1-(Furan-2-ylmethylsulfanyl)-3-propan-2-yloxypropan-2-ol | 1341546-37-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 1-(Furan-2-ylmethylsulfanyl)-3-propan-2-yloxypropan-2-ol
• CAS: 1341546-37-9
• 化学式: C₁₁H₁₈O₃S
• 分子量: 230.328
• InChiKey: WZJQPJVBYTVATI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  67.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  异丙基缩水甘油醚 、 糠基硫醇 以 水 为溶剂， 反应 0.17h， 以79%的产率得到1-(Furan-2-ylmethylsulfanyl)-3-propan-2-yloxypropan-2-ol
  参考文献：
  名称：

  Rapid, benign, and additive-free thiolysis of epoxides under ultrasonic/aqueous conditions

  摘要：

  An environmentally friendly and efficient procedure is developed for ring opening of various epoxides with thiols under non-thermal conditions. Reactions take place by ultrasonic irradiation of the two reactants suspended in an additive-free aqueous medium. Consequently, high-yield formation of various beta-hydroxy sulfides is quickly observed.[GRAPHICS].

  DOI：

  10.1080/17415993.2014.909814

文献信息

• Rapid, benign, and additive-free thiolysis of epoxides under ultrasonic/aqueous conditions
  作者：Mohammad M. Mojtahedi、Sajad Khalili

  DOI：10.1080/17415993.2014.909814

  日期：2014.7.4

  An environmentally friendly and efficient procedure is developed for ring opening of various epoxides with thiols under non-thermal conditions. Reactions take place by ultrasonic irradiation of the two reactants suspended in an additive-free aqueous medium. Consequently, high-yield formation of various beta-hydroxy sulfides is quickly observed.[GRAPHICS].