The present invention relates to improving the efficiency of man-made and/or natural organic-based animal manure fertilizers by administration of formulations containing poly(organic acids), [P(OA)]s, and/or their salts dispersed in a Non-aqueous Organic Solvent Delivery System (NOSDS). Utilizing a NOSDS allows for coating all components in a fertilizer formulation including but not limited to Urea, Manure, mono-ammonium phosphate (MAP), di-ammonium phosphate (DAP), solid micronutrients such as lime, zinc chloride, etc.) with a layer of [P(OA)]s and/or their salts that liberates, in a plant available form, the micronutrient metals and macronutrients, that are bound as insoluble salts and complexes in the soil. The carboxylic groups of a [P(OA)] that can exist within the [P(OA)] as carboxylic acids, carboxylic anhydrides and/or carboxylic imides, dispersed within the NOSDS, can be neutralized with one or more metals in the form of elemental metals, metal oxides, metal hydroxides, metal alkylates and metal carbonates and/or nitrogen containing compounds such as ammonia, ammonium hydroxide or organoamines to form a stable dispersion that can contain completely complexed micronutrients and provide the vehicle for the delivery of these nutrients to soils and/or as a coating to the surfaces fertilizer granules and seeds.
本发明涉及通过施用分散在非
水有机溶剂给料系统(NOSDS)中的含有聚有机酸、[P(OA)]和/或其盐的制剂来提高人造和/或天然有机基动物粪便肥料的效率。利用 NOSDS 可以在肥料配方中的所有成分(包括但不限于
尿素、粪肥、
磷酸一
铵 (
MAP)、
磷酸二
铵 (DAP)、固体微量营养元素,如
石灰、
氯化锌等)上涂上一层 [P(OA)]s 和/或其盐,从而以植物可利用的形式释放出土壤中以不溶盐和络合物形式结合的微量营养元素
金属和大量营养元素。分散在 NOSDS 中的[P(OA)]的羧基可以
羧酸、
羧酸酐和/或羧
酰亚胺的形式存在,可以一种或多种
金属元素、金属氧化物、
金属氢氧化物、
金属烷基化物和
金属
碳酸盐的形式中和、
金属烷基化物和
金属
碳酸盐和/或
含氮化合物,如
氨、氢氧化
铵或有机胺,以形成稳定的分散体,该分散体可包含完全络合的微量营养元素,并提供将这些营养元素输送到土壤中的载体和/或作为肥料颗粒和种子表面的包衣。