1-N,6-N-bis(4-fluorophenyl)-1-N,6-N-diphenylpyrene-1,6-diamine | 722498-77-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-N,6-N-bis(4-fluorophenyl)-1-N,6-N-diphenylpyrene-1,6-diamine
• CAS: 722498-77-3
• 化学式: C₄₀H₂₆F₂N₂
• 分子量: 572.657
• InChiKey: MCCGDRKJECNRIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,6-二溴芘 、 4-氟二苯基胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以40%的产率得到1-N,6-N-bis(4-fluorophenyl)-1-N,6-N-diphenylpyrene-1,6-diamine
  参考文献：
  名称：

  Emission Color Tuning and Deep Blue Dopant Materials Based on 1,6-Bis(N-phenyl-p-(R)-phenylamino)pyrene

  摘要：

  Panchromatic 1,6-bis(N-phenyl-p-(R)-phenylamino)pyrenes, 2R, were obtained from Buchwald-Hartwig coupling reactions between N-phenyl-p-(R)-phenylamines and 1,6-dibromopyrene. The photophysical properties of 2R corresponded well to the electron-withdrawing and -donating nature of the diarylamine substituents, exhibiting a full color visible range between 454 and 620 nm. In particular, a deep blue 2CN showed a high radiative rate constant of 2.85 x 10(8) s(-1) with high emission quantum efficiency of 79%. Further applications of 2CN its it blue dopant were attempted using multilayer organic light-emitting devices. A maximum efficiency of 3.98 cd/A with CIE coordinates of x = 0.14, y = 0.10 were obtained.

  DOI：

  10.1021/jo901783a

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE AND ELECTRONIC APPARATUS PROVIDED WITH THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20200111965A1

  公开（公告）日：2020-04-09

  An organic electroluminescence device including a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer contains a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by formulas (11), (21), (31), (41), (51), (61), (71) and (81). In the formula (1), at least one of R 1 to R 8 is a deuterium atom.

  一种有机电致发光器件，包括阴极、阳极以及设置在阴极和阳极之间的发光层，其中该发光层包含以下式（1）所表示的化合物和从以下式（11）、（21）、（31）、（41）、（51）、（61）、（71）和（81）所表示的化合物组成的化合物中选择的一个或多个化合物。在式（1）中，R1至R8中的至少一个是氘原子。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：SEO Jeong Dae

  公开号：US20100155714A1

  公开（公告）日：2010-06-24

  Disclosed is an organic electroluminescent device including a substrate, a first and a second electrode, and an emitting layer formed between the first electrode and the second electrode. The emitting layer includes a plurality of materials which is a blue emitting material using a following chemical formula as dopant. In this case, at least one of A 1 and A 2 is selected from a substituted or non-substituted aromatic group, a heterocyclic group, an aliphatic group, and hydrogen.

  揭示了一种有机电致发光器件，包括基板、第一和第二电极，以及形成在第一电极和第二电极之间的发光层。发光层包括多种材料，其中一种是使用以下化学式作为掺杂剂的蓝色发光材料。在这种情况下，A1和A2中至少有一个是从取代或非取代芳香基团、杂环基团、脂肪基团和氢中选择的。
• ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.

  公开号：US20200152885A1

  公开（公告）日：2020-05-14

  The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. An organic electroluminescent device having a low driving voltage, a high luminous efficiency and/or excellent color coordinates can be provided by comprising the organic electroluminescent compound according to the present disclosure.

  本公开涉及一种有机电致发光化合物和包括该化合物的有机电致发光装置。根据本公开的有机电致发光化合物，可以提供具有低驱动电压、高发光效率和/或优秀色坐标的有机电致发光装置。
• [EN] ORGANIC ELECTROLUMINESCENCE COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉS À ÉLECTROLUMINESCENCE ORGANIQUE ET DISPOSITIF À ÉLECTROLUMINESCENCE ORGANIQUE LES COMPRENANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2014061961A1

  公开（公告）日：2014-04-24

  The present invention relates to an organic electroluminescence compound and an organic electroluminescence device containing the same. Using the organic electroluminescence compound according to the present invention, it is possible to manufacture an organic electroluminescence device having long lifespan and high luminous efficiency.

  本发明涉及一种有机电致发光化合物和含有该化合物的有机电致发光器件。利用本发明的有机电致发光化合物，可以制造具有长寿命和高发光效率的有机电致发光器件。
• PLURALITY OF LIGHT-EMITTING MATERIALS, ORGANIC ELECTROLUMINESCENT COMPOUND, AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.

  公开号：US20220037596A1

  公开（公告）日：2022-02-03

  The present disclosure relates to a plurality of light-emitting materials, an organic electroluminescent compound, and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound or a specific combination of compounds according to the present disclosure as a host material and/or a dopant material, it is possible to provide an organic electroluminescent device having improved driving voltage, luminous efficiency and/or lifetime properties compared to conventional organic electroluminescent devices.

  本公开涉及多种发光材料、有机电致发光化合物以及包含它们的有机电致发光器件。通过将本公开的有机电致发光化合物或特定化合物组合作为主体材料和/或掺杂材料，可以提供具有比传统有机电致发光器件更好的驱动电压、发光效率和/或寿命特性的有机电致发光器件。