6-(9-羧基-1-壬烯基)-4,5-二己基环己-2-烯-1-辛酸 | 47818-40-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 6-(9-羧基-1-壬烯基)-4,5-二己基环己-2-烯-1-辛酸
• 英文名称: dimer acid
• 英文别名: Dilinoleic acid；10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid
• CAS: 47818-40-6
• 化学式: C₃₆H₆₄O₄
• 分子量: 560.902
• InChiKey: CIRMGZKUSBCWRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  40
• 可旋转键数：
  27
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-(9-羧基-1-壬烯基)-4,5-二己基环己-2-烯-1-辛酸 、 2-乙基己醇 在 硫酸 作用下， 反应 102.0h， 生成
  参考文献：
  名称：

  二聚酸 2-乙基己酯的合成及其作为生物润滑剂基础油的理化性质及其作为商业基础油添加剂的潜力

  摘要：

  先前合成的 C36-二聚酸 (DA) 已用 2-乙基己醇 (2-EH) 酯化（97 ± 0.2% 转化率在 120 °C 下持续 72 小时），以产生一类新的 C52-DA 2-EH 酯，其具有在生物润滑剂配方中的潜在应用，如基础油和添加剂。物理化学和润滑剂特性的研究表明，生物基酯在商业基础油中具有良好的溶解性，例如聚α 烯烃 (PAO-6) (>20 w/w) 和高油酸葵花籽油 (HOSuO) (>20 w/w) ）。纯 C52-DA 2-EH 酯显示出比商业基础油 PAO-6 (VI = 137) 高三到八倍的运动粘度和可比的粘度指数 (VI = 134)。两种 C52-DA 2-EH 酯，其母体 C36-DA 是用两种不同的沸石催化剂合成的，在 176 °C 以上是氧化稳定的。在 HOSuO 中混合 C52-DA 2-EH 酯将 HOSuO 的倾点 (PP) 从 -18.8°C 提高到

  DOI：

  10.1002/aocs.12455

文献信息

• Solvent- and catalyst-free synthesis of fully biobased nonisocyanate polyurethanes with different macromolecular architectures
  作者：C. Carré、L. Bonnet、L. Avérous

  DOI：10.1039/c5ra17638g

  日期：——

  A bis(cyclic carbonate) based on a dimeric fatty acid was successfully synthesized.

  基于二聚脂肪酸的双(环状碳酸酯)成功合成。
• Dimer amidopropyl dimethyl quaternary compounds
  申请人：O'Lenick, Jr. Anthony J.

  公开号：US06861542B1

  公开（公告）日：2005-03-01

  The present invention relates to a class of compounds having specific quaternized amine based upon a dimer acid amido amine linked to specific phosphate esters. Dimer acid is a C-36 diacid having a cyclic structure and two amine groups that allow for the synthesis of a high molecular weight material quaternary compound which is extremely substantitive to human skin and are well tolerated by human tissue making them suitable for use preparation of barrier products for personal care applications.

  本发明涉及一类化合物，其具有基于二聚酸酰胺胺的特定季铵基团，与特定磷酸酯相连。二聚酸是一种具有环状结构和两个胺基团的C-36二酸，可用于合成高分子量季铵化合物，对人体皮肤具有极高的亲和力，并且人体组织耐受性良好，适用于用于个人护理产品的屏障制备。
• Dimer poly-quaternary ester compounds
  申请人：O'Lenick Kevin A.

  公开号：US20090247629A1

  公开（公告）日：2009-10-01

  The present invention relates to a novel class of polymeric compounds having specific quaternized amine based upon a dimer acid reacted with an alkanolamine to make an ester quaternary compound. Dimer acid is a C-36 diacid having a cyclic structure and two amine groups that allow for the synthesis of a high molecular weight cationic compound which is extremely substantitive to human skin and are well tolerated by human tissue making them suitable for use preparation of barrier products for personal care applications. These materials are dimethylaminopropyl amine free, which is highly desirable in personal care applications.

  本发明涉及一种新型聚合物化合物类别，其具有基于二聊酸与一种烷基胺反应制备酯季铵化合物的特定季铵胺。二聊酸是一种具有环状结构和两个胺基的C-36二元酸，可用于合成高分子量阳离子化合物，对人体皮肤具有极高的亲和力，并且被人体组织很好地耐受，适合用于个人护理应用的屏障产品的制备。这些材料不含二甲基氨基丙胺，这在个人护理应用中非常理想。
• Dimer poly-quaternary compounds
  申请人：Surfa Tech Corporation

  公开号：US07193111B1

  公开（公告）日：2007-03-20

  The present invention relates to a novel class of polymeric compounds having specific quaternized amine based upon a dimer acid reacted with an dimethyl amino propyl amine to make an amido amine, which is subsequently reacted to make a polymeric quaternary compound. Dimer acid is a C-36 diacid having a cyclic structure and two amine groups that allow for the synthesis of a high molecular weight cationic compound which is extremely substantitive to human skin and are well tolerated by human tissue making them suitable for use preparation of barrier products for personal care applications.

  本发明涉及一种新型的聚合物化合物类，其具有基于二聚酸反应的特定季铵化胺，该二聚酸与二甲基氨丙基胺反应形成酰胺胺，随后反应形成聚合物季铵化合物。二聚酸是一种具有环状结构和两个胺基团的C-36二元酸，允许合成高分子量阳离子化合物，该化合物对人体皮肤具有极强的亲和力，并且被人体组织很好地耐受，使其适用于制备个人护理应用的屏障产品。
• Dimer amidopropyl dimethyl betaines
  申请人：O'Lenick, Jr. Anthony J.

  公开号：US06979744B1

  公开（公告）日：2005-12-27

  The present invention relates to a class of compounds having specific betaines based upon a dimer acid amido amine. Dimer acid is a C-36 diacid having a cyclic structure and two amine groups that allow for the synthesis of a high molecular weight material quaternary compound which is extremely substantitive to human skin and are well tolerated by human tissue making them suitable for use preparation of personal care products.

  本发明涉及一类基于二聚酸酰胺胺的特定季铵盐的化合物。二聚酸是一种具有环状结构和两个胺基的C-36双酸，可以合成高分子量物质季铵化合物，对人体皮肤具有极高的亲和力，并且被人体组织很好地耐受，使它们适用于制备个人护理产品。