consisting of hydrogen atom, halogen atom, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted phenoxy group, an unsubstituted or substituted alkylthio group, and an unsubstituted or substituted phenylthio group, (B) represents a group anthraquinone compounds having an anthraquinone skeleton in which one to three of the 1, 2, 3, and 4 positions are occupied each by at least one group selected from the class consisting of secondary amimo group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted phenoxy group, an unsubstituted or substituted alkylthio group, and an unsubstituted or substituted phenylthio group and the remainders of the 1, 2, 3, and 4 positions are occupied each by hydrogen atom or a halogen atom, and (C) represents a group of phthalocyanine compounds having a phthalocyanine skeleton represented by the following general formula (1) wherein M represents a divalent metal or a ligand-containing tetravalent metal in which one to eight of the 16 positions of benzene rings permitting substitution are occupied each by an unsubstituted or substituted alkoxy group and/or an unsubstituted or substituted phenoxy group and the remainders of the positions are occupied each by a halogen atom.

  一种用于彩色滤光片的光敏树脂着色组合物，含有树脂和染料，染料是形成彩色滤光片彩色层的材料，其特征在于染料是用选自以下类别的一个成员制造的：单独的(C)基团(仅包括下式(1)所代表的酞菁化合物，其具有1至8个未取代或取代的烷氧基和/或在2、(A)+(B)基团的组合、(A)+(C)基团的组合、(B)+(C)基团的组合以及(A)+(B)+(C)基团的组合、其中(A)代表一组具有喹嗪类骨架的喹嗪类化合物，其 5、6、7 和 8 位中的一至三个位以及 6 和 7 位中的至少一个位分别被仲氨基占据，而 5、6、7 和 8 位的剩余位分别被至少一个仲氨基占据、(B) 代表一组具有蒽醌骨架的蒽醌化合物，其中 1、2、3 和 4 位中的 1 至 3 位分别被至少一个选自仲氨基的基团占据、(C) 代表一组酞菁化合物，其酞菁骨架由以下通式 (1) 表示 其中 M 代表二价金属或含配体的四价金属，其中允许取代的苯环 16 个位置中的 1 至 8 个位置分别由未取代或取代的烷氧基和/或未取代或取代的苯氧基占据，其余位置分别由卤原子占据。
• ISIKAVA, RYUITI;KAJEHDA, OSAMU
  作者：ISIKAVA, RYUITI、KAJEHDA, OSAMU

  DOI：——

  日期：——
• JPS62126162A
  申请人：——

  公开号：JPS62126162A

  公开（公告）日：1987-06-08