A polymerizable composition contains unsaturated urethane shown by Formula (1) given below, vinyl monomer which is copolymerizable with this unsaturated urethane, and an inorganic powder filler at weight ratio of (unsaturated urethane)/(vinyl monomer) = 10/90-90/10, the inorganic powder filler being 30-300 weight parts with respect to 100 weight parts of the sum of the unsaturated urethane and vinyl monomer:
where X is a residual group obtained by removing isocyanate groups from polyisocyanate; Y is a residual group obtained by removing hydroxyl groups from polyol; R¹ is a residual group obtained by removing hydroxyl group from non-radical polymerizable mono-ol having aliphatic hydrocarbon group with 6-22 carbon atoms; R² is H or CH₃; and p, q and r are each an integer 1-3 such that 2 ≦ p + q ≦ 4 and qr ≧ 2. In-mold cured products obtained from such a polymerizable composition have superior external appearance and water-resistance, and their mold shrinkage is small.
一种可聚合组合物包含如下式(1)所示的不饱和聚
氨酯、可与该不饱和聚
氨酯共聚的
乙烯基单体和无机粉末填料(重量比为(不饱和聚
氨酯)/(
乙烯基单体)=10/90-90/10),其中无机粉末填料相对于 100 重量份的不饱和聚
氨酯和
乙烯基单体之和为 30-300 重量份:
其中,X 是通过从多
异氰酸酯中去除
异氰酸酯基团而获得的残余基团;Y 是通过从多元醇中去除羟基而获得的残余基团;R¹ 是通过从具有 6-22 个碳原子的脂族烃基的非辐射可聚合单醇中去除羟基而获得的残余基团;R² 是 H 或 CH₃;p、q 和 r 分别是 1-3 的整数,使得 2 ≦ p + q ≦ 4 和 qr ≧ 2。由这种可聚合组合物制成的模内固化产品具有出色的外观和防
水性能,而且模具收缩率小。