1,4-bis(2'-pyridyl-3'-(2'',6''-dimethylphenyl))-2,5-diphenylbenzene | 1166837-82-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,4-bis(2'-pyridyl-3'-(2'',6''-dimethylphenyl))-2,5-diphenylbenzene
• 英文别名: 2-(2,6-Dimethylphenyl)-6-[4-[6-(2,6-dimethylphenyl)pyridin-2-yl]-2,5-diphenylphenyl]pyridine
• CAS: 1166837-82-6
• 化学式: C₄₄H₃₆N₂
• 分子量: 592.783
• InChiKey: RAHADWRWIICUHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  46
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,5-diphenylbenzene 、 2-bromo-6-(2,6-dimethylphenyl)pyridine 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 以93%的产率得到1,4-bis(2'-pyridyl-3'-(2'',6''-dimethylphenyl))-2,5-diphenylbenzene
  参考文献：
  名称：

  ORGANIC MATERIAL CONTAINING OLIGOPHENYLENE SKELETON AND LIGHT-EMITTING DEVICE USING THE SAME

  摘要：

  提供一种能够形成稳定非晶态薄膜的宽禁带材料，以及使用这种化合物并具有高发光效率的有机电致发光器件。 已经发现，一种新型的寡苯基衍生物可以通过交叉偶联反应有效地制备，该衍生物可用作有机电致发光材料。还发现，使用这种化合物可以制造出高效蓝色磷光发光器件。本发明基于这些发现。

  公开号：

  EP2236485A1

文献信息

• Organic Material Containing Oligophenylene Skeleton and Light-Emitting Device Using the Same
  申请人：Yamaguchi Shigehiro

  公开号：US20100308313A1

  公开（公告）日：2010-12-09

  [Object] To provide a wide band-gap material capable of forming a stable amorphous thin film and an organic electroluminescent device using such a compound and having a high light emission efficiency. [Solution] It has been found that a novel oligophenylene derivative, which is applicable as an organic electroluminescent material, can be produced efficiently using a cross-coupling reaction. It has also been found that a highly-efficient blue phosphorescent light-emitting device can be produced using this compound. The present invention is based on these findings.
• ORGANIC MATERIAL CONTAINING OLIGOPHENYLENE SKELETON AND LIGHT-EMITTING DEVICE USING THE SAME
  申请人：National University Corporation Nagoya University

  公开号：EP2236485A1

  公开（公告）日：2010-10-06

  [Object] To provide a wide band-gap material capable of forming a stable amorphous thin film and an organic electroluminescent device using such a compound and having a high light emission efficiency. [Solution] It has been found that a novel oligophenylene derivative, which is applicable as an organic electroluminescent material, can be produced efficiently using a cross-coupling reaction. It has also been found that a highly-efficient blue phosphorescent light-emitting device can be produced using this compound. The present invention is based on these findings.

  提供一种能够形成稳定非晶态薄膜的宽禁带材料，以及使用这种化合物并具有高发光效率的有机电致发光器件。 已经发现，一种新型的寡苯基衍生物可以通过交叉偶联反应有效地制备，该衍生物可用作有机电致发光材料。还发现，使用这种化合物可以制造出高效蓝色磷光发光器件。本发明基于这些发现。